[논문]Additive-promoted hypergolic ignition of ionic liquid with hydrogen peroxide

Bhosale, Vikas K.; Jeong, Junyeong; Choi, Jonghoon; Churchill, David G.; Lee, Yunho; Kwon, Sejin

doi:10.1016/j.combustflame.2020.01.013

[해외논문] Additive-promoted hypergolic ignition of ionic liquid with hydrogen peroxide

Combustion and flame, v.214, 2020년, pp.426 - 436

Bhosale, Vikas K. (Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology, KAIST) , Jeong, Junyeong (Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology, KAIST) , Choi, Jonghoon (Department of Chemistry, Korea Advanced Institute of Science and Technology, KAIST) , Churchill, David G. (Department of Chemistry, Korea Advanced Institute of Science and Technology, KAIST) , Lee, Yunho (Department of Chemistry, Korea Advanced Institute of Science and Technology, KAIST) , Kwon, Sejin (Department of Aerospace Engineering, Korea Advanced Institute of Science and Technology, KAIST)

Abstract ▼ AI-Helper

Abstract The exploration of environmentally friendly hypergolic combinations of ionic liquid fuels and hydrogen peroxide as an oxidizer offers opportunities to replace commonly used conventional toxic, corrosive and carcinogenic hydrazine-based liquid hypergolic combinations. Various research opportunities await regarding the detailed investigations of green hypergolic ionic liquids (HILs) with rocket grade hydrogen peroxide (RGHP, >85% H2O2). In this work, the combustion of HILs 1-ethyl-3-methyl imidazolium cyanoborohydride ([EMIM][BH3CN]) and 1-allyl-3-ethyl imidazolium cyanoborohydride ([AEIM][BH3CN]), and HIL-additive mixtures with 95% H2O2 has been investigated. A new additive, 1,3-dimethyl imidazolium copper iodide ([diMIM] n [Cu2I3] n ) was synthesized successfully; a structural investigation was performed through the use of single-crystal x-ray diffraction analysis through which a crystal density of 3.22 g/cm3 was revealed. The physicochemical properties (density, viscosity, and decomposition temperature) as well as performance parameters (ignition delay and specific impulse) of 2 to 15 wt% of [diMIM] n [Cu2I3] n in [EMIM][BH3CN] were determined. A 15 wt% of [diMIM] n [Cu2I3] n exhibited ignition delay time (IDT) values of 13 and 29 ms under fuel-rich and oxidizer-rich conditions, respectively; these IDT values are 100 times lower than those for [EMIM][BH3CN]. Interestingly, [diMIM] n [Cu2I3] n -[EMIM][BH3CN] combinations revealed high density (>0.98 g/cm3), good thermal (>200 °C) and chemical stability, and 5.6–6.0% higher density specific impulse than those found for unsymmetrical dimethyl hydrazine. The additive-promoted hypergolic combustion of HIL with RGHP opens a new avenue to the replacement of conventional toxic hypergolic combinations.

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참고문헌 (49)

Clark 1972 IGNITION ! An informal histroy of liquid propellants
Suttan 2001 Rocket propulsion elements
Kit 1960 Rocket propellant handbook
Silverman 301 1969 10.1021/ba-1969-0088.ch011 Advances in Chemistry Current liquid propellant systems
Arch. Environ. Health Int. J. Reinhardt 10 859 1965 10.1080/00039896.1965.10664110 Toxicity of hydrazine and 1,1-dimethylhydrazine (UDMH)

상세보기
Fundam. Appl. Toxicol. Vernot 5 1050 1985 10.1016/0272-0590(85)90141-1 Long-term inhalation toxicity of hydrazine

상세보기
A.A. Thomas, Proceedings of the ninth conference on environmental toxicity, AMRL-TR-79-68, 1979.
Russ. Chem. Bull. Int. Ed. Guseinov 67 1943 2018 10.1007/s11172-018-2314-1 Hypergolic propellants based on hydrogen peroxide and organic compounds: historical aspect and current state

상세보기
Combust. Flame Sun 205 441 2019 10.1016/j.combustflame.2019.04.033 Hypergolicity evaluation and prediction of ionic liquids based on hypergolic reactive groups

상세보기
Fuel Bhosale 255 2019 10.1016/j.fuel.2019.115729 Ignition of boron-based green hypergolic fuels with hydrogen peroxide

상세보기
Fuel Li 215 612 2018 10.1016/j.fuel.2017.10.091 The ignition process measurements and performance evaluations for hypergolic ionic liquid fuels: [EMIm][DCA] and [BMIm][DCA]

상세보기
Acta Astronaut. Stovbun 135 110 2017 10.1016/j.actaastro.2016.11.047 Synthesis and testing of hypergolic ionic liquids for chemical propulsion

상세보기
Chem. Rev. Zhang 114 10527 2014 10.1021/cr500364t Energetic ionic liquids as explosives and propellant fuels : a new journey of ionic liquid chemistry

상세보기
Wasserscheid 2008 Ionic liquids in synthesis
Chem. Sel. Bhosale 1 1921 2016 Ionic liquid and biofuel blend : a low-cost and high performance hypergolic fuel for propulsion application
Angew. Chem. Int. Ed. Li 53 2969 2014 10.1002/anie.201309044 Borohydride ionic liquids and borane/ionic-liquid solutions as hypergolic fuels with superior low ignition-delay times

상세보기
Chem. A Eur. J. Chand 21 13297 2015 10.1002/chem.201502059 Borohydride ionic liquids as hypergolic fuels: a quest for improved stability

상세보기
Angew. Chem. Int. Ed. Li 53 2969 2014 10.1002/anie.201309044 Borohydride ionic liquids and borane/ionic-liquid solutions as hypergolic fuels with superior low ignition-delay times

상세보기
Angew. Chem. Int. Ed. Zhang 50 9554 2011 10.1002/anie.201101954 Ionic liquids as hypergolic fuels

상세보기
Dalton Trans. Wang 48 6198 2019 10.1039/C9DT00958B Synthesis and hypergolic properties of flammable ionic liquids based on the cyano (1H-1,2,3-triazole-1-yl) dihydroborate anion

상세보기
Chem. A Eur. J. Jin 24 4620 2018 10.1002/chem.201705506 Synthesis and properties of triaminocyclopropenium cation based ionic liquids as hypergolic fluids

상세보기
Chem. A Eur. J. Liu 24 10201 2018 10.1002/chem.201801593 Rational design and facile synthesis of boranophosphate ionic liquids as hypergolic rocket fuels

상세보기
New J. Chem. Jiao 43 1127 2019 10.1039/C8NJ04676J IL-oxidizer/IL-fuel combinations as greener hypergols

상세보기
Combust. Flame Kang 181 149 2017 10.1016/j.combustflame.2017.03.021 Autoignition and combustion characteristics of sodium borohydride-based non-toxic hypergolic fuel droplet at elevated temperatures

상세보기
J. Spacecr. Rockets Kang 55 1230 2018 10.2514/1.A34177 Experiment and speculations on nontoxic hypergolic propulsion with hydrogen peroxide

상세보기
Aerosp. Sci. Technol. Moon 33 118 2014 10.1016/j.ast.2014.01.006 Design specifications of H2O2/kerosene bipropellant rocket system for space missions

상세보기
Acta Astronaut. Kang 137 25 2017 10.1016/j.actaastro.2017.04.009 Green hypergolic combination: diethylenetriamine-based fuel and hydrogen peroxide

상세보기
Combust. Flame Kang 210 43 2019 10.1016/j.combustflame.2019.08.016 A mixture of hydrogen peroxide and tetraglyme as a green energetic monopropellant

상세보기
Florczuk 2017 53rd AIAA/SAE/ASEE Joint Propulsion Conference Performance evaluation of the hypergolic green propellants based on the HTP for a future next generation spacecrafts
Angew. Chem. Int. Ed. Schneider 50 5886 2011 10.1002/anie.201101752 Green bipropellants: hydrogen-rich ionic liquids that are hypergolic with hydrogen peroxide

상세보기
J. Mater. Chem. A Wang 6 22819 2018 10.1039/C8TA08042A Iodocuprate-containing ionic liquids as promoters for green propulsion

상세보기
J. Mater. Chem. A Chinnam 6 19989 2018 10.1039/C8TA03780A Effects of closo-icosahedral periodoborane salts on hypergolic reactions of 70% H2O2 with energetic ionic liquids

상세보기
New J. Chem. Bhosale 41 1250 2017 10.1039/C6NJ03233H Ultrafast igniting, imidazolium based hypergolic ionic liquids with enhanced hydrophobicity

상세보기
New J. Chem. Bhosale 41 9889 2017 10.1039/C7NJ01748K Theoretical performance evaluation of hypergolic ionic liquid fuels with storable oxidizers

상세보기
1, 1- Dimethyl hydrazine, ILO International Chemical Safety Cards. (2008). url:http://www.ilo.org/dyn/icsc/showcard.display?p_version=2&p_card_id=0147.
Gordon 44135 1994
Mcbride 44135 1996
Explos. Pyrotech. Swami 44 1139 2019 10.1002/prep.201800381 Ignition delays of mixtures of the non-hypergolic energetic ionic liquid hydroxyethylhydrazinium nitrate blended with unsymmetrical dimethylhydrazine, propellants

상세보기
Sci. Adv. Titi 5 2019 10.1126/sciadv.aav9044 Hypergolic zeolitic imidazolate frameworks (ZIFs) as next-generation solid fuels: unlocking the latent energetic behavior of ZIFs

상세보기
Combust. Flame Bhosale 210 1 2019 10.1016/j.combustflame.2019.08.015 Ignition study of amine borane/cyanoborane based green hypergolic fuels

상세보기
Proc. Combust. Inst. Khomik 37 3311 2019 10.1016/j.proci.2018.05.144 Ignition characteristics of hypergolic fuels with various N-substituents

상세보기
Atkins 2006 Atkins’ Physical Chemistry
J. Propuls. Power Connell 34 170 2018 10.2514/1.B36458 Ignition of hydrogen peroxide with gel hydrocarbon fuels

상세보기
Yuan 1 2018 2018 Joint Propulsion Conference The auto-ignition of kerosene-based sythetic fuel/hydrogen peroxide propellants and its injector design
J. Propuls. Power Kang 33 1111 2017 10.2514/1.B36510 Suppression of hard start for nontoxic hypergolic thruster using H2O2 oxidizer

상세보기
Mater. Today Energy Lombardo 9 391 2018 10.1016/j.mtener.2018.07.001 Destabilizing sodium borohydride with an ionic liquid

상세보기
Combust. Flame Weng 194 464 2018 10.1016/j.combustflame.2018.05.015 Coulomb explosion and ultra-fast hypergolic ignition of borohydride-rich ionic liquids with WFNA

상세보기
J. Propuls. Power Li 34 125 2018 10.2514/1.B36441 Experimental observation of hypergolic ignition of superbase-derived ionic liquids

상세보기
Altman 1960 Liquid propellant rockets

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[해외논문] Additive-promoted hypergolic ignition of ionic liquid with hydrogen peroxide

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[해외논문] Additive-promoted hypergolic ignition of ionic liquid with hydrogen peroxide

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