[논문]Periodic Arrays of Chiral Domains Generated from the Self-Assembly of Micropatterned Achiral Lyotropic Chromonic Liquid Crystal

Park, Geonhyeong; Č; opar, Simon; Suh, Ahram; Yang, Minyong; Tkalec, Uroš; Yoon, Dong Ki

doi:10.1021/acscentsci.0c00995

[해외논문] Periodic Arrays of Chiral Domains Generated from the Self-Assembly of Micropatterned Achiral Lyotropic Chromonic Liquid Crystal 원문보기

ACS central science, v.6 no.11, 2020년, pp.1964 - 1970

Park, Geonhyeong (Graduate School of Nanoscience and Technology , Korea Advanced Institute of Science and Technology , Daejeon 34141 , Republic of Korea) , Čopar, Simon (Faculty of Mathematics and Physics , University of Ljubljana , Jadranska 19 , 1000 Ljubljana , Slovenia) , Suh, Ahram (Graduate School of Nanoscience and Technology , Korea Advanced Institute of Science and Technology , Daejeon 34141 , Republic of Korea) , Yang, Minyong (Graduate School of Nanoscience and Technology , Korea Advanced Institute of Science and Technology , Daejeon 34141 , Republic of Korea) , Tkalec, Uroš , Yoon, Dong Ki

Abstract ▼ AI-Helper

Achiral building blocks forming achiral structures is a common occurrence in nature, while chirality emerging spontaneously from an achiral system is usually associated with important scientific phenomena. We report on the spontaneous chiral symmetry-breaking phenomena upon the topographic confinement of achiral lyotropic chromonic liquid crystals in periodically arranged micrometer scale air pillars. The anisotropic fluid arranges into chiral domains that depend on the arrangement and spacing of the pillars. We characterize the resulting domains by polarized optical microscopy, support their reconstruction by numerical calculations, and extend the findings with experiments, which include chiral dopants. Well-controlled and addressed chiral structures will be useful in potential applications like programmable scaffolds for living liquid crystals and as sensors for detecting chirality at the molecular level.Well-addressed chiral domains are generated with achiral lyotropic chromonic liquid crystal materials using periodic air pillars, which can be potentially used for scaffolds for living matters.[FIG OMISSION]

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