ANODE ACTIVE MATERIAL FOR LITHIUM SECONDARY BATTERY, METHOD OF MANUFACTURING SAME AND LITHIUM SECONDARY BATTERY COMPRISING SAME
원문보기
IPC분류정보
국가/구분
United States(US) Patent
공개
국제특허분류(IPC7판)
H01M-004/587
C01B-032/23
H01M-004/36
H01M-010/0525
출원번호
16710452
(2019-12-11)
공개번호
20200185720
(2020-06-11)
우선권정보
KR-10-2018-0159047 (2018-12-11)
발명자
/ 주소
LEE, Sung Man
KIM, Ki Hoon
출원인 / 주소
LEE, Sung Man
인용정보
피인용 횟수 :
0인용 특허 :
0
초록▼
The present disclosure relates to an anode active material for a lithium secondary battery, a method of manufacturing the anode active material, and a lithium secondary battery including the anode active material. The anode active material includes natural graphite particles configured such that fla
The present disclosure relates to an anode active material for a lithium secondary battery, a method of manufacturing the anode active material, and a lithium secondary battery including the anode active material. The anode active material includes natural graphite particles configured such that flaky natural graphite fragment particles having uneven (□□) surface defects are structured in a cabbage shape or at random and granulated, the surface and the inside of the natural graphite particles including a gap formed between the flaky natural graphite fragment particles, and a coating layer including amorphous or semicrystalline carbon formed on the surface of the flaky natural graphite fragment particles that form the gap and the surface of the natural graphite particles.
대표청구항▼
1. An anode active material for a lithium secondary battery, the anode active material comprising: natural graphite particles configured such that flaky natural graphite fragment particles having uneven (□□) surface defects are structured in a cabbage shape or at random and granulated, a surface and
1. An anode active material for a lithium secondary battery, the anode active material comprising: natural graphite particles configured such that flaky natural graphite fragment particles having uneven (□□) surface defects are structured in a cabbage shape or at random and granulated, a surface and an inside of the natural graphite particles including a gap formed between the flaky natural graphite fragment particles; anda coating layer including amorphous or semicrystalline carbon formed on a surface of the flaky natural graphite fragment particles that form the gap and the surface of the natural graphite particles. 2. The anode active material of claim 1, wherein the amorphous or semicrystalline carbon is included in an amount of 1 to 20 parts by weight based on 100 parts by weight of the natural graphite particles. 3. The anode active material of claim 1, wherein the natural graphite particles have an average particle diameter (D50) of 5 to 40 μm. 4. A method of manufacturing the anode active material of claim 1, the method comprising: preparing a solution, including spheroidized natural graphite particles in which flaky natural graphite fragment particles are structured in a cabbage shape or at random and granulated, an amorphous or semicrystalline carbon precursor, an oxidizing agent, and a solvent;sonicating the solution, whereby a gap is formed between the flaky natural graphite fragment particles present at a surface of and inside the spheroidized natural graphite particles, uneven (□□) defects are formed on a surface of the flaky natural graphite fragment particles present at the surface of and inside the spheroidized natural graphite particles, and the surface of the flaky natural graphite fragment particles forming the gap and the surface of the spheroidized natural graphite particles are impregnated and coated with the amorphous or semicrystalline carbon precursor;drying the sonicated solution, thus manufacturing spheroidized-natural-graphite-modified particles; andheat-treating the spheroidized-natural-graphite-modified particles. 5. The method of claim 4, wherein the carbon precursor is at least one selected from the group consisting of citric acid, stearic acid, sucrose, polyvinylidene fluoride, a Pluronic block copolymer (Pluronic F127), carboxymethyl cellulose (CMC), hydroxypropyl cellulose, regenerated cellulose, polyvinylpyrrolidone, tetrafluoroethylene, polyethylene, polypropylene, an ethylene-propylene-diene monomer (EPDM), sulfonated EPDM, starch, a phenol resin, a furan resin, furfuryl alcohol, polyacrylic acid, sodium polyacrylate, polyacrylonitrile, polyimide, an epoxy resin, cellulose, styrene, polyvinylalcohol, polyvinyl chloride, M polyvinyl pyrrolidone, glycerol, polyol, a coal-based pitch, a petroleum-based pitch, a mesophase pitch, low-molecular-weight heavy oil, glucose, gelatin and sugars. 6. The method of claim 4, wherein the solvent is at least one selected from the group consisting of water, N-methylpyrrolidone, dimethylformamide, toluene, ethylene, dimethylacetamide, acetone, methyl ethyl ketone, hexane, tetrahydrofuran, decane, ethanol, methanol, isopropanol, and ethyl acetate. 7. The method of claim 4, wherein the sonicating is performed at a frequency of 10 to 35 kHz and an ultrasonic amplitude of 10 to 100 W for 1 min to 24 hr. 8. The method of claim 4, wherein the drying is performed through at least one spray-drying process selected from among rotary spraying, nozzle spraying and ultrasonic spraying, a drying process using a rotary evaporator, a vacuum-drying process, or a natural drying process. 9. The method of claim 4, wherein the oxidizing agent includes at least one selected from among hydrogen peroxide (H2O2), nitric acid (HNO3), sulfuric acid (H2SO4), potassium permanganate (KMnO4) and sodium hydroxide (NaOH). 10. The method of claim 4, wherein the heat-treating is performed at 500 to 3200° C. 11. The method of claim 4, wherein the heat-treating is performed in an atmosphere containing nitrogen, argon, hydrogen or combinations thereof, or in a vacuum. 12. The method of claim 4, wherein the carbon precursor is included in an amount of 2 to 80 parts by weight based on 100 parts by weight of the spheroidized natural graphite particles. 13. A lithium secondary battery, comprising: an anode including the anode active material of claim 1;a cathode; andan electrolyte.
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