[논문]Ultrafast igniting, low toxicity hypergolic hybrid solid fuels and hydrogen peroxide oxidizer

Jeong, Junyeong; Bhosale, Vikas Khandu; Kwon, Sejin

doi:10.1016/j.fuel.2020.119307

[해외논문] Ultrafast igniting, low toxicity hypergolic hybrid solid fuels and hydrogen peroxide oxidizer

Fuel, v.286 pt.1, 2021년, pp.119307 -

Jeong, Junyeong (Corresponding authors.) , Bhosale, Vikas Khandu (Corresponding authors.) , Kwon, Sejin

Abstract ▼ AI-Helper

Abstract The hydrazine derivatives, conventional hypergolic fuels, are highly toxic and carcinogenic; inspiring the search for safe and environmentally friendly hypergolic fuels. Hypergolic solid fuels (HSFs) containing amine-boranes, paraffin wax, and metal additives (MnO2-C, Pt-Ru-C, and Pd-C) were evaluated as new safe hypergolic fuels for space propulsion. Further, the hypergolic combustion of HSFs wasdemonstratedwith an environmentally friendly storable oxidizer, (95% H2O2). The effect of change in the weight percentage of ammonia borane (AB) and Pd-C on hypergolic ignitions were studied. A very small quantity of additive ‘triggers’ the hypergolic combustion of HSFs. HSFs containing 1 wt% of Pt-Ru-C and Pd-C additives exhibited ultrafast ignition delay times (IDTs) of 2.0 and 1.2 ms, respectively. Other than AB fuel, the dimethyl-imidazolium-borane, and tetramethyl-diamino-bisborane also demonstrated their application for HSFs. The thermal and chemical stability of HSF were evaluated by using DSC-TGA and powder XRD, respectively. The XRD study of HSF containing AB, Pd-C, and paraffin wax confirmed theβ-PdHx phase, which was maintained for 9 weeks under air atmosphere and proves the stability of HSF. Hence, such low toxicity propellants of HSFs and H2O2 oxidizer can be promising choices for green space propulsion. Graphical abstract [DISPLAY OMISSION]

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[해외논문] Ultrafast igniting, low toxicity hypergolic hybrid solid fuels and hydrogen peroxide oxidizer

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