[논문]A Robust and Highly Selective Catalytic System of Copper-Silica Nanocomposite and 1‐Butanol in Fructose Hydrogenation to Mannitol

Upare, Pravin P.; Hwang, Young Kyu; Kim, Jin Chul; Lee, Jeong Hyeon; Kwak, Sang Kyu; Hwang, Dong Won

doi:10.1002/cssc.202001323

[해외논문] A Robust and Highly Selective Catalytic System of Copper-Silica Nanocomposite and 1‐Butanol in Fructose Hydrogenation to Mannitol

ChemSusChem, v.13 no.18, 2020년, pp.5050 - 5057

Upare, Pravin P. (Green Carbon Catalysis Research Group Korea Research Institute of Chemical Technology (KRICT) 141 Gajeongro, Yuseoung Daejeon 34114 (Republic of Korea) , Hwang, Young Kyu (Green Carbon Catalysis Research Group Korea Research Institute of Chemical Technology (KRICT) 141 Gajeongro, Yuseoung Daejeon 34114 (Republic of Korea) , Kim, Jin Chul (Department of Energy Engineering School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST) 50 UNIST-gil, Ulju-gun Ulsan 44919 (Republic of Korea) , Lee, Jeong Hyeon (Department of Energy Engineering School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST) 50 UNIST-gil, Ulju-gun Ulsan 44919 (Republic of Korea) , Kwak, Sang Kyu (Department of Energy Engineering School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST) 50 UNIST-gil, Ulju-gun Ulsan 44919 (Republic of Korea) , Hwang, Dong Won (Green Carbon Catalysis Research Group Korea Research Institute of Chemical Technology (KRICT) 141 Gajeongro, Yuseoung Daejeo)

Abstract ▼ AI-Helper

AbstractWe report for the first time the selective production of mannitol, a low‐calorie sweetener and an important pharmaceutical ingredient, from fructose using Cu−SiO2 nanocomposite as catalyst and 1‐butanol as solvent. When compared with water and ethanol, a lower fructose solubility was achieved in 1‐butanol, which caused a lower fructose conversion and higher mannitol selectivity by reducing formation of side products. Among various Cu‐based catalysts in 1‐butanol, Cu(80)−SiO2 nanocomposite gave an unprecedented mannitol (83 %) and sorbitol (15 %) yield at 120 °C, 35 bar H2, and 10 h reaction time. More importantly, this catalyst did not show any Cu leaching and its physicochemical properties were maintained after liquid‐phase fructose hydrogenation whereas other Cu‐based catalysts such as Cu(32)−Cr2O and Cu(66)−ZnO did show significant leaching of Cu and Cr. Thus, Cu(80)−SiO2 nanocomposite and 1‐butanol are regarded as a robust and highly efficient catalytic system for the selective hydrogenation of fructose to mannitol. Also, density functional theory calculations supported that in addition to the stable initial structure of adsorbed fructose, the mannitol pathway was more thermodynamically favorable than the sorbitol pathway. Notably, the highly pure mannitol (99 %) could be recovered from the sorbitol‐containing 1‐butanol solution by simple filtration. Therefore, the present protocol is a novel and effective method to produce pure mannitol from fructose in both an environmental and an industrial context.

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