There is provided a cellulose based fiber made of a i) cellulose dissolving pulp, and ii) a recycled cellulose textile, which is treated to swell the cellulose with a reducing additive and a) bleached with oxygen at alkaline conditions with a pH in the range 9-13.5 and/or b) bleached with ozone at a
There is provided a cellulose based fiber made of a i) cellulose dissolving pulp, and ii) a recycled cellulose textile, which is treated to swell the cellulose with a reducing additive and a) bleached with oxygen at alkaline conditions with a pH in the range 9-13.5 and/or b) bleached with ozone at acid conditions below pH 6, wherein the cellulose based fiber is manufactured with one selected from a Viscose process and a Lyocell process. Advantages include that the tensile strength of the fiber is improved and it is possible to manufacture improved cellulose fibers which comprise a fraction of recycled material.
대표청구항▼
1. A cellulose based fiber made of a i) cellulose dissolving pulp, and ii) a material made from recycled textile comprising cellulose, which is a) treated to swell the cellulose under reducing conditions together with at least one reducing additive present at least during a part of the swelling and
1. A cellulose based fiber made of a i) cellulose dissolving pulp, and ii) a material made from recycled textile comprising cellulose, which is a) treated to swell the cellulose under reducing conditions together with at least one reducing additive present at least during a part of the swelling and b) treated in at least one of the following bleaching steps i) bleaching with oxygen at alkaline conditions with a pH in the range 9-13.5 and ii) bleaching with ozone at acid conditions below pH 6, wherein the steps a) and b) are carried out in sequential order and wherein the bleaching steps i) and ii) may be carried out in any order if both i) and ii) are performed, and wherein the cellulose based fiber is manufactured with one selected from a Viscose process and a Lyocell process. 2. The cellulose based fiber according to claim 1, wherein the cellulose dissolving pulp is from a virgin source. 3. The cellulose based fiber according to claim 1, wherein the cellulose dissolving pulp is of a type normally used in a Viscose process. 4. The cellulose based fiber according to claim 1, wherein the cellulose dissolving pulp is of a type normally used in a Lyocell process. 5. The cellulose based fiber according to claim 1, wherein the material made from recycled textile constitutes at least 10 wt % of the cellulose based fiber. 6. The cellulose based fiber according to claim 1, wherein the recycled textile is at least one selected from the group consisting of cotton, Lyocell, rayon, and Viscose. 7. The cellulose based fiber according to claim 1, wherein the recycled textile is cotton. 8. The cellulose based fiber according to claim 1, wherein the recycled textile is mechanically disintegrated to at least partially disintegrate the cellulose before the swelling of the cellulose. 9. The cellulose based fiber according to claim 1, wherein the pH during the swelling is in the range of 9-13.5. 10. The cellulose based fiber according to claim 1, wherein NaOH is present during the swelling in a concentration from 0.01 to 0.5 mol/l. 11. The cellulose based fiber according to claim 1, wherein the temperature during the swelling is in the range 50-100° C. 12. The cellulose based fiber according to claim 1, wherein the at least one reducing additive comprises sodium dithionite, Na2S2O4 in a concentration from 0.01 to 0.25 mol/l. 13. The cellulose based fiber according to claim 1, wherein the bleaching with oxygen at alkaline conditions is carried out at a temperature in the interval 60-120° C. 14. The cellulose based fiber according to claim 1, wherein the bleaching with oxygen at alkaline conditions is carried out during 20 minutes-24 hours. 15. The cellulose based fiber according to claim 1, wherein the bleaching with oxygen at alkaline conditions is carried out during 30 min-120 min. 16. The cellulose based fiber according to claim 1, wherein a wash is carried out before the bleaching with ozone at acid conditions. 17. The cellulose based fiber according to claim 1, wherein the material is dewatered to a water content of less than 66 wt % before the bleaching with ozone at acid conditions. 18. The cellulose based fiber according to claim 1, wherein the bleaching with ozone at acid conditions is carried out at a pH in the interval 1.5-5. 19. A method for manufacturing a cellulose based fiber, comprising the step of mixing: i) cellulose dissolving pulp, andmaterial made from recycled textile comprising cellulose, which is a) treated to swell the cellulose under reducing conditions together with at least one reducing additive present at least during a part of the swelling and b) treated in at least one of the following bleaching steps i) bleaching with oxygen at alkaline conditions with a pH in the range 9-13.5 and ii) bleaching with ozone at acid conditions below pH 6, wherein the steps a) and b) are carried out in sequential order and wherein the bleaching steps i) and ii) may be carried out in any order if both i) and ii) are performed, andwherein the cellulose based fiber is manufactured with one selected from a Viscose process and a Lyocell process.
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