[논문]Laser-scribed ultrasmall nanoparticles with unary and binary phases

Lam, Do Van; Sohail, Muhammad; Nguyen, Van-Toan; Ngo, Quang-Tung; Anto Jeffery, A.; Choi, Ho-Suk; Jung, Namgee; Kim, Jae-Hyun; Kim, Hyunuk; Lee, Seung-Mo

doi:10.1016/j.cej.2020.127731

[해외논문] Laser-scribed ultrasmall nanoparticles with unary and binary phases

Chemical engineering journal, v.421 pt.2, 2021년, pp.127731 -

Lam, Do Van (Korea Institute of Machinery and Materials (KIMM)) , Sohail, Muhammad (Korea Institute of Energy Research (KIER)) , Nguyen, Van-Toan (Department of Chemical Engineering and Applied Chemistry, Chungnam National University) , Ngo, Quang-Tung (Department of Chemical Engineering and Applied Chemistry, Chungnam National University) , Anto Jeffery, A. (Graduate School of Energy Science and Technology (GEST), Chungnam National University) , Choi, Ho-Suk (Department of Chemical Engineering and Applied Chemistry, Chungnam National University) , Jung, Namgee (Graduate School of Energy Science and Technology (GEST), Chungnam National University) , Kim, Jae-Hyun (Korea Institute of Machinery and Materials (KIMM)) , Kim, Hyunuk (Korea Institute of Energy Research (KIER)) , Lee, Seung-Mo (Korea Institute of Machinery and Materials (KIMM))

Abstract ▼ AI-Helper

Abstract Ultrasmall nanoparticles embedded in conductive support have immense potential in catalytic and energy-related applications, yet developing a fast and proper synthesis method remains a challenge. Herein, we demonstrate that, via simple laser scribing, isostructural metal–organic frameworks can be readily transformed into ultrasmall nanoparticles (5–14 nm) with different elemental compositions embedded in conductive carbon support. We found that the formation kinetics of nanoparticles is controlled by the thermodynamic reducibility of metal ions in the metal-organic framework as well as the cooling rate. This method allowed us to precisely tune the particle size and uniformity as well as the composition. As a potential application of the produced nanoparticles, we evaluated the electrocatalytic behavior of the Ni nanoparticles embedded in carbon support. It exhibited excellent performance and stability for the hydrogen evolution reaction in both acid and alkaline electrolytes. Highlights Laser-scribing enables rapid synthesis of ultrasmall nanoparticles@carbon out of MOFs. The method can precisely tune the particle size, uniformity and phase composition. The kinetics is controlled by the reducibility of metal ions and the cooling rate. The Ni nanoparticles@carbon showed excellent HER activities in various electrolytes. Graphic abstract [DISPLAY OMISSION]

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