Difunctional monomers of the formula, [Figure] where R is an organic linking group derived from a diol or a dihalide of the formula X－R－X, where X is either chlorine, bromine, iodine, or hydroxy, are prepared by reacting a conjugated diene, exemplified by anthracene, with an ester of 2-cyanoacrylic
Difunctional monomers of the formula, [Figure] where R is an organic linking group derived from a diol or a dihalide of the formula X－R－X, where X is either chlorine, bromine, iodine, or hydroxy, are prepared by reacting a conjugated diene, exemplified by anthracene, with an ester of 2-cyanoacrylic acid to form the Diels-Alder adduct of the ester. The ester adduct is hydrolyzed to ultimately obtain either the Diels-Adler adduct of either 2-cyanoacrylic acid--alkali metal salt or 2-cyanoacryloyl halide. These latter intermediates are respectively reacted with either the dihalide or the diol to afford the bis-Diels-Alder adduct of the R substituted bis (2-cyanoacrylate) monomer. The protective diene group may then be removed, for example, by reaction with excess maleic anhydride and the resulting difunctional monomer isolated. The difunctional monomers thus prepared can be utilized as crosslinking agents in blends comprising one or more of these difunctional monomers and at least one monofunctional monomer, exemplified by an ester of 2-cyanoacrylic acid. Alternately, one or more difunctional monomers can be homopolymerized or copolymerized to a highly crosslinked polymer. The copolymerized compositions of the monomer blends are particularly useful as adhesives, especially in dental applications for coating or sealing enamel surfaces of teeth to allay decay, or for the bonding of brackets to teeth in orthodontics and bond being substantially more resistant to moisture than where the monofunctional monomer is used alone.
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As a new composition of matter a compound represented by the formula V [Figure] wherein D is selected from the group consisting of [Figure] where R1 and R2 are the same R1 and R2 may be H, an alkyl group of 1 to 5 carbons, phenyl, Br or Cl and where R1 and R2 are different, R1 is H and R2 may be any
As a new composition of matter a compound represented by the formula V [Figure] wherein D is selected from the group consisting of [Figure] where R1 and R2 are the same R1 and R2 may be H, an alkyl group of 1 to 5 carbons, phenyl, Br or Cl and where R1 and R2 are different, R1 is H and R2 may be any of the group consisting of an alkyl group of 1 to 5 carbons, phenyl, Br and Cl; [Figure] where R3 is H or CH3; and [Figure] wherein the organo linking group R of Formula V is any one of the group consisting of: －(CH2)m－, where m is an integer of from 1 to 20 inclusive; [Figure] where n is an integer of from 0 to 18 inclusive, and R4 and R5 are independently hydrogen or a C1 to C5 alkyl group, R4 and R5 not simultaneously being hydrogen; －(CH2)r－Z－(CH2)s－, where Z is －O－, －S－, －CH=CH－; －C≡C－; [Figure] where r and s are independent integers of from 1 to 10 inclusive and r and s total from 2 to 20, R6 and R7 are independently hydrogen or a straight or branched chain C1 to C5 alkyl group; [Figure] where x and y are integers of from 1 to 6 inclusive; [Figure] where x and y are as hereinbefore defined; －CH2－(CF2)z－CH2－, where z is an integer of from 1 to 10 inclusive; and [Figure]
Zhang, Sheng; Ruiz, Rafael, Method of preparing adhesive compositions for medical use: single additive as both the thickening agent and the accelerator.
Gherardi, Stefano; McArdle, Ciaran B.; Faimani, Giovanni; Loschen, Christoph, Substituted activated methylene reagents and methods of using such reagents to form electron deficient olefins.
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