[논문]Selective detection of cyanide ion in 100 % water by indolium based dual reactive binding site optical sensor

Park, Jong Ho; Manivannan, Ramalingam; Jayasudha, Palanisamy; Son, Young-A

doi:10.1016/j.jphotochem.2020.112571

[해외논문] Selective detection of cyanide ion in 100 % water by indolium based dual reactive binding site optical sensor

Journal of photochemistry and photobiology. A, Chemistry, v.397, 2020년, pp.112571 -

Park, Jong Ho (Corresponding author.) , Manivannan, Ramalingam , Jayasudha, Palanisamy , Son, Young-A

Abstract ▼ AI-Helper

Abstract The indolium based sensor (R) system was designed, synthesized, characterized and its cyanide recognizing abilities are examined in 100 % water. The sensor attach with cyanide ion through nucleophilic addition to C atom of the indolium CN group. Also the sensor displayed colorimetric and fluorimetric behavior and it can be simply observed by naked eye. The addition of other chosen anions does not affect the sensor response towards cyanide ion. Test strip constructed on R was act as a convenient test kit to distinguish cyanide ion. Besides, the recognizing ability of sensor has been effectively applied in real water samples and this was validated with HPLC technique. Thus the receptor can be used as an effective sensor to sense cyanide ion water. Highlights An indolium based chemodosimeter for the detection of cyanide is described. The color of the sensor changed from purple to colourless with the addition of cyanide ion. The mechanism of sensing involves nucleophilic addition of CN− to C atom of the indolium CN bond. Graphical abstract [DISPLAY OMISSION]

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