[논문]Hydrogenation of Adiponitrile to Hexamethylenediamine over Raney Ni and Co Catalysts

Lee, Younghyun; Lee, Sung Woo; Kim, Hyung Ju; Kim, Yong Tae; Lin, Kun-Yi Andrew; Lee, Jechan

doi:10.3390/app10217506

[해외논문] Hydrogenation of Adiponitrile to Hexamethylenediamine over Raney Ni and Co Catalysts 원문보기

Applied sciences, v.10 no.21, 2020년, pp.7506 -

Lee, Younghyun (Department of Environmental Engineering, Ajou University, 206 Worldcup-ro, Suwon 16499, Korea) , Lee, Sung Woo (C1 Gas & Carbon Convergent Research Center, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Daejeon 34114, Korea) , Kim, Hyung Ju (C1 Gas & Carbon Convergent Research Center, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Daejeon 34114, Korea) , Kim, Yong Tae (C1 Gas & Carbon Convergent Research Center, Korea Research Institute of Chemical Technology, 141 Gajeong-ro, Daejeon 34114, Korea) , Lin, Kun-Yi Andrew (Department of Environmental Engineering & Innovation and Development Center of Sustainable Agriculture & Research Center of Sustainable Energy and Nanotechnology, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung 402, Taiwan) , Lee, Jechan (Department of Environmental Engineering, Ajou University, 206 Worldcup-ro, Suwon 16499, Korea)

Abstract ▼ AI-Helper

Hexamethylenediamine (HMDA), a chemical for producing nylon, was produced on Raney Ni and Raney Co catalysts via the hydrogenation of adiponitrile (ADN). HMDA was hydrogenated from ADN via 6-aminohexanenitrile (AHN). For the two catalysts, the effects of five different reaction parameters (reaction temperature, H2 pressure, catalyst loading, and ADN/HMDA ratio in the reactant) on the hydrogenation of ADN were investigated. Similar general trends demonstrating the dependence of ADN hydrogenation on the reaction conditions for both catalysts were observed: higher temperature (60-80 °C) and H2 pressure, as well as lower ADN/catalyst and ADN/HMDA ratios, led to higher HMDA yields. A further increase in temperature from 80 to 100 °C increased the HMDA yield from 90.5 to 100% for the Raney Ni catalyst, but did not affect the HMDA yield (85~87%) for the Raney Co catalyst. A 100% HMDA yield (the highest yield reported to date) was also achieved via ADN hydrogenation over the Raney Ni catalyst, with a high HMDA content in the reactant (e.g., ADN/HMDA volumetric ratio of 0.06). No sign of metal leaching into the product solution was found, meaning that the Raney Ni and Raney Co catalysts were stable during ADN hydrogenation.

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