[논문]Experimental observation of the liquid-liquid transition in bulk supercooled water under pressure

Kim, Kyung Hwan; Amann-Winkel, Katrin; Giovambattista, Nicolas; Spa¨h, Alexander; Perakis, Fivos; Pathak, Harshad; Parada, Marjorie Ladd; Yang, Cheolhee; Mariedahl, Daniel; Eklund, Tobias; Lane, Thomas. J.; You, Seonju; Jeong, Sangmin; Weston, Matthew; Lee, Jae Hyuk; Eom, Intae; Kim, Minseok; Park, Jaeku; Chun, Sae Hwan; Poole, Peter H.; Nilsson, Anders

doi:10.1126/science.abb9385

[해외논문] Experimental observation of the liquid-liquid transition in bulk supercooled water under pressure 원문보기

Science, v.370 no.6519 = no.6519, 2020년, pp.978 - 982

Kim, Kyung Hwan (Department of Physics, AlbaNova University Center, Stockholm University, SE-10691 Stockholm, Sweden.) , Amann-Winkel, Katrin (Department of Physics, AlbaNova University Center, Stockholm University, SE-10691 Stockholm, Sweden.) , Giovambattista, Nicolas (Department of Physics, Brooklyn College of the City University of New York, Brooklyn, NY 11210, USA.) , Spa¨h, Alexander (Department of Physics, AlbaNova University Center, Stockholm University, SE-10691 Stockholm, Sweden.) , Perakis, Fivos (Department of Physics, AlbaNova University Center, Stockholm University, SE-10691 Stockholm, Sweden.) , Pathak, Harshad (Department of Physics, AlbaNova University Center, Stockholm University, SE-10691 Stockholm, Sweden.) , Parada, Marjorie Ladd (Department of Physics, AlbaNova University Center, Stockholm University, SE-10691 Stockholm, Sweden.) , Yang, Cheolhee (Department of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang 37673, Republic of Korea.) , Mariedahl, Daniel (Department of Physics, AlbaNova University Center, Stockholm University, SE-10691 Stockholm, Sweden.) , Eklund, Tobias (Department of Physics, AlbaNova University Center, Stockholm) , Lane, Thomas. J. , You, Seonju , Jeong, Sangmin , Weston, Matthew , Lee, Jae Hyuk , Eom, Intae , Kim, Minseok , Park, Jaeku , Chun, Sae Hwan , Poole, Peter H. , Nilsson, Anders

Abstract ▼ AI-Helper

Liquid-liquid transitions under pressureTheoretical simulations suggest that deeply supercooled water undergoes a transition between high- and low-density forms, but this transition is difficult to study experimentally because it occurs under conditions in which ice crystallization is extremely rapid. Kim et al. combined x-ray lasers for rapid structure determination with infrared femtosecond pulses for rapid heating of amorphous ice layers formed at about 200 kelvin. The heating process created high-density liquid water at increased pressures. As the layer expanded and decompressed, low-density liquid domains appeared and grew on time scales between 20 nanoseconds and 3 microseconds, which was much faster than competing ice crystallization.Science, this issue p. 978We prepared bulk samples of supercooled liquid water under pressure by isochoric heating of high-density amorphous ice to temperatures of 205 ± 10 kelvin, using an infrared femtosecond laser. Because the sample density is preserved during the ultrafast heating, we could estimate an initial internal pressure of 2.5 to 3.5 kilobar in the high-density liquid phase. After heating, the sample expanded rapidly, and we captured the resulting decompression process with femtosecond x-ray laser pulses at different pump-probe delay times. A discontinuous structural change occurred in which low-density liquid domains appeared and grew on time scales between 20 nanoseconds to 3 microseconds, whereas crystallization occurs on time scales of 3 to 50 microseconds. The dynamics of the two processes being separated by more than one order of magnitude provides support for a liquid-liquid transition in bulk supercooled water.

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해당 논문의 주제분야에서 활용도가 높은 상위 5개 콘텐츠를 보여줍니다.
더보기 버튼을 클릭하시면 더 많은 관련자료를 살펴볼 수 있습니다.

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

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구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
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