[논문]Enhanced Morphological Preservation and Redox Activity in Al-Incorporated NiFe2O4 for Chemical Looping Hydrogen Production

Kim, Yikyeom; Lim, Hyun Suk; Lee, Minbeom; Kim, Minkyu; Kang, Dohyung; Lee, Jae W.

doi:10.1021/acssuschemeng.1c04619

[해외논문] Enhanced Morphological Preservation and Redox Activity in Al-Incorporated NiFe2O4 for Chemical Looping Hydrogen Production

ACS sustainable chemistry et engineering, v.9 no.44, 2021년, pp.14800 - 14810

Kim, Yikyeom (Department of Chemical and Biomolecular Engineering , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , Republic of Korea) , Lim, Hyun Suk (Department of Chemical and Biomolecular Engineering , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , Republic of Korea) , Lee, Minbeom (Department of Chemical and Biomolecular Engineering , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , Republic of Korea) , Kim, Minkyu (School of Chemical Engineering , Yeungnam University , 280 Daehak-Ro , Gyeongsan 38541 , Republic of Korea) , Kang, Dohyung (School of Chemical Engineering , Yeungnam University , 280 Daehak-Ro , Gyeongsan 38541 , Republic of Korea) , Lee, Jae W.

Abstract ▼ AI-Helper

Although chemical looping technology has enabled energy-efficient H2 production by combining separation and reaction through the lattice oxygen in oxygen storage materials (OSMs), metal oxides undergoing successive reduction-oxidation cycles generally suffer from a decline in long-term performance. This work investigates an Al-incorporated Ni-ferrite (NiFe2O4) particle to demonstrate a detailed deactivation mechanism induced by redox stress and suggests a strategy to prolong the lifespan of the particle. It is revealed that the grain coalescence and surface densification hamper the redox performance by decreased electrical conductivity and retarded gas transfer, eventually leading to deactivation over the cycles. The formation of a spinel solid solution with aluminum (Al) incorporation was found to be an effective strategy to prevent densification and maintain the long-term performance. Al incorporation at 3.3 wt % is determined as the best particle that can maintain the highest H2 yield (8.2 mmol H2·g-1) and average production rate (0.41 mmol H2·g-1·min-1) for 11 cycles.Al incorporated in the spinel lattice can effectively hinder the deactivation of the particle induced by redox reaction.[FIG OMISSION]

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