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Synthesis of Arenesulfonyl Fluorides via Sulfuryl Fluoride Incorporation from Arynes

Organic letters, v.21 no.2, 2019년, pp.428 - 433  

Kwon, Jungmin (Department of Chemistry, College of Natural Sciences , Seoul National University , 1 Gwanak-ro , Gwanak-gu, Seoul 08826 , Republic of Korea) ,  Kim, B. Moon

Abstract AI-Helper 아이콘AI-Helper

Transition-metal-free multicomponent reactions involving aryne precursors, secondary amines, and sulfuryl fluoride are reported herein. Zwitterionic intermediates formed from the reaction of arynes with amine nucleophiles can capture SO2F2 under mild conditions, offering a novel and practical protoc...

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