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[국내논문] OXIDATIVELY INDUCED Reductive Elimination for Methyl Group Transfer via Isolable Transmetalation Complexes 원문보기

Bulletin of the Korean Chemical Society, v.42 no.3, 2021년, pp.529 - 532  

Kim, Jinwoo (Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 South Korea) ,  Jin, Seongho (Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 South Korea) ,  Kim, Dongwook (Center for Catalytic Hydrocarbon Functionalization Institute for Basic Science (IBS) Daejeon 34141 South Korea) ,  Chang, Sukbok (Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 South Korea)

Abstract AI-Helper 아이콘AI-Helper

Herein, we describe the mechanistic details on the oxidatively induced reductive elimination of isolated methyl iridium and ruthenium metallacycle complexes. It was demonstrated that the otherwise challenging C─C bond formation is indeed facilitated by external oxidation, being enabled under mild co...

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