[논문]Cation Effects of Phosphate Additives for Enhancing the Oxidative Stability of Amine-Containing CO2 Adsorbents

Choi, Woosung; Park, Jongbeom; Choi, Minkee

doi:10.1021/acs.iecr.1c00515

[해외논문] Cation Effects of Phosphate Additives for Enhancing the Oxidative Stability of Amine-Containing CO2 Adsorbents

Industrial & engineering chemistry research, v.60 no.17, 2021년, pp.6147 - 6152

Choi, Woosung (Department of Chemical and Biomolecular Engineering , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , Republic of Korea) , Park, Jongbeom (Department of Chemical and Biomolecular Engineering , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , Republic of Korea) , Choi, Minkee

Abstract ▼ AI-Helper

Amine-containing adsorbents have been widely investigated for capturing CO2 but suffer from rapid oxidative degradation. We recently reported that ppm-level metal impurities (Fe and Cu) in commercial amine polymers can accelerate the oxidative degradation of these amine-containing adsorbents, which can be suppressed by adding chelators such as phosphate. In the present study, we investigated the amine-stabilization effects of monocationic phosphate salts containing cations of different charge densities, such as Li+, Na+, tetramethylammonium (TMA+), and tetraethylammonium (TEA+). The results showed that phosphate salts containing organophilic cations of low charge densities can effectively stabilize amine polymers. Such organophilic phosphate salts might be better dispersed within the organic amine polymers and have a loosely associated ion-pair form, which is beneficial for binding with metal impurities. Consequently, the adsorbent stabilized with the most organophilic TEAH2PO4 exhibited unprecedentedly high stability; specifically, it showed a very minor decrease in CO2 capacity (<3.5%) even after 1 month of aging in O2-containing flue gas at 110 °C.[FIG OMISSION]

참고문헌 (38)

Yu, Cheng-Hsiu, Huang, Chih-Hung, Tan, Chung-Sung. A Review of CO2 Capture by Absorption and Adsorption. Aerosol and air quality research, vol.12, no.5, 745-769.

상세보기
Samanta, Arunkumar, Zhao, An, Shimizu, George K. H., Sarkar, Partha, Gupta, Rajender. Post-Combustion CO₂ Capture Using Solid Sorbents: A Review. Industrial & engineering chemistry research, vol.51, no.4, 1438-1463.

상세보기
Bollini, Praveen, Didas, Stephanie A., Jones, Christopher W.. Amine-oxide hybrid materials for acid gas separations. Journal of materials chemistry, vol.21, no.39, 15100-15120.

상세보기
D'Alessandro, Deanna M., Smit, Berend, Long, Jeffrey R.. Carbon Dioxide Capture: Prospects for New Materials. Angewandte Chemie. international edition, vol.49, no.35, 6058-6082.

상세보기
Gao, Wanlin, Liang, Shuyu, Wang, Rujie, Jiang, Qian, Zhang, Yu, Zheng, Qianwen, Xie, Bingqiao, Toe, Cui Ying, Zhu, Xuancan, Wang, Junya, Huang, Liang, Gao, Yanshan, Wang, Zheng, Jo, Changbum, Wang, Qiang, Wang, Lidong, Liu, Yuefeng, Louis, Benoit, Scott, Jason, Roger, Anne-Cecile, Amal, Rose, He, Hong, Park, Sang-Eon. Industrial carbon dioxide capture and utilization: state of the art and future challenges. Chemical Society reviews, vol.49, no.23, 8584-8686.

상세보기
Hu, Xiayi (Eric), Liu, Libin, Luo, Xiao, Xiao, Gongkui, Shiko, Elenica, Zhang, Rui, Fan, Xianfeng, Zhou, Yefeng, Liu, Yang, Zeng, Zhaogang, Li, Chao'en. A review of N-functionalized solid adsorbents for post-combustion CO₂ capture. Applied energy, vol.260, 114244-.

상세보기
Jahandar Lashaki, Masoud, Khiavi, Soheil, Sayari, Abdelhamid. Stability of amine-functionalized CO₂ adsorbents: a multifaceted puzzle. Chemical Society reviews, vol.48, no.12, 3320-3405.

상세보기
Qi, Genggeng, Fu, Liling, Giannelis, Emmanuel P.. Sponges with covalently tethered amines for high-efficiency carbon capture. Nature communications, vol.5, 5796-.

상세보기
Hicks, J. C., Drese, J. H., Fauth, D. J., Gray, M. L., Qi, G., Jones, C. W.. Designing Adsorbents for CO₂ Capture from Flue Gas-Hyperbranched Aminosilicas Capable of Capturing CO₂ Reversibly. Journal of the American Chemical Society, vol.130, no.10, 2902-2903.

상세보기
McDonald, Thomas M., Mason, Jarad A., Kong, Xueqian, Bloch, Eric D., Gygi, David, Dani, Alessandro, Crocellà, Valentina, Giordanino, Filippo, Odoh, Samuel O., Drisdell, Walter S., Vlaisavljevich, Bess, Dzubak, Allison L., Poloni, Roberta, Schnell, Sondre K., Planas, Nora, Lee, Kyuho, Pascal, Tod, Wan, Liwen F., Prendergast, David, Neaton, Jeffrey B., Smit, Berend, Kortright, Jeffrey B., Gagliardi, Laura, Bordiga, Silvia, Reimer, Jeffrey A., Long, Jeffrey R.. Cooperative insertion of CO₂ in diamine-appended metal-organic frameworks. Nature, vol.519, no.7543, 303-308.

상세보기
Kim, Chaehoon, Cho, Hae Sung, Chang, Shuai, Cho, Sung June, Choi, Minkee. An ethylenediamine-grafted Y zeolite: a highly regenerable carbon dioxide adsorbent via temperature swing adsorption without urea formation. Energy & environmental science, vol.9, no.5, 1803-1811.

상세보기
Didas, Stephanie A., Zhu, Rongshun, Brunelli, Nicholas A., Sholl, David S., Jones, Christopher W.. Thermal, Oxidative and CO₂ Induced Degradation of Primary Amines Used for CO₂ Capture: Effect of Alkyl Linker on Stability. The journal of physical chemistry. C, Nanomaterials and Interfaces, vol.118, no.23, 12302-12311.

상세보기
Bollini, Praveen, Choi, Sunho, Drese, Jeffrey H., Jones, Christopher W.. Oxidative Degradation of Aminosilica Adsorbents Relevant to Postcombustion CO₂ Capture. Energy & fuels : an American Chemical Society journal, vol.25, no.5, 2416-2425.

상세보기
Heydari-Gorji, Aliakbar, Belmabkhout, Youssef, Sayari, Abdelhamid. Degradation of amine-supported CO₂ adsorbents in the presence of oxygen-containing gases. Microporous and mesoporous materials : the official journal of the International Zeolite Association, vol.145, no.1, 146-149.

상세보기
Calleja, G., Sanz, R., Arencibia, A., Sanz-Pérez, E. S.. Influence of Drying Conditions on Amine-Functionalized SBA-15 as Adsorbent of CO2. Topics in catalysis, vol.54, no.1, 135-145.

상세보기
Sayari, Abdelhamid, Heydari-Gorji, Aliakbar, Yang, Yong. CO₂-Induced Degradation of Amine-Containing Adsorbents: Reaction Products and Pathways. Journal of the American Chemical Society, vol.134, no.33, 13834-13842.

상세보기
Zhai, Yuxin, Chuang, Steven S. C.. Enhancing Degradation Resistance of Polyethylenimine for CO₂ Capture with Cross-Linked Poly(vinyl alcohol). Industrial & engineering chemistry research, vol.56, no.46, 13766-13775.

상세보기
Isenberg, Mathew, Chuang, Steven S. C.. The Nature of Adsorbed CO₂ and Amine Sites on the Immobilized Amine Sorbents Regenerated by Industrial Boiler Steam. Industrial & engineering chemistry research, vol.52, no.35, 12530-12539.

상세보기
Drage, T.C., Arenillas, A., Smith, K.M., Snape, C.E.. Thermal stability of polyethylenimine based carbon dioxide adsorbents and its influence on selection of regeneration strategies. Microporous and mesoporous materials : the official journal of the International Zeolite Association, vol.116, no.1, 504-512.

상세보기
Heydari-Gorji, Aliakbar, Sayari, Abdelhamid. Thermal, Oxidative, and CO₂-Induced Degradation of Supported Polyethylenimine Adsorbents. Industrial & engineering chemistry research, vol.51, no.19, 6887-6894.

상세보기
Choi, Woosung, Park, Jongbeom, Kim, Chaehoon, Choi, Minkee. Structural effects of amine polymers on stability and energy efficiency of adsorbents in post-combustion CO₂ capture. Chemical engineering journal, vol.408, 127289-.

상세보기
Min, Kyungmin, Choi, Woosung, Kim, Chaehoon, Choi, Minkee. Rational Design of the Polymeric Amines in Solid Adsorbents for Postcombustion Carbon Dioxide Capture. ACS applied materials & interfaces, vol.10, no.28, 23825-23833.

상세보기
Choi, Woosung, Min, Kyungmin, Kim, Chaehoon, Ko, Young Soo, Jeon, Jae Wan, Seo, Hwimin, Park, Yong-Ki, Choi, Minkee. Epoxide-functionalization of polyethyleneimine for synthesis of stable carbon dioxide adsorbent in temperature swing adsorption. Nature communications, vol.7, 12640-.

상세보기
Bali, Sumit, Chen, Thomas T., Chaikittisilp, Watcharop, Jones, Christopher W.. Oxidative Stability of Amino Polymer–Alumina Hybrid Adsorbents for Carbon Dioxide Capture. Energy & fuels : an American Chemical Society journal, vol.27, no.3, 1547-1554.

상세보기
Zhang, Xiaoyun, Zheng, Xiuxin, Zhang, Sisi, Zhao, Bei, Wu, Wei. AM-TEPA Impregnated Disordered Mesoporous Silica as CO₂ Capture Adsorbent for Balanced Adsorption–Desorption Properties. Industrial & engineering chemistry research, vol.51, no.46, 15163-15169.

상세보기
Min, Kyungmin, Choi, Woosung, Kim, Chaehoon, Choi, Minkee. Oxidation-stable amine-containing adsorbents for carbon dioxide capture. Nature communications, vol.9, no.1, 726-.

상세보기
Srikanth, Chakravartula S, Chuang, Steven S C. Spectroscopic Investigation into Oxidative Degradation of Silica-Supported Amine Sorbents for CO ₂ Capture. ChemSusChem, vol.5, no.8, 1435-1442.

상세보기
Pang, Simon H., Lee, Li-Chen, Sakwa-Novak, Miles A., Lively, Ryan P., Jones, Christopher W.. Design of Aminopolymer Structure to Enhance Performance and Stability of CO₂ Sorbents: Poly(propylenimine) vs Poly(ethylenimine). Journal of the American Chemical Society, vol.139, no.10, 3627-3630.

상세보기
Pang, Simon H., Lively, Ryan P., Jones, Christopher W.. Oxidatively‐Stable Linear Poly(propylenimine)‐Containing Adsorbents for CO₂ Capture from Ultradilute Streams. ChemSusChem, vol.11, no.15, 2628-2637.

상세보기
Goeppert, Alain, Zhang, Hang, Sen, Raktim, Dang, Huong, Prakash, G. K. Surya. Oxidation‐Resistant, Cost‐Effective Epoxide‐Modified Polyamine Adsorbents for CO₂ Capture from Various Sources Including Air. ChemSusChem, vol.12, no.8, 1712-1723.

상세보기
Vu, Quyen T., Yamada, Hidetaka, Yogo, Katsunori. Oxidative Degradation of Tetraethylenepentamine-Impregnated Silica Sorbents for CO₂ Capture. Energy & fuels : an American Chemical Society journal, vol.33, no.4, 3370-3379.

상세보기
Meng, Yuan, Jiang, Jianguo, Aihemaiti, Aikelaimu, Ju, Tongyao, Gao, Yuchen, Liu, Jiwei, Han, Siyu. Feasibility of CO₂ Capture from O₂-Containing Flue Gas Using a Poly(ethylenimine)-Functionalized Sorbent: Oxidative Stability in Long-Term Operation. ACS applied materials & interfaces, vol.11, no.37, 33781-33791.

상세보기
Min, Kyungmin, Choi, Woosung, Choi, Minkee. Macroporous Silica with Thick Framework for Steam‐Stable and High‐Performance Poly(ethyleneimine)/Silica CO₂ Adsorbent. ChemSusChem, vol.10, no.11, 2518-2526.

상세보기
Kim, Chaehoon, Choi, Woosung, Choi, Minkee. SO₂-Resistant Amine-Containing CO₂ Adsorbent with a Surface Protection Layer. ACS applied materials & interfaces, vol.11, no.18, 16586-16593.

상세보기
Chi, Susan, Rochelle, Gary T.. Oxidative Degradation of Monoethanolamine. Industrial & engineering chemistry research, vol.41, no.17, 4178-4186.

상세보기
Goff, G. S., Rochelle, G. T.. Monoethanolamine Degradation: O₂ Mass Transfer Effects under CO₂ Capture Conditions. Industrial & engineering chemistry research, vol.43, no.20, 6400-6408.

상세보기
Goff, G. S., Rochelle, G. T.. Oxidation Inhibitors for Copper and Iron Catalyzed Degradation of Monoethanolamine in CO₂ Capture Processes. Industrial & engineering chemistry research, vol.45, no.8, 2513-2521.

상세보기
Idris, Salah A, Mkhatresh, Omar A, Heatley, Frank. Assignment of ¹H NMR spectrum and investigation of oxidative degradation of poly(ethylenimine) using ¹H and ¹³C 1-D and 2-D NMR. Polymer international, vol.55, no.9, 1040-1048.

상세보기

LOADING...

활용도 분석정보

상세보기

다운로드

내보내기

활용도 Top5 논문

해당 논문의 주제분야에서 활용도가 높은 상위 5개 콘텐츠를 보여줍니다.
더보기 버튼을 클릭하시면 더 많은 관련자료를 살펴볼 수 있습니다.

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증