[논문]Sub-micro droplet reactors for green synthesis of Li 3 VO 4 anode materials in lithium ion batteries

Tran Huu, Ha; Vu, Ngoc Hung; Ha, Hyunwoo; Moon, Joonhee; Kim, Hyun You; Im, Won Bin

doi:10.1038/s41467-021-23366-8

[해외논문] Sub-micro droplet reactors for green synthesis of Li 3 VO 4 anode materials in lithium ion batteries 원문보기

Nature communications, v.12 no.1, 2021년, pp.3081 -

Tran Huu, Ha (Division of Materials Science and Engineering, Hanyang University, Seoul, Republic of Korea) , Vu, Ngoc Hung (Faculty of Biotechnology, Chemistry and Environmental Engineering, Phenikaa University, Hanoi, Vietnam) , Ha, Hyunwoo (Department of Materials Science and Engineering, Chungnam National University, Daejeon, Korea) , Moon, Joonhee (Advanced Nano-Surface Research Group, Korea Basic Science Institute, Daejeon, Republic of Korea) , Kim, Hyun You (Department of Materials Science and Engineering, Chungnam National University, Daejeon, Korea) , Im, Won Bin (Division of Materials Science and Engineering, Hanyang University, Seoul, Republic of Korea)

Abstract ▼ AI-Helper

The conventional solid-state reaction suffers from low diffusivity, high energy consumption, and uncontrolled morphology. These limitations are competed by the presence of water in solution route reaction. Herein, based on concept of combining above methods, we report a facile solid-state reaction conducted in water vapor at low temperature along with calcium doping for modifying lithium vanadate as anode material for lithium-ion batteries. The optimized material, delivers a superior specific capacity of 543.1, 477.1, and 337.2 mAh g−1 after 200 and 1000 cycles at current densities of 100, 1000 and 4000 mA g−1, respectively, which is attributed to the contribution of pseudocapacitance. In this work, we also use experimental and theoretical calculation to demonstrate that the enhancement of doped lithium vanadate is attributed to particles confinement of droplets in water vapor along with the surface and structure variation of calcium doping effect.The conventional solid-state reaction suffers from the low diffusivity, high energy consumption, and uncontrolled morphology. Here, the authors report a low-temperature solid-state reaction under water vapour for synthesis of various electrodes for lithium ions batteries.

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