[논문]Highly Pure, Length-Sorted Boron Nitride Nanotubes by Gel Column Chromatography

Ko, Jaehyoung; Kim, Hyun Min; Moon, Se Youn; Ahn, Seokhoon; Im, Sung Gap; Joo, Yongho

doi:10.1021/acs.chemmater.1c01165

[해외논문] Highly Pure, Length-Sorted Boron Nitride Nanotubes by Gel Column Chromatography

Chemistry of materials : a publication of the American Chemical Society, v.33 no.12, 2021년, pp.4723 - 4732

Ko, Jaehyoung (Institute of Advanced Composite Materials , Korea Institute of Science and Technology (KIST) , 92 Chudong-ro, Bongdong-eup , Wanju-gun , Jeonbuk 55324 , Republic of Korea) , Kim, Hyun Min (Institute of Advanced Composite Materials , Korea Institute of Science and Technology (KIST) , 92 Chudong-ro, Bongdong-eup , Wanju-gun , Jeonbuk 55324 , Republic of Korea) , Moon, Se Youn (Department of Quantum System Engineering , Jeonbuk National University , 567 Baekje-daero, Deokjin-gu , Jeonju-si , Jeollabuk-do 54896 , Republic of Korea) , Ahn, Seokhoon (Institute of Advanced Composite Materials , Korea Institute of Science and Technology (KIST) , 92 Chudong-ro, Bongdong-eup , Wanju-gun , Jeonbuk 55324 , Republic of Korea) , Im, Sung Gap (Department of Chemical and Biomolecular Engineering and KAIST Institute for Nano Century , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , Kore) , Joo, Yongho

Abstract ▼ AI-Helper

Boron nitride nanotubes (BNNTs) have attracted enormous attention owing to their exceptional physical, chemical, and thermal properties. However, the implementation of such properties into practical applications has been hindered severely by limitations on the synthesis that results in a BNNT mixture containing significant amounts of impurities with varying size dispersity. Here, we present simultaneous purification and length sorting of such a mixture via gel column chromatography, where the components are effectively separated based on their affinity difference to the matrix. We report near-complete removal of the major impurities including >99% of the boron allotropes and 99.9% of the hexagonal boron nitrides while showing a series of length fractions containing long (1.00 ± 0.36 μm), medium (0.51 ± 0.21), and short (0.31 ± 0.19 μm) BNNTs in a one-step process that takes less than an hour. We expect the protocol established here to serve as a simple, fast, and scalable processing method amenable to the low-cost industrial processes, targeting various future BNNT applications that require high-purity BNNTs with tailored nanotube length.[FIG OMISSION]

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