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NTIS 바로가기Bulletin of the Korean Chemical Society, v.42 no.3, 2021년, pp.529 - 532
Kim, Jinwoo (Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 South Korea) , Jin, Seongho (Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 South Korea) , Kim, Dongwook (Center for Catalytic Hydrocarbon Functionalization Institute for Basic Science (IBS) Daejeon 34141 South Korea) , Chang, Sukbok (Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 South Korea)
Herein, we describe the mechanistic details on the oxidatively induced reductive elimination of isolated methyl iridium and ruthenium metallacycle complexes. It was demonstrated that the otherwise challenging C─C bond formation is indeed facilitated by external oxidation, being enabled under mild co...
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For triplet neutral (Mn‐MeS=3) and quartet cationic (Mn+1‐MeS=4) species each metallacycle displayed significantly higher energy compared to the low‐spin counterparts. On the other hand the RE process from triplet dicationic analogues (Mn+2‐MeS=3) was calculated to require higher energy (23.5 and 13.3 kcal/mol forIrV‐MeS=3andRuIV‐MeS=4 respectively). See the Supporting Information for details.
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