[논문]Amount concentration of Ar in O2 obtained by means of thermal analysis of certified mixtures at the α–β transition of O2, and preliminary confirmation of a new finding

Steur, Peter P.M.; Yang, Inseok; Giraudi, Domenico; Pavese, Franco

doi:10.1016/j.jct.2019.105934

[해외논문] Amount concentration of Ar in O2 obtained by means of thermal analysis of certified mixtures at the α–β transition of O2, and preliminary confirmation of a new finding

The Journal of chemical thermodynamics, v.141, 2020년, pp.105934 -

Steur, Peter P.M. (Istituto Nazionale di Ricerca Metrologica (INRiM)) , Yang, Inseok (Korea Research Institute of Standards and Science) , Giraudi, Domenico (Istituto Nazionale di Ricerca Metrologica (INRiM)) , Pavese, Franco (Independent Scientist)

Abstract ▼ AI-Helper

Abstract For the first time, high-precision measurements were performed on the temperature of the α–β transition of oxygen, both pure and affected by different amount concentrations of Ar impurity up to an amount concentration x(Ar) ≈ 1·10−3 mol. The aim of this study was to find an accurate way to detect the amount concentration of argon in oxygen, which affects the triple point temperature of oxygen, previously without another possibility to determine it accurately (except with the 10-times less sensitive β–γ transition of oxygen). It was found that the influence on the α–β transition temperature is strong, with a maximum value at no supplied power of T tr,0 = 23.894 85 K, with a standard uncertainty u(T tr,0) = 60 μK, and a first derivative for nearly null amount concentration of 133.9 μK/10−6 mol Ar, with a standard uncertainty of 0.4 μK/10−6 mol Ar, allowing to detect an impurity of x(Ar) = 1·10−6 mol corresponding to an accuracy in temperature measurement of ≈100 μK. The correction equation is provided up to an amount concentration x(Ar) ≈ 1·10−3 mol, where the sensitivity to argon amount concentration is about half. In the course of this study, confirmation was found of previous findings of an unknown weak apparent transition occurring in oxygen (pure or containing up to x(Ar) ≈ 1·10−3 mol) just below the known α–β one by less than 0.1 K. Highlights Production of gravimetrically prepared artificial mixtures of Argon in Oxygen at KRISS. Experimental determination at INRIM of the effect of Argon Content on the triple point temperature of Oxygen. Measurements at the α–β solid-solid transition of Oxygen.

Keyword

참고문헌 (36)

Metrologia Pavese 46 47 2009 10.1088/0026-1394/46/1/007 Critical review of information relevant to the correction of the effect of chemical impurities in gases used for the realization of ITS-90 fixed points

상세보기
Metrologia Pavese 48 268 2011 10.1088/0026-1394/48/5/005 Methods for the assessment of correction for chemical-impurity effects and related uncertainty in ITS-90 fixed points, namely of e-H2, Ne, O2 and Ar

상세보기
Accred. Qual. Assur. Shimosaka 22 5 281 2017 10.1007/s00769-017-1279-3 Development of primary standard gas mixtures containing 10 μmol/mol oxygen in nitrogen with verification by a two-oven GC-TCD system for effective separation of oxygen from argon in presence of plenty of nitrogen

상세보기
F. Pavese, Final Report of the International Intercomparison of fixed points by means of sealed cells: 13.81 K to 90.686 K, Monograph 84/4 of Bureau International des Poids et Mesures, BIPM Sèvres (1984), pp. 219
10.1088/0026-1394/20/4/002 F. Pavese, J. Ancsin, D.N. Astrov, J. Bonhoure, G. Bonnier, G.T. Furukawa, R.C. Kemp, H. Maas, R.L. Rusby, H. Sakurai, Ling Shankang, An International Intercomparison of fixed points by means of sealed cells in the range 13.81 K to 90.686 K, Metrologia 20 (1984), 127-144.

상세보기
Adv. Cryo. Eng. Pavese 33 1039 1988 Evidence of unreliability of factory analyses of argon impurity in oxygen
Pavese vol 6 251 1992 Long-term stability of permanent realizations of the triple point of gases in metal sealed cells
F. Pavese, G.F. Molinar, Modern gas-based temperature and pressure measurements, International Monograph Series on Cryogenic Engineering, Plenum Publ.Co., New York, 1st Edition (1992) and 2nd Edition (2012), pp.520.
C. Rhee, D. Chi, K.H. Kang, K.S. Gam, Y.G. Kim, J.W. Hahn, S.N, Park, Document CCT/93-31.
Szmyrka-Grzebyk 1552 204 2013 The β - γ transition of oxygen as secondary fixed point
IJOT Steur 38 2 20 2017 Evidence for argon content in pure oxygen from thermal data
10.1007/s10765-019-2582-5 P.P.M. Steur, Inseok Yang, F. Pavese, The effect of argon content on the β-γ transition of oxygen, TEMPMEKO 2019, June 2019, ChengDu, China, submitted to International Journal of Thermophysics.

상세보기
Pavese 217 1982 Ten years of research on sealed cells for phase transition studies of gases at IMGC
Cryogenics Lipiński 36 921 1996 10.1016/S0011-2275(96)00074-4 Hysteresis effect in the α-β transition of solid oxygen

상세보기
Szmyrka-Grzebyk 105 1997 Proc Tempmeko Evidence of anomalies in the solid-solid phase transitions of solid oxygen and impurity detection
J. Low Temp. Phys. Szmyrka-Grzebyk 111 399 1998 10.1023/A:1022248006071
A. Szmyrka-Grzebyk, L. Lipinski, H. Manuszkiewicz, A. Kowal, P.P.M. Steur, 2nd International Seminar and Workshop on Low-Temperature Thermometry, Wroclaw (2003), 119-125.
10.1063/1.3117963 A. Szmyrka-Grzebyk, A. Kowal, Fizika Nizkich Temperatur (in Polish), 35 (4) 2009, 427-432.

상세보기
Metrologia Pavese 14 93 1978 10.1088/0026-1394/14/3/001 The triple point of argon and oxygen

상세보기
Pavese 167 2003 Temperature, Its Measurement and Control in Science and Industry Century stable cryogenic temperature fixed points: problems solved and problems to be solved
Metrologia Pavese 47 499 2010 10.1088/0026-1394/47/5/001 Comparison with U ≈ 50 μK of neon samples of different isotopic composition

상세보기
Pavese 161 2003 Temperature, Its Measurement and Control in Science and Industry “MULTICELLS”: A European Project on Cryogenic Temperature Fixed Points in Sealed Cells
Int. J. Thermophys. Fellmuth 32 161 2010 10.1007/s10765-010-0883-9 Investigation on the parameters of sealed triple-point cells for cryogenic gases

상세보기
Metrologia Fellmuth 42 171 2005 10.1088/0026-1394/42/4/001 Isotopic and other influences on the realization of the triple point of hydrogen

상세보기
F. Pavese, I. Peroni, F. Sparasci, P.P.M. Steur, D. Ferri and A. Pugliese, A closed-cycle refrigerator for realizing low temperature fixed points, In: 2nd International Seminar and Workshop on Low-Temperature Thermometry (2003), Wroclaw, 102-107.
Metrologia Steur 56 2019 10.1088/1681-7575/aaee3a Comparison of xenon triple point realizations

상세보기
Pavese 1552 192 2013 Dependence of the triple point temperature of neon on isotopic composition and its implications for the ITS-90
J. Low Temp. Phys. Fagerstroem 1 3 1969 10.1007/BF00628329 The specific heat of solid oxygen

상세보기
Phys. Rep. Freiman 401 165 2004 10.1016/j.physrep.2004.06.002 Solid oxygen

상세보기
J. Res. Nat. Bur. Standards Hoge 44 321 1950 10.6028/jres.044.029 Vapor pressure and fixed points of oxygen and heat capacity in the critical region

상세보기
Physica Muijlwijk 43 475 1969 10.1016/0031-8914(69)90179-7 The temperatures of the transition points in oxygen

상세보기
Kemp 4 217 1972 Temperature, its Measurement and Control in Science and Industry The transition temperatures of solid oxygen
Phys. Conf. Series Ancsin 26 57 1975 Crystalline transformation of oxygen
Metrologia Bedford 33 133 1996 10.1088/0026-1394/33/2/3 Recommended values of temperature on the International Temperature Scale of 1990 for a selected set of secondary reference points

상세보기
Metrologia Ancsin 1973 10.1088/0026-1394/9/1/007 Dew point, boiling points and triple points of “pure” and impure oxygen

상세보기
Metrologia Compton 12 101 1976 10.1088/0026-1394/12/3/003 Realization of the boiling and triple points of oxygen

상세보기

LOADING...

활용도 분석정보

상세보기

다운로드

내보내기

활용도 Top5 논문

해당 논문의 주제분야에서 활용도가 높은 상위 5개 콘텐츠를 보여줍니다.
더보기 버튼을 클릭하시면 더 많은 관련자료를 살펴볼 수 있습니다.

내보내기 구분	파일저장 인쇄 메일전송
구성항목	기본정보 상세정보 관리번호, 논문명, 저널/프로시딩명, 저자 , 발행년, 권, 호, 시작페이지, 끝페이지, 발행기관 관리번호, 논문명, 대등논문명, 저자 , 저널/프로시딩명, 발행기관, 발행년, 발행언어, 권, 호, 시작페이지, 끝페이지, ISBN, ISSN, 주제분야, 키워드, 초록(한글), 초록(영문), 저자(소속기관)
저장형식	Text(ASCII format) Excel format RefWorks Direct Export RIS format (for Reference Manager, ProCite, EndNote), Scholar's Aids, Mendeley
메일정보	받는사람 (필수) @ 보내는사람 (선택) @ 제목 내용 KISTI 검색결과 이메일 서비스
안내	총 건의 자료가 검색되었습니다. 다운받으실 자료의 인덱스를 입력하세요. (1-10,000) 검색결과의 순서대로 최대 10,000건 까지 다운로드가 가능합니다. 데이타가 많을 경우 속도가 느려질 수 있습니다.(최대 2~3분 소요) 다운로드 파일은 UTF-8 형태로 저장됩니다. 파일의 내용이 제대로 보이지 않을실 때는 웹브라우저 상단의 보기 -> 인코딩 -> 자동선택 여부를 확인하십시오. ~ Text(ASCII format) Excel format

연합인증

[해외논문] Amount concentration of Ar in O2 obtained by means of thermal analysis of certified mixtures at the α–β transition of O2, and preliminary confirmation of a new finding

Abstract ▼ AI-Helper

Keyword

참고문헌 (36)

이 논문을 인용한 문헌

연구과제 타임라인

활용도 분석정보

활용도 Top5 논문

관련 콘텐츠

원문 URL 링크

AI-Helper ※ AI-Helper는 오픈소스 모델을 사용합니다.

선택된 텍스트

연합인증

[해외논문] Amount concentration of Ar in O2 obtained by means of thermal analysis of certified mixtures at the α–β transition of O2, and preliminary confirmation of a new finding

Abstract ▼ AI-Helper

Keyword

참고문헌 (36)

이 논문을 인용한 문헌

연구과제 타임라인

전체(0) 논문(0) 특허(0) 보고서(0)

전체(0) 논문(0) 특허(0) 보고서(0)

활용도 분석정보

활용도 Top5 논문 더보기

관련 콘텐츠

원문 URL 링크

AI-Helper ※ AI-Helper는 오픈소스 모델을 사용합니다.

선택된 텍스트

활용도 Top5 논문