[논문]Rapid ignition of “green” bipropellants enlisting hypergolic copper (II) promoter-in-fuel

Bhosale, Vikas Khandu; Gwak, Jinseong; Kim, Kyu-Seop; Churchill, David G.; Lee, Yunho; Kwon, Sejin

doi:10.1016/j.fuel.2021.120734

[해외논문] Rapid ignition of “green” bipropellants enlisting hypergolic copper (II) promoter-in-fuel

Fuel, v.297, 2021년, pp.120734 -

Bhosale, Vikas Khandu (Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology, KAIST) , Gwak, Jinseong (Department of Chemistry, Korea Advanced Institute of Science and Technology, KAIST) , Kim, Kyu-Seop (Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology, KAIST) , Churchill, David G. (Department of Chemistry, Korea Advanced Institute of Science and Technology, KAIST) , Lee, Yunho (Department of Chemistry, Seoul National University) , Kwon, Sejin (Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology, KAIST)

Abstract ▼ AI-Helper

Abstract Ionic liquid-with-promoter fuels and H2O2 oxidizer require optimization and further exploration of inexpensive initiators that can be understood at the molecular level; it is advantageous when exacting structural characterization comparisons can also be made. For the first time, hypergolic energetic copper(II) complexes viz. [CuII(1-H-imidazole)4(BH3CN)][BH3CN] (Cu-P1) and [CuII(1-methyl imidazole)4(BH3CN)2] (Cu-P2) were developed as new ‘promoters’ for “green” space vehicle propulsion. Cu-P1 and Cu-P2 exhibited ignition delay times (IDTs) of 3.75 and 8.5 ms, respectively, with 95% H2O2. The superior solubility of Cu-P1 in ionic and non-ionic fuels helped to promote the hypergolic ignition of green liquid fuels. The ionic liquid, 1-ethyl-3-methyl imidazolium cyanoborohydride ([EMIM][BH3CN]), non-ionic tetraglyme, and mixtures thereof (1:1, wt/wt%) were employed. A 13 wt% of Cu-P1 in [EMIM][BH3CN] improved the IDT from >1000 ms to 9.50 ms with 95% H2O2 and from >5000 ms to 21.25 ms with 70% H2O2. Hence, the development of a suitable energetic promoter, soluble in ionic liquid, gained significant attention for “green” bipropellant development. Interestingly, tetraglyme is non-hypergolic with H2O2; a 13 wt% Cu-P1 induced the hypergolic ignition with an IDT of 9.0 ms (95% H2O2). Moreover, the fuel mixture of [EMIM][BH3CN] and tetraglyme (1:1, wt/wt%) with 13 wt% Cu-P1 also revealed the shortest IDT of 7.75 ms (95% H2O2) and 16.5 ms (70% H2O2). The superior ignition performance, reasonable viscosity and density, long-term stability of promoter in the fuel, and comparable theoretical performance of hypergolic propellants are advantages of our approach. Highlights Hypergolic energetic copper complexes are investigated as new promoters. Low ignition delay of “green” fuels with 70% and 95% hydrogen peroxide. Promoter lowers the ignition delay of ionic liquids by 1000 times. Non-hypergolic to hypergolic fuels by using promoter. Graphical abstract [DISPLAY OMISSION]

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