[논문]Improved Separation of Pa from Th and U in Marine Sediments with TK400 Resin

Sü; fke, Finn; Lippold, Jö; rg; Happel, Steffen

doi:10.1021/acs.analchem.7b04723

Improved Separation of Pa from Th and U in Marine Sediments with TK400 Resin

Analytical chemistry, v.90 no.2, 2018년, pp.1395 - 1401

Süfke, Finn (Institute of Earth Science, Heidelberg University, Im Neuenheimer Feld 234, 69120 Heidelberg,) , Lippold, Jörg (Institute of Earth Science, Heidelberg University, Im Neuenheimer Feld 234, 69120 Heidelberg,) , Happel, Steffen (TrisKem International, 3 rue des champs Geons, 35170 Bruz,)

Abstract ▼ AI-Helper

Protactinium-231 is a radionuclide of broad interest in paleoceanography and paleoclimatology. This study describes an improved method for the purification and separation of Pa from marine sediment samples using the new TK400 resin by TrisKem International. The focus lies on the improvement of the separation of the abundant 232Th from the Pa fraction of the sample, which would reduce the peak tailing from 232Th on masses 231 and 233 during ICP-MS measurement. Furthermore, the reusability of TK400 has been tested. For this purpose, the conventional method using Dowex AG1X8 for the separation and purification of Pa has been compared to methods using the TK400 resin. A combination of a Dowex AG1X8 prior to a TK400 column has shown most convincing results. Based on our results we suggest a new efficient procedural method of analyzing 231Pa from marine sediment samples using TK400. Chemical Pa yields for a Dowex-TK400 combination are highest compared to the Dowex only method. Furthermore, the 232Th/231Pa ratio of the Pa-fractions has been reduced by 1 order of magnitude compared to conventional methods with Dowex AG1X8. Additionally, the reusability of TK400 resin up to nine times has been proven. The usage of TK400 is only limited in the presence of samples with a high matrix load (e.g., Fe). Therefore, matrix from sediment samples needs to be removed (here using Dowex resin) before samples are loaded onto TK400. We also report a series of concentration measurements from standard reference materials (UREM-11, NIST 2702), which have been used for 233Pa calibration.Graphic AbstractACS Electronic Supporting Info

참고문헌 (39)

Francois, Roger, Frank, Martin, Rutgers van der Loeff, Michiel M., Bacon, Michael P.. ²³⁰Th normalization: An essential tool for interpreting sedimentary fluxes during the late Quaternary. Paleoceanography, vol.19, no.1, 2003PA000939-.

상세보기
Not, Christelle, Hillaire-Marcel, Claude. Time constraints from ²³⁰Th and ²³¹Pa data in late Quaternary, low sedimentation rate sequences from the Arctic Ocean: an example from the northern Mendeleev Ridge. Quaternary science reviews, vol.29, no.25, 3665-3675.

상세보기
Walter, H.J., Rutgers van der Loeff, M.M., Hoeltzen, H.. Enhanced scavenging of ²³¹Pa relative to ²³⁰Th in the South Atlantic south of the Polar Front: Implications for the use of the ²³¹Pa/²³⁰Th ratio as a paleoproductivity proxy. Earth and planetary science letters, vol.149, no.1, 85-100.

상세보기
Christl, Marcus, Lippold, Jörg, Hofmann, Alexander, Wacker, Lukas, Lahaye, Yann, Synal, Hans-Arno. ²³¹Pa/²³⁰Th: A proxy for upwelling off the coast of West Africa. Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, vol.268, no.7, 1159-1162.

상세보기
Anderson, R.F., Bacon, M.P., Brewer, P.G.. Removal of ²³⁰Th and ²³¹Pa at ocean margins. Earth and planetary science letters, vol.66, 73-90.

상세보기
Yu, Ein-Fen, Francois, Roger, Bacon, Michael P.. Similar rates of modern and last-glacial ocean thermohaline circulation inferred from radiochemical data. Nature, vol.379, no.6567, 689-694.

상세보기
McManus, J. F., Francois, R., Gherardi, J.-M., Keigwin, L. D., Brown-Leger, S.. Collapse and rapid resumption of Atlantic meridional circulation linked to deglacial climate changes. Nature, vol.428, no.6985, 834-837.

상세보기
Lippold, J., Gutjahr, M., Blaser, P., Christner, E., de Carvalho Ferreira, M.L., Mulitza, S., Christl, M., Wombacher, F., Bohm, E., Antz, B., Cartapanis, O., Vogel, H., Jaccard, S.L.. Deep water provenance and dynamics of the (de)glacial Atlantic meridional overturning circulation. Earth and planetary science letters, vol.445, 68-78.

상세보기
Shen, C.-C., Cheng, H., Edwards, R. L., Moran, S. B., Edmonds, H. N., Hoff, J. A., Thomas, R. B.. Measurement of Attogram Quantities of ²³¹Pa in Dissolved and Particulate Fractions of Seawater by Isotope Dilution Thermal Ionization Mass Spectroscopy. Analytical chemistry, vol.75, no.5, 1075-1079.

상세보기
Christl, M., Wacker, L., Lippold, J., Synal, H.A., Suter, M.. Protactinium-231: A new radionuclide for AMS. Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, vol.262, no.2, 379-384.

상세보기
Regelous, M., Turner, S. P., Elliott, T. R., Rostami, K., Hawkesworth, C. J.. Measurement of Femtogram Quantities of Protactinium in Silicate Rock Samples by Multicollector Inductively Coupled Plasma Mass Spectrometry. Analytical chemistry, vol.76, no.13, 3584-3589.

상세보기
Holden, N. E.. Total half-lives for selected nuclides. Pure and applied chemistry. : Chimie pure et appliqueé, vol.62, no.5, 941-958.

상세보기
Lawrence Edwards, R., Chen, J.H., Wasserburg, G.J.. ²³⁸U?²³⁴U?²³⁰Th?²³²Th systematics and the precise measurement of time over the past 500,000 years. Earth and planetary science letters, vol.81, no.2, 175-192.

상세보기
Anderson, Robert F., Fleer, Alan P.. Determination of natural actinides and plutonium in marine particulate material. Analytical chemistry, vol.54, no.7, 1142-1147.

상세보기
Negre, César, Thomas, Alexander L., Mas, José Luis, Garcia-Orellana, Jordi, Henderson, Gideon M., Masqué, Pere, Zahn, Rainer. Separation and Measurement of Pa, Th, and U Isotopes in Marine Sediments by Microwave-Assisted Digestion and Multiple Collector Inductively Coupled Plasma Mass Spectrometry. Analytical chemistry, vol.81, no.5, 1914-1919.

상세보기
Bourdon, Bernard, Joron, Jean-Louis, Allègre, Claude J.. A method for ²³¹Pa analysis by thermal ionization mass spectrometry in silicate rocks. Chemical geology, vol.157, no.1, 147-151.

상세보기
Aciego, S.M., Bourdon, B., Lupker, M., Rickli, J.. A new procedure for separating and measuring radiogenic isotopes (U, Th, Pa, Ra, Sr, Nd, Hf) in ice cores. Chemical geology, vol.266, no.3, 194-204.

상세보기
Morgenstern, A., Apostolidis, C., Mayer, K.. Age Determination of Highly Enriched Uranium: Separation and Analysis of ²³¹Pa. Analytical chemistry, vol.74, no.21, 5513-5516.

상세보기
Knight, A.W., Eitrheim, E.S., Nelson, A.W., Nelson, S., Schultz, M.K.. A simple-rapid method to separate uranium, thorium, and protactinium for U-series age-dating of materials. Journal of environmental radioactivity, vol.134, 66-74.

상세보기
Kretschmer, S., Geibert, W., Rutgers van der Loeff, M.M., Schnabel, C., Xu, S., Mollenhauer, G.. Fractionation of ²³⁰Th, ²³¹Pa, and ¹⁰Be induced by particle size and composition within an opal-rich sediment of the Atlantic Southern Ocean. Geochimica et cosmochimica acta, vol.75, no.22, 6971-6987.

상세보기
Guihou, A., Pichat, S., Nave, S., Govin, A., Labeyrie, L., Michel, E., Waelbroeck, C.. Late slowdown of the Atlantic Meridional Overturning Circulation during the Last Glacial Inception: New constraints from sedimentary (²³¹Pa/²³⁰Th). Earth and planetary science letters, vol.289, no.3, 520-529.

상세보기
Auro, Maureen E., Robinson, Laura F., Burke, Andrea, Bradtmiller, Louisa I., Fleisher, Martin Q., Anderson, Robert F.. Improvements to 232‐thorium, 230‐thorium, and 231‐protactinium analysis in seawater arising from GEOTRACES intercalibration. Limnology and oceanography, methods, vol.10, no.7, 464-474.

상세보기
Anderson, Robert F., Fleisher, Martin Q., Robinson, Laura F., Edwards, R. Lawrence, Hoff, John A., Moran, S. Bradley, van der Loeff, Michiel Rutgers, Thomas, Alexander L., Roy‐Barman, Matthieu, Francois, Roger. GEOTRACES intercalibration of ²³⁰Th, ²³²Th, ²³¹Pa, and prospects for ¹⁰Be. Limnology and oceanography, methods, vol.10, no.4, 179-213.

상세보기
Knight, Andrew W., Nelson, Andrew W., Eitrheim, Eric S., Forbes, Tori Z., Schultz, Michael K.. A chromatographic separation of neptunium and protactinium using 1-octanol impregnated onto a solid phase support. Journal of radioanalytical and nuclear chemistry, vol.307, no.1, 59-67.

상세보기
Jerome, S.M., Collins, S.M., Happel, S., Ivanov, P., Russell, B.C.. Isolation and purification of protactinium-231. Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry, and medicine, vol.134, 18-22.

상세보기
Lippold, J., Mulitza, S., Mollenhauer, G., Weyer, S., Heslop, D., Christl, M.. Boundary scavenging at the East Atlantic margin does not negate use of ²³¹Pa/²³⁰Th to trace Atlantic overturning. Earth and planetary science letters, vol.333, 317-331.

상세보기
Usman, K., MacMahon, T.D.. Determination of the half-life of ²³³Pa. Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry, and medicine, vol.52, no.3, 585-589.

상세보기
Fietzke, J, Bollhöfer, A, Frank, N, Mangini, A. Protactinium determination in manganese crust VA13/2 by thermal ionization mass spectrometry (TIMS). Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, vol.149, no.3, 353-360.

상세보기
Geibert, W., Voge, I.. Progress in the determination of ²²⁷Ac in sea water. Marine chemistry, vol.109, no.3, 238-249.

상세보기
Hansen, R. G.; Ring, E. J.The preparation and certification of a uranium reference material.Mintek Report, M84,Randburg, 1983.
Anderson, R. F., Ali, S., Bradtmiller, L. I., Nielsen, S. H. H., Fleisher, M. Q., Anderson, B. E., Burckle, L. H.. Wind-Driven Upwelling in the Southern Ocean and the Deglacial Rise in Atmospheric CO ₂. Science, vol.323, no.5920, 1443-1448.

상세보기
Asmus, T., Frank, M., Koschmieder, C., Frank, N., Gersonde, R., Kuhn, G., Mangini, A.. Variations of biogenic particle flux in the southern Atlantic section of the Subantarctic Zone during the late Quaternary: Evidence from sedimentary ²³¹Paex and ²³⁰Thex. Marine geology, vol.159, no.1, 63-78.

상세보기
https://nemo.nist.gov/srmors/view_detail.cfm?srm=2702.
Matteson, B.S., Hanson, S.K., Miller, J.L., Oldham, W.J.. Concurrent determination of ²³⁷Np and Pu isotopes using ICP-MS: analysis of NIST environmental matrix standard reference materials 4357, 1646a, and 2702. Journal of environmental radioactivity, vol.142, 62-67.

상세보기
Bourne, Mark D., Thomas, Alex L., Mac Niocaill, Conall, Henderson, Gideon M.. Improved determination of marine sedimentation rates using ²³⁰Th_xs. Geochemistry, geophysics, geosystems : G³, vol.13, no.9, 2012GC004295-.

상세보기
Henderson, G. M.. The U-series Toolbox for Paleoceanography. Reviews in mineralogy and geochemistry, vol.52, no.1, 493-531.

상세보기
Choi, M.S, Francois, R, Sims, K, Bacon, M.P, Brown-Leger, S, Fleer, A.P, Ball, L, Schneider, D, Pichat, S. Rapid determination of ²³⁰Th and ²³¹Pa in seawater by desolvated micro-nebulization Inductively Coupled Plasma magnetic sector mass spectrometry. Marine chemistry, vol.76, no.1, 99-112.

상세보기
Guihou, Abel, Pichat, Sylvain, Govin, Aline, Nave, Silvia, Michel, Elisabeth, Duplessy, Jean-Claude, Telouk, Philippe, Labeyrie, Laurent. Enhanced Atlantic Meridional Overturning Circulation supports the Last Glacial Inception. Quaternary science reviews, vol.30, no.13, 1576-1582.

상세보기
Böhm, E., Lippold, J., Gutjahr, M., Frank, M., Blaser, P., Antz, B., Fohlmeister, J., Frank, N., Andersen, M. B., Deininger, M.. Strong and deep Atlantic meridional overturning circulation during the last glacial cycle. Nature, vol.517, no.7532, 73-76.

상세보기

표제어: PCR

동의어: Packet Collision Rate

용어 설명 출처 목록 (6)

용어 설명: PCR은 세균 특이성이 있는 primer를 이용하여 적은 수의 세균이 있을지라도 쉽게 검출할 수 있는 유용한 방법이며, 이를 이용하여 구강 내 치면세균막이나 타액에서 직접 세균을 검출할 수 있게 되었다[8].

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증

Improved Separation of Pa from Th and U in Marine Sediments with TK400 Resin

Abstract ▼ AI-Helper

참고문헌 (39)

이 논문을 인용한 문헌

AI-Helper ※ AI-Helper는 오픈소스 모델을 사용합니다.

선택된 텍스트