초록 ▼

A method for activating a hydrodesulfurization catalyst by passing a gaseous stream comprising carbon oxides, hydrogen, and sulfur-containing compounds into contact with the catalyst at a temperature from about 400°to about 700°F. until the outlet gaseous stream from the catalyst has a sulfur conten

A method for activating a hydrodesulfurization catalyst by passing a gaseous stream comprising carbon oxides, hydrogen, and sulfur-containing compounds into contact with the catalyst at a temperature from about 400°to about 700°F. until the outlet gaseous stream from the catalyst has a sulfur content substantially equal to the sulfur content of the inlet gaseous stream and thereafter increasing the temperature incrementally and continuing to contact the catalyst with the inlet gas stream until the sulfur content in the outlet gaseous stream is substantially equal to the sulfur content of the inlet gaseous stream after each incremental temperature increase.

대표청구항 ▼

A method for sulfiding a hydrodesulfurization catalyst useful in reacting a sulfur-containing synthesis gas stream containing carbon oxides and hydrogen, said catalyst consisting essentially of at least one member selected from the group consisting of nickel, nickel compounds, cobalt, cobalt compoun

A method for sulfiding a hydrodesulfurization catalyst useful in reacting a sulfur-containing synthesis gas stream containing carbon oxides and hydrogen, said catalyst consisting essentially of at least one member selected from the group consisting of nickel, nickel compounds, cobalt, cobalt compounds, molybdenum and molybdenum compounds supported on a catalyst carrier material comprising at least one of the group consisting of aluminum oxides, silica, kaolin, and kieselguhr, said method consisting essentially of sequentially (a) passing an inlet gaseous stream comprising carbon oxides, H2 and at least one sulfur-containing compound selected from the group consisting of H2S, COS, C2S, mercaptans and thiophenes, into contact with said catalyst at a temperature from about 400°to about 700°F. and a space velocity greater than about 500 hr-1 until the outlet gaseous stream has a sulfur content substantially equal to the sulfur content of said inlet gaseous stream; (b) increasing the temperature in said catalyst bed incrementally, until a desired operating temperature is reached; and (c) further contacting said catalyst at said increased temperature which said inlet stream after each incremental temperature increase until said outlet gaseous stream again has a sulfur content substantially equal to the sulfur content of said inlet gaseous stream.