$\require{mediawiki-texvc}$

연합인증

연합인증 가입 기관의 연구자들은 소속기관의 인증정보(ID와 암호)를 이용해 다른 대학, 연구기관, 서비스 공급자의 다양한 온라인 자원과 연구 데이터를 이용할 수 있습니다.

이는 여행자가 자국에서 발행 받은 여권으로 세계 각국을 자유롭게 여행할 수 있는 것과 같습니다.

연합인증으로 이용이 가능한 서비스는 NTIS, DataON, Edison, Kafe, Webinar 등이 있습니다.

한번의 인증절차만으로 연합인증 가입 서비스에 추가 로그인 없이 이용이 가능합니다.

다만, 연합인증을 위해서는 최초 1회만 인증 절차가 필요합니다. (회원이 아닐 경우 회원 가입이 필요합니다.)

연합인증 절차는 다음과 같습니다.

최초이용시에는
ScienceON에 로그인 → 연합인증 서비스 접속 → 로그인 (본인 확인 또는 회원가입) → 서비스 이용

그 이후에는
ScienceON 로그인 → 연합인증 서비스 접속 → 서비스 이용

연합인증을 활용하시면 KISTI가 제공하는 다양한 서비스를 편리하게 이용하실 수 있습니다.

Effect of hydro-oleophobic perfluorocarbon chain on interfacial behavior and mechanism of perfluorooctane sulfonate in oil-water mixture 원문보기

Scientific reports, v.7, 2017년, pp.44694 -   

Meng, Pingping (State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University , Beijing, 100084, China) ,  Deng, Shubo (State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University , Beijing, 100084, China) ,  Du, Ziwen (State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University , Beijing, 100084, China) ,  Wang, Bin (State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University , Beijing, 100084, China) ,  Huang, Jun (State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, POPs Research Center, Tsinghua University , Beijing, 100084, China) ,  Wang, Yujue (State Key Joint Laboratory of) ,  Yu, Gang ,  Xing, Baoshan

Abstract AI-Helper 아이콘AI-Helper

Perfluorocarbon chain of perfluorooctane sulfonate (PFOS) is not only hydrophobic but also oleophobic, and its effect on PFOS distribution in oil-water mixture and underlying mechanism are unclear. For the first time, we propose that PFOS can emulsify oil-water mixture only in the presence of air, c...

참고문헌 (41)

  1. Yeung L. W. Y. . Perfluorooctanesulfonate and related fluorochemicals in human blood samples from China . Environ. Sci. Technol. 40 , 715 – 720 ( 2006 ). 16509308 

  2. Hansen K. J. , Clemen L. A. , Ellefson M. E. & Johnson H. O. Compound-specific, quantitative characterization of organic: Fluorochemicals in biological matrices . Environ. Sci. Technol. 35 , 766 – 770 ( 2001 ). 11349290 

  3. D′Eon J. C. & Mabury S. A. Production of perfluorinated carboxylic acids (PFCAs) from the biotransformation of polyfluoroalkyl phosphate surfictants (PAPS): Exploring routes of human contamination . Environ. Sci. Technol. 41 , 4799 – 4805 ( 2007 ). 17695932 

  4. Conder J. M. , Hoke R. A. , De Wolf W. , Russell M. H. & Buck R. C. Are PFCAs bioaccumulative? A critical review and comparison with regulatory lipophilic compounds . Environ. Sci. Technol. 42 , 995 – 1003 ( 2008 ). 18351063 

  5. Scheringer M. . Helsingor statement on poly- and perfluorinated alkyl substances (PFASs) . Chemosphere. 114 , 337 – 9 ( 2014 ). 24938172 

  6. Ng C. A. & Hungerbuhler K. Bioaccumulation of perfluorinated alkyl acids: observations and models . Environ. Sci. Technol. 48 , 4637 – 48 ( 2014 ). 24762048 

  7. Shi Y. . Tissue Distribution and Whole Body Burden of the Chlorinated Polyfluoroalkyl Ether Sulfonic Acid F-53B in Crucian Carp (Carassius carassius): Evidence for a Highly Bioaccumulative Contaminant of Emerging Concern . Environ. Sci. Technol. 49 , 14156 – 14165 ( 2015 ). 26560673 

  8. D′Eon J. C. , Simpson A. J. , Kumar R. , Baer A. J. & Mabury S. A. Determining the molecular interactions of perfluorinated carboxylic acids with human sera and isolated human serum albumin using nuclear magnetic resonance spectroscopy . Environ. Toxicol. Chem. 29 , 1678 – 88 ( 2010 ). 20821619 

  9. Chen M. , Qiang L. , Pan X. , Fang S. , Han Y. & Zhu L. In Vivo and in Vitro Isomer-Specific Biotransformation of Perfluorooctane Sulfonamide in Common Carp (Cyprinus carpio) . Environ. Sci. Technol. 49 , 13817 – 24 ( 2015 ). 26053759 

  10. Han X. , Snow T. A. , Kemper R. A. & Jepson G. W. Binding of perfluorooctanoic acid to rat and human plasma proteins . Chem. Res. Toxicol. 16 , 775 – 781 ( 2003 ). 12807361 

  11. Bischel H. N. , MacManus-Spencer L. A. & Luthy R. G. Noncovalent Interactions of Long-Chain Perfluoroalkyl Acids with Serum Albumin . Environ. Sci. Technol. 44 , 5263 – 5269 ( 2010 ). 20540534 

  12. Hebert P. C. & MacManus-Spencer L. A. Development of a Fluorescence Model for the Binding of Medium- to Long-Chain Perfluoroalkyl Acids to Human Serum Albumin Through a Mechanistic Evaluation of Spectroscopic Evidence . Anal. Chem. 82 , 6463 – 6471 ( 2010 ). 20590160 

  13. Campos R. , Guenthner A. J. , Haddad T. S. & Mabry J. M. Fluoroalkyl-functionalized silica particles: synthesis, characterization, and wetting characteristics . Langmuir 27 , 10206 – 15 ( 2011 ). 21728328 

  14. Zhu X. , Loo H.-E. & Bai R. A novel membrane showing both hydrophilic and oleophobic surface properties and its non-fouling performances for potential water treatment applications . J. Membrane Sci. 436 , 47 – 56 ( 2013 ). 

  15. Cansoy C. E. & Cengiz U. The effect of perfluoroalkyl and hydrocarbon liquid chain lengths on oleophobic behaviors of copolymer surfaces . Colloid. Surface. A 441 , 695 – 700 ( 2014 ). 

  16. Coclite A. M. , Shi Y. & Gleason K. K. Grafted crystalline poly-perfluoroacrylate structures for superhydrophobic and oleophobic functional coatings . Adv. Mater. 24 , 4534 – 9 ( 2012 ). 22786672 

  17. Deng X. , Mammen L. , Butt H. J. & Vollmer D. Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating . Science 335 , 67 – 70 ( 2012 ). 22144464 

  18. Tuteja A. . Designing superoleophobic surfaces . Science 318 , 1618 – 1622 ( 2007 ). 18063796 

  19. Du Z. W. . Adsorption behavior and mechanism of perfluorinated compounds on various adsorbents-A review . J. Hazard. Mater. 274 , 443 – 454 ( 2014 ). 24813664 

  20. Yu Q. , Zhang R. , Deng S. , Huang J. & Yu G. Sorption of perfluorooctane sulfonate and perfluorooctanoate on activated carbons and resin: Kinetic and isotherm study . Water Res. 43 , 1150 – 8 ( 2009 ). 19095279 

  21. Deng S. B. . Enhanced adsorption of perfluorooctane sulfonate and perfluorooctanoate by bamboo-derived granular activated carbon . J. Hazard. Mater. 282 , 150 – 157 ( 2015 ). 24721493 

  22. Higgins C. P. & Luthy R. G. Sorption of perfluorinated surfactants on sediments . Environ. Sci. Technol. 40 , 7251 – 7256 ( 2006 ). 17180974 

  23. Ahrens L. . Partitioning Behavior of Per- and Polyfluoroalkyl Compounds between Pore Water and Sediment in Two Sediment Cores from Tokyo Bay, Japan . Environ. Sci. Technol. 43 , 6969 – 6975 ( 2009 ). 19806729 

  24. Guelfo J. L. & Higgins C. P. Subsurface transport potential of perfluoroalkyl acids at aqueous film-forming foam (AFFF)-impacted sites . Environ. Sci. Technol. 47 , 4164 – 71 ( 2013 ). 23566120 

  25. McMurdo C. J. , Ellis D. A. , Webster E. , Butler J. , Christensen R. D. & Reid L. K. Aerosol enrichment of the surfactant PFO and mediation of the water - Air transport of gaseous PFOA . Environ. Sci. Technol. 42 , 3969 – 3974 ( 2008 ). 18589953 

  26. Stone M. T. , da Rocha S. R. P. , Rossky P. J. & Johnston K. P. Molecular differences between hydrocarbon and fluorocarbon Surfactants at the CO 2 /water interface . J. Phys. Chem. B 107 , 10185 – 10192 ( 2003 ). 

  27. Dickson J. L. . Interfacial properties of fluorocarbon and hydrocarbon phosphate surfactants at the water-CO 2 interface . Ind. Eng. Chem. Res. 44 , 1370 – 1380 ( 2005 ). 

  28. Eastoe J. , Paul A. , Downer A. , Steytler D. C. & Rumsey E. Effects of fluorocarbon surfactant chain structure on stability of water-in-carbon dioxide microemulsions. Links between aqueous surface tension and microemulsion stability . Langmuir 18 , 3014 – 3017 ( 2002 ). 

  29. Meng P. P. . Role of air bubbles overlooked in the adsorption of perfluorooctanesulfonate on hydrophobic carbonaceous adsorbents . Environ. Sci. Technol. 48 , 13785 – 92 ( 2014 ). 25365738 

  30. Hawker D. W. & Connell D. W. , Octanol Water Partition-Coefficients of Polychlorinated Biphenyl Congeners . Environ. Sci. Technol. 22 , 382 – 387 ( 1988 ). 

  31. Levin V. A. Relationship of Octanol-Water Partition-Coefficient and Molecular-Weight to Rat-Brain Capillary-Permeability . J. Med. Chem. 23 , 682 – 684 ( 1980 ). 7392035 

  32. Ju X. D. , Jin Y. H. , Sasaki K. & Saito N. Perfluorinated surfactants in surface, subsurface water and microlayer from Dalian Coastal waters in China . Environ. Sci. Technol. 42 , 3538 – 3542 ( 2008 ). 18546686 

  33. Zhou Q. , Deng S. B. , Zhang Q. Y. , Fan Q. , Huang J. & Yu G. Sorption of perfluorooctane sulfonate and perfluorooctanoate on activated sludge . Chemosphere 81 , 453 – 458 ( 2010 ). 20797760 

  34. Deng S. B. . Effect of co-existing organic compounds on adsorption of perfluorinated compounds onto carbon nanotubes . Front. Env. Sci. Eng. 9 , 784 – 792 ( 2015 ). 

  35. Tang C. Y. Y. , Fu Q. S. , Robertson A. P. , Criddle C. S. & Leckie J. O. Use of reverse osmosis membranes to remove perfluorooctane sulfonate (PFOS) from semiconductor wastewater . Environ. Sci. Technol. 40 , 7343 – 7349 ( 2006 ). 17180987 

  36. Du Z. W. . Efficient adsorption of PFOS and F53B from chrome plating wastewater and their subsequent degradation in the regeneration process . Chem. Eng. J. 290 , 405 – 413 ( 2016 ). 

  37. Moody C. A. , Martin J. W. , Kwan W. C. , Muir D. C. G. & Mabury S. C. Monitoring perfluorinated surfactants in biota and surface water samples following an accidental release of fire-fighting foam into Etobicoke Creek . Environ. Sci. Technol. 36 , 545 – 551 ( 2002 ). 11883418 

  38. Schwarzenbach R. P. , Gschwend P. M. & Imboden D. M. Environmental organic chemistry: Activity coefficient and solubility in water . 2nd Ed. John Wiley & Sons, New York ( 2003 ). 

  39. Ysambertt F. , Anton R. & Salager J. L. Retrograde transition in the phase behaviour of surfactant-oil-water systems produced by an oil equivalent alkane carbon number scan . Colloid. Surface. A 125 , 131 – 136 ( 1997 ). 

  40. Wade W. H. , Morgan J. C. , Jacobson J. K. & Schechter R. S. Low interfacial-tensions involving mixtures of surfactants . Soc. Petrol. Eng. J. 17 , 122 – 128 ( 1977 ). 

  41. Craft N. E. & Soares J. H. Relative solubility, stability, and absorptivity of lutein and.beta.-carotene in organic solvents . J. Agr. Food Chem. 40 , 431 – 434 ( 1992 ). 

관련 콘텐츠

오픈액세스(OA) 유형

GOLD

오픈액세스 학술지에 출판된 논문

저작권 관리 안내
섹션별 컨텐츠 바로가기

AI-Helper ※ AI-Helper는 오픈소스 모델을 사용합니다.

AI-Helper 아이콘
AI-Helper
안녕하세요, AI-Helper입니다. 좌측 "선택된 텍스트"에서 텍스트를 선택하여 요약, 번역, 용어설명을 실행하세요.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.

선택된 텍스트

맨위로