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[해외논문] Tuning Triplet Energy Transfer of Hydroxamates as the Nitrene Precursor for Intramolecular C(sp3)-H Amidation

Journal of the American Chemical Society, v.142 no.12, 2020년, pp.5811 - 5818  

Jung, Hoimin (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , South Korea) ,  Keum, Hyeyun (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , South Korea) ,  Kweon, Jeonguk (Department of Chemistry , Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 34141 , South Korea) ,  Chang, Sukbok

Abstract AI-Helper 아이콘AI-Helper

Reported herein is the design of a photosensitization strategy to generate triplet nitrenes and its applicability for the intramolecular C-H amidation reactions. Substrate optimization by tuning physical organic parameters according to the proposed energy transfer pathway led us to identify hydroxam...

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