[논문]Enhancement of Catalytic Activity and Durability of Pt Nanoparticle through Strong Chemical Interaction with Electrically Conductive Support of Magnéli Phase Titanium Oxide

Dogan, Didem C.; Choi, Jiye; Seo, Min Ho; Lee, Eunjik; Jung, Namgee; Yim, Sung-Dae; Yang, Tae-Hyun; Park, Gu-Gon

doi:10.3390/nano11040829

[해외논문] Enhancement of Catalytic Activity and Durability of Pt Nanoparticle through Strong Chemical Interaction with Electrically Conductive Support of Magnéli Phase Titanium Oxide 원문보기

Nanomaterials, v.11 no.4, 2021년, pp.829 -

Dogan, Didem C. (Fuel Cell Laboratory, Korea Institute of Energy Research (KIER), 152, Gajeong-ro, Yuseong-gu, Daejeon 34129, Korea) , Choi, Jiye (didemcil@gmail.com (D.C.D.)) , Seo, Min Ho (jiye1120@kier.re.kr (J.C.)) , Lee, Eunjik (ejlee21@kier.re.kr (E.L.)) , Jung, Namgee (jimmyim@kier.re.kr (S.-D.Y.)) , Yim, Sung-Dae (thyang@kier.re.kr (T.-H.Y.)) , Yang, Tae-Hyun (Fuel Cell Laboratory, Korea Institute of Energy Research (KIER), 152, Gajeong-ro, Yuseong-gu, Daejeon 34129, Korea) , Park, Gu-Gon (didemcil@gmail.com (D.C.D.))

Abstract ▼ AI-Helper

In this study, we address the catalytic performance of variously sized Pt nanoparticles (NPs) (from 1.7 to 2.9 nm) supported on magnéli phase titanium oxide (MPTO, Ti4O7) along with commercial solid type carbon (VXC-72R) for oxygen reduction reaction (ORR). Key idea is to utilize a robust and electrically conductive MPTO as a support material so that we employed it to improve the catalytic activity and durability through the strong metal-support interaction (SMSI). Furthermore, we increase the specific surface area of MPTO up to 61.6 m2 g−1 to enhance the SMSI effect between Pt NP and MPTO. After the deposition of a range of Pt NPs on the support materials, we investigate the ORR activity and durability using a rotating disk electrode (RDE) technique in acid media. As a result of accelerated stress test (AST) for 30k cycles, regardless of the Pt particle size, we confirmed that Pt/MPTO samples show a lower electrochemical surface area (ECSA) loss (<20%) than that of Pt/C (~40%). That is explained by the increased dissolution potential and binding energy of Pt on MPTO against to carbon, which is supported by the density functional theory (DFT) calculations. Based on these results, we found that conductive metal oxides could be an alternative as a support material for the long-term fuel cell operation.

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참고문헌 (76)

1. Rabis A. Rodriguez P. Schmidt T.J. Electrocatalysis for polymer electrolyte fuel cells: Recent achievements and future challenges ACS Catal. 2012 2 864 890 10.1021/cs3000864

상세보기
2. Carter D. Ryan M. Wing J. The Fuel Cell Industry Review 2013 Platin. Met. Rev. 2013 57 310 10.1595/147106713x674292
3. Yang Y. Song Y. Sun H. Xiang D. Jiang Q. Lu Z. He H. Huang H. Rh-decorated three-dimensional graphene aerogel networks as highly-efficient electrocatalysts for direct methanol fuel cells Front. Energy Res. 2020 8 8 10.3389/fenrg.2020.00060

상세보기
4. Zheng H.B. An L. Zheng Y. Qu C. Fang Y. Liu Q. Dang D. Tuning the catalytic activity of Ir@Pt nanoparticles through controlling Ir core size on cathode performance for PEM fuel cell application Front. Chem. 2018 6 299 10.3389/fchem.2018.00299 30094230

상세보기
5. Noel J.M. Yu Y. Mirkin M.V. Dissolution of Pt at moderately negative potentials during oxygen reduction in water and organic media Langmuir 2013 29 1346 1350 10.1021/la304694d 23323756

상세보기
6. Brouzgou A. Seretis A. Song S. Shen P.K. Tsiakaras P. CO tolerance and durability study of PtMe(Me = Ir or Pd) electrocatalysts for H2-PEMFC application Int. J. Hydrogen Energy 2020 10.1016/j.ijhydene.2020.07.224

상세보기
7. Tian Z.Q. Lim S.H. Poh C.K. Tang Z. Xia Z. Luo Z. Shen P.K. Chua D. Feng Y.P. Shen Z. A highly order-structured membrane electrode assembly with vertically aligned carbon nanotubes for ultra-low Pt loading PEM fuel cells Adv. Energy Mater. 2011 1 1205 1214 10.1002/aenm.201100371

상세보기
8. Murata S. Imanishi M. Hasegawa S. Namba R. Vertically aligned carbon nanotube electrodes for high current density operating proton exchange membrane fuel cells J. Power Sources 2014 253 104 113 10.1016/j.jpowsour.2013.11.073

상세보기
9. Hwang S.M. Park J.H. Lim S. Jung D.H. Guim H. Yoon Y.G. Yim S.D. Kim T.Y. Designing an ultrathin silica layer for highly durable carbon nanofibers as the carbon support in polymer electrolyte fuel cells Nanoscale 2014 6 12111 12119 10.1039/C4NR04293J 25196022

상세보기
10. Ghosh A. Basu S. Verma A. Graphene and functionalized graphene supported platinum catalyst for PEMFC Fuel Cells 2013 13 355 363 10.1002/fuce.201300039

상세보기
11. Antolini E. Graphene as a new carbon support for low-temperature fuel cell catalysts Appl. Catal. B Environ. 2012 123–124 52 68 10.1016/j.apcatb.2012.04.022

상세보기
12. Zhong X. Ye S. Tang J. Zhu Y. Wu D. Gu M. Pan H. Xu B. Engineering Pt and Fe dual-metal single atoms anchored on nitrogen-doped carbon with high activity and durability towards oxygen reduction reaction for zinc-air battery Appl. Catal. B Environ. 2021 286 119891 10.1016/j.apcatb.2021.119891

상세보기
13. Krishnan P. Advani S. Prasad A.K. Magneli phase Ti n O2n—1 as corrosion-resistant PEM fuel cell catalyst support J. Solid State Chem. 2012 16 2515 2521 10.1007/s10008-012-1663-1

상세보기
14. Yao C. Li F. Li X. Xia D. Fiber-like nanostructured Ti4O7 used as durable fuel cell catalyst support in oxygen reduction catalysis J. Mater. Chem. 2012 22 16560 10.1039/c2jm32866f

상세보기
15. Kakinuma K. Chino Y. Senoo Y. Uchida M. Kamino T. Uchida H. Deki S. Watanabe M. Characterization of Pt catalysts on Nb-doped and Sb-doped SnO2–δ support materials with aggregated structure by rotating disk electrode and fuel cell measurements Electrochim. Acta. 2013 110 316 324 10.1016/j.electacta.2013.06.127

상세보기
16. Shao Y. Liu J. Wang Y. Lin Y. Novel catalyst support materials for PEMfuelcells: Current status and future prospects J. Mater. Chem. 2009 19 46 59 10.1039/B808370C

상세보기
17. Yang D.H. Sui X.L. Zhao L. Huang G.S. Gu D.M. Wang Z.B. Pt supported on carbon-coating antimony Tin oxide as anode catalyst for direct methanol fuel cell Fuel Cells 2018 18 763 770 10.1002/fuce.201800039

상세보기
18. Naik K.M. Higuchi E. Inoue H. Two-dimensional oxygen-deficient TiO 2 nanosheets-supported Pt nanoparticles as durable catalyst for oxygen reduction reaction in proton exchange membrane fuel cells J. Power Sources 2020 455 227972 10.1016/j.jpowsour.2020.227972

상세보기
19. Alipour Moghadam Esfahani R. Ebralidze I.I. Specchia S. Easton E.B. A fuel cell catalyst support based on doped titanium suboxides with enhanced conductivity, durability and fuel cell performance J. Mater. Chem. A 2018 6 14805 14815 10.1039/C8TA02470G

상세보기
20. Jeon Y. Ji Y. Cho Y.I. Lee C. Park D.H. Shul Y.G. Oxide-carbon nanofibrous composite support for a highly active and stable polymer electrolyte membrane fuel-cell catalyst ACS Nano 2018 12 6819 6829 10.1021/acsnano.8b02040 29966089

상세보기
21. Sullivan M.T. Alipour Moghadam Esfahani R. Easton E.B. Conductive metal oxide-based fuel cell catalyst supports prepared by doping TiO 2 with Si understanding the role of Si content EXS Trans. 2020 97 659 670 10.1149/09707.0659ecst

상세보기
22. Wang J. Yin G. Shao Y. Zhang S. Wang Z. Gao Y. Effect of carbon black support corrosion on the durability of Pt/C catalyst J. Power Sources 2007 171 331 339 10.1016/j.jpowsour.2007.06.084

상세보기
23. Maass S. Finsterwalder F. Frank G. Hartmann R. Merten C. Carbon support oxidation in PEM fuel cell cathodes J. Power Sources 2008 176 444 451 10.1016/j.jpowsour.2007.08.053

상세보기
24. Tang H. Qi Z. Ramani M. Elter J.F. PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode J. Power Sources 2006 158 1306 1312 10.1016/j.jpowsour.2005.10.059

상세보기
25. Hacker V. Baumgartner W. Wallnöfer E. Schaffer T. Besenhard J.O. Characterization of carbon nanofiber-based fuel cell electrodes EXS Trans. 2006 3 295 10.1149/1.2356148

상세보기
26. Bartholomew R.F. Frankl D.R. Electrical properties of some titanium oxides Phys. Rev. B 1969 187 828 833 10.1103/PhysRev.187.828

상세보기
27. Chen G. Bare S.R. Mallouk T.E. Development of supported bifunctional electrocatalysts for unitized regenerative fuel cells J. Electrochem. Soc. 2002 149 A1092 10.1149/1.1491237

상세보기
28. Ioroi T. Siroma Z. Fujiwara N. Yamazaki S. Yasuda K. Sub-stoichiometric titanium oxide-supported platinum electrocatalyst for polymer electrolyte fuel cells Electrochem. Commun. 2005 7 183 188 10.1016/j.elecom.2004.12.007

상세보기
29. Ioroi T. Senoh H. Yamazaki S. Siroma Z. Fujiwara N. Yasuda K. Stability of corrosion-resistant Magnéli-phase Ti4O7-supported PEMFC catalysts at high potentials J. Electrochem. Soc. 2008 155 B321 10.1149/1.2833310

상세보기
30. Dogan D.C. Hwang S.M. Jang E.H. Yim S.D. Sohn Y.J. Kim S.H. Yang T.H. Park G.G. Highly platinum-loaded Magneli phase titanium oxides as a high voltage tolerant electrocatalyst for polymer electrolyte fuel cells J. Nanosci. Nanotechnol. 2015 15 6988 6994 10.1166/jnn.2015.10549 26716272

상세보기
31. Islam J. Kim S.K. Kim K.H. Lee E. Park G.G. Enhanced durability of Pt/C catalyst by coating carbon black with silica for oxygen reduction reaction Int. J. Hydrogen Energy 2021 46 1133 1143 10.1016/j.ijhydene.2020.09.194

상세보기
32. Warschkow O. Wang Y. Subramanian A. Asta M. Marks L.D. Structure and local-equilibrium thermodynamics of the c(2x2) reconstruction of rutile TiO 2 (100) Phys. Rev. Lett. 2008 100 086102 10.1103/PhysRevLett.100.086102 18352638

상세보기
33. Wang Y. Warschkow O. Marks L.D. Surface evolution of rutile TiO 2 (100) in an oxidizing environment Surf. Sci. 2007 601 63 67 10.1016/j.susc.2006.09.005

상세보기
34. Yoshida K. Kawai T. Nambara T. Tanemura S. Saitoh K. Tanaka N. Direct observation of oxygen atoms in rutile titanium dioxide by spherical aberration corrected high-resolution transmission electron microscopy Nanotechnology 2006 17 3944 3950 10.1088/0957-4484/17/15/056

상세보기
35. Kresse G. Furthmuller J. Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Phys. Rev. B 1996 54 11169 11186 10.1103/PhysRevB.54.11169

상세보기
36. Blochl P.E. Projector augmented-wave method Phys. Rev. B Condens. Matter 1994 50 17953 17979 10.1103/PhysRevB.50.17953 9976227

상세보기
37. Kresse G. Joubert D. From ultrasoft pseudopotentials to the projector augmented-wave method Phys. Rev. B 1999 59 1758 1775 10.1103/PhysRevB.59.1758

상세보기
38. Perdew J.P. Burke K. Ernzerhof M. Generalized gradient approximation made simple Phys. Rev. Lett. 1996 77 3865 3868 10.1103/PhysRevLett.77.3865 10062328

상세보기
39. Blochl P.E. Jepsen O. Andersen O.K. Improved tetrahedron method for Brillouin-zone integrations Phys. Rev. B Condens. Matter 1994 49 16223 16233 10.1103/PhysRevB.49.16223 10010769

상세보기
40. Wang Y.J. Wilkinson D.P. Zhang J. Noncarbon support materials for polymer electrolyte membrane fuel cell electrocatalysts Chem. Rev. 2011 111 7625 7651 10.1021/cr100060r 21919529

상세보기
41. Feldberg S.W. Enke C.G. Bricker C.E. Formation and dissolution of platinum oxide film: Mechanism and kinetics J. Electrochem. Soc. 1963 110 826 834 10.1149/1.2425880

상세보기
42. Seo M.H. Choi S.M. Lim E.J. Kwon I.H. Seo J.K. Noh S.H. Kim W.B. Han B. Toward new fuel cell support materials: A theoretical and experimental study of nitrogen-doped graphene ChemSusChem 2014 7 2609 2620 10.1002/cssc.201402258 25044873

상세보기
43. Higgins D. Hoque M.A. Seo M.H. Wang R. Hassan F. Choi J.Y. Pritzker M. Yu A. Zhang J. Chen Z. Development and simulation of sulfur-doped graphene supported platinum with exemplary stability and activity towards oxygen reduction Adv. Funct. Mater. 2014 24 4325 4336 10.1002/adfm.201400161

상세보기
44. Seo M.H. Park H.W. Lee D.U. Park M.G. Chen Z. Design of highly active perovskite oxides for oxygen evolution reaction by combining experimental and ab Initio studies ACS Catal. 2015 5 4337 4344 10.1021/acscatal.5b00114

상세보기
45. Lundqvist B.I. Gunnarsson O. Hjelmberg H. Theoretical description of molecure-metal interaction and surface reactions Surf. Sci. 1979 89 196 225 10.1016/0039-6028(79)90608-3

상세보기
46. Hammer B. Norskov J.K. Why gold is the noblest of all the metals Lett. Nat. 1995 376 238 240 10.1038/376238a0

상세보기
47. Hammer B. Norskov J.K. Theoretical Surface Science and Catalysis—Calculations and Concepts Adv. Catal. 2000 45 71 129
48. Calle-Vallejo F. Díaz-Morales O.A. Kolb M.J. Koper M.T.M. Why Is bulk thermochemistry a good descriptor for the electrocatalytic activity of rransition metal oxides? ACS Catal. 2015 5 869 873 10.1021/cs5016657

상세보기
49. Calle-Vallejo F. Martinez J.I. Garcia-Lastra J.M. Mogensen M. Rossmeisl J. Trends in stability of perovskite oxides Angew. Chem. Int. Ed. 2010 49 7699 7701 10.1002/anie.201002301

상세보기
50. Calle-Vallejo F. Inoglu N.G. Su H.Y. Martínez J.I. Man I.C. Koper M.T.M. Kitchin J.R. Rossmeisl J. Number of outer electrons as descriptor for adsorption processes on transition metals and their oxides Chem. Sci. 2013 4 1245 10.1039/c2sc21601a

상세보기
51. Bader R.F. Atoms in Molecules Wiley online Library Hoboken, NJ, USA 1990
52. Seo J.K. Khetan A. Seo M.H. Kim H. Han B. First-principles thermodynamic study of the electrochemical stability of Pt nanoparticles in fuel cell applications J. Power Sources 2013 238 137 143 10.1016/j.jpowsour.2013.03.077

상세보기
53. Jinnouchi R. Toyoda E. Hatanaka T. Morimoto Y. First principles calculations on site-dependent dissolution potentials of supported and unsupported Pt particles J. Phys. Chem. C 2010 114 17557 17568 10.1021/jp106593d

상세보기
54. Noh S.H. Seo M.H. Seo J.K. Fischer P. Han B. First principles computational study on the electrochemical stability of Pt-Co nanocatalysts Nanoscale 2013 5 8625 8633 10.1039/c3nr02611f 23897215

상세보기
55. Tang L. Han B. Persson K. Friesen C. He T. Sieradzki K. Ceder G. Electrochemical stability of nanometer-scale Pt particles in acidic environments J. Am. Chem. Soc. 2009 132 596 600 10.1021/ja9071496

상세보기
56. Shao M. Liu P. Zhang J. Adzic R. Origin of enhanced activity in palladium alloy electrocatalysts for oxygen reduction reaction J. Phys. Chem. B 2007 111 6772 6775 10.1021/jp0689971 17441757

상세보기
57. Hammer B. Norskov J.K. Electronic factors determining the reactivity of metal surfaces Surf. Sci. 1995 343 211 220 10.1016/0039-6028(96)80007-0

상세보기
58. Demirci U.B. Theoretical means for searching bimetallic alloys as anode electrocatalysts for direct liquid-feed fuel cells J. Power Sources 2007 173 11 18 10.1016/j.jpowsour.2007.04.069

상세보기
59. Shao M. Liu P. Zhang J. Sasaki K. Vukmirovic M.B. Adzic R.R. Palladium monolayer and palladium alloy electrocatalysts for oxygen reduction Langmuir 2006 22 10409 10415 10.1021/la0610553 17129009

상세보기
60. Greeley J. Mavrikakis M. Alloy catalysts designed from first principles Nat. Mater. 2004 3 810 815 10.1038/nmat1223 15502837

상세보기
61. Shao M. Sasaki K. Marinkovic N. Zhang L. Adzic R. Synthesis and characterization of platinum monolayer oxygen-reduction electrocatalysts with Co–Pd core–shell nanoparticle supports Electrochem. Commun. 2007 9 2848 2853 10.1016/j.elecom.2007.10.009

상세보기
62. Greeley J. Stephens I.E. Bondarenko A.S. Johansson T.P. Hansen H.A. Jaramillo T.F. Rossmeisl J. Chorkendorff I. Norskov J.K. Alloys of platinum and early transition metals as oxygen reduction electrocatalysts Nat. Chem. 2009 1 552 556 10.1038/nchem.367 21378936

상세보기
63. Strasser P. Koh S. Anniyev T. Greeley J. More K. Yu C. Liu Z. Kaya S. Nordlund D. Ogasawara H. Lattice-strain control of the activity in dealloyed core-shell fuel cell catalysts Nat. Chem. 2010 2 454 460 10.1038/nchem.623 20489713

상세보기
64. Lee Y. Kleis J. Rossmeisl J. Morgan D. Ab initio energetics of LaBO3(001) (B=Mn, Fe, Co, and Ni) for solid oxide fuel cell cathodes Phys. Rev. B 2009 80 224101 10.1103/PhysRevB.80.224101

상세보기
65. Pople J.A. HeadGordon M. Fox D.J. Raghavachari K. Curtiss L.A. Gaussian-1 theory: A general procedure for prediction of molecular energies J. Chem. Phys. 1989 90 5622 5629 10.1063/1.456415

상세보기
66. Han B.C. Miranda C.R. Ceder G. Effect of particle size and surface structure on adsorption of O and OH on platinum nanoparticles: A first-principles study Phys. Rev. B 2008 77 075410 10.1103/PhysRevB.77.075410

상세보기
67. Sattiler M.L. Ross P.N. The surface structure of Pt crystallites supported on carbon black Ultramicroscopy 1986 20 21 28 10.1016/0304-3991(86)90163-4

상세보기
68. Kinoshita K. Particle size effects for oxygen reduction on highly dispersed platinum in acid electrolytes J. Electrochem. Soc. 1990 137 845 848 10.1149/1.2086566

상세보기
69. Mukerjee S. McBreen J. Effect of particle size on the electrocatalysis by carbon-supported Pt electrocatalysts: An in situ XAS investigation J. Electroanal. Chem. 1998 448 163 171 10.1016/S0022-0728(97)00018-1

상세보기
70. Ekuma E.E. Bagayoko D. Ab-initio electronic and structural properties of rutile titanium dioxide Jpn. J. Appl. Phys. 2011 50 101103 10.1143/JJAP.50.101103

상세보기
71. Labat F. Baranek P. Domain C. Minot C. Adamo C. Density functional theory analysis of the structural and electronic properties of TiO 2 rutile and anatase polytypes: Performances of different exchange-correlation functionals J. Chem. Phys. 2007 126 154703 10.1063/1.2717168 17461655

상세보기
72. Zhang J. Su N. Hu X. Zhu F. Yu Y. Yang H. Facile synthesis of Pt nanoparticles supported on anatase TiO 2 nanotubes with good photo-electrocatalysis performance for methanol RSC Adv. 2017 7 56194 56203 10.1039/C7RA11564D

상세보기
73. Huang K. Sasaki K. Adzic R.R. Xing Y. Increasing Pt oxygen reduction reaction activity and durability with a carbon-doped TiO 2 nanocoating catalyst support J. Mater. Chem. 2012 22 16824 10.1039/c2jm32234j

상세보기
74. Mayrhofer K.J.J. Blizanac B.B. Arenz M. Stamenkovic V.R. Ross P.N. Markovic N.M. The impact of geometric and surface electronic properties of Pt-catalysts on the particle size effect in electrocatalysis J. Phys. Chem. B 2005 109 14433 14440 10.1021/jp051735z 16852816

상세보기
75. Jang J.H. Kim J. Lee Y.H. Kim I.Y. Park M.H. Yang C.W. Hwang S.J. Kwon Y.U. One-pot synthesis of core–shell-like Pt3Co nanoparticle electrocatalyst with Pt-enriched surface for oxygen reduction reaction in fuel cells Energy Environ. Sci. 2011 4 4947 10.1039/c1ee01825f

상세보기
76. Shinagawa T. Garcia-Esparza A.T. Takanabe K. Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion Sci. Rep. 2015 5 13801 10.1038/srep13801 26348156

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