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[해외논문] Ni-Catalyzed Intermolecular C(sp3)-H Amidation Tuned by Bidentate Directing Groups

ACS catalysis, v.11 no.5, 2021년, pp.3067 - 3072  

Kim, Yeong Bum (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , South Korea) ,  Won, Joonghee (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , South Korea) ,  Lee, Jeonghyo (Center for Catalytic Hydrocarbon Functionalizations , Institute for Basic Science (IBS) , Daejeon 34141 , South Korea) ,  Kim, Junho (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , South Korea) ,  Zhou, Bingwei (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , South Korea) ,  Park, Jung-Woo (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , South Korea) ,  Baik, Mu-Hyun ,  Chang, Sukbok

Abstract AI-Helper 아이콘AI-Helper

We disclose herein a directing group-assisted nickel-catalyzed intermolecular C(sp3)-H amidation using organic azides as nitrene precursors. With the installation of an electronically tailored directing group, enhanced amidation efficiency was achieved. A series of experimental and computational stu...

Keyword

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