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Coal or other high ash containing carbonaceous solid fuel is reacted with a free-oxygen containing gas, with or without a temperature moderator, in a down-flow partial oxidation gas generator to produce a stream of raw synthesis gas, fuel gas, or reducing gas. A large portion of the combustion resid

Coal or other high ash containing carbonaceous solid fuel is reacted with a free-oxygen containing gas, with or without a temperature moderator, in a down-flow partial oxidation gas generator to produce a stream of raw synthesis gas, fuel gas, or reducing gas. A large portion of the combustion residue, i.e., molten slag and/or particulate solids that is entrained in the down-flowing generated gas stream is removed by gravity when the gas stream is passed through a diversion chamber where the velocity of the gas stream is reduced and its direction is diverted. The main gas stream leaving the diversion chamber through the side outlet passes upward through a solids separation zone, optionally including gas-gas quench cooling, cyclones, filters, impingement separators, or combinations thereof, where additional entrained solids are removed and where some cooling of the gas stream may be effected by impingement with a cooled cleaned recycle portion of the gas stream. Next, most of the sensible heat in the gas stream is recovered by the production of steam. The gas stream, with a substantially reduced solids content, is passed through the tubes of one or more shell-and-straight fire tube gas coolers.

대표청구항 ▼

A process for the partial oxidation of an ash-containing solid carbonaceous fuel for producing a cooled cleaned product gas stream of synthesis gas, fuel gas or reducing gas and by-product steam comprising: (1) reacting particles of said solid fuel with a free-oxygen containing gas and with or witho

A process for the partial oxidation of an ash-containing solid carbonaceous fuel for producing a cooled cleaned product gas stream of synthesis gas, fuel gas or reducing gas and by-product steam comprising: (1) reacting particles of said solid fuel with a free-oxygen containing gas and with or without a temperature moderator in a down-flow refractory lined gas generator at a temperature in the range of about 1700°to 3100°F. and a pressure in the range of about 10 to 200 atmospheres to produce a raw gas stream comprising H2, CO, CO2, and one or more materials selected from the group consisting of H2O, H2S, COS, CH4, NH3, N2, and A, and containing molten slag and/or particulate matter; (2) passing the gas stream from (1) down through the central outlet in the bottom of the reaction zone and into a thermally insulated diversion chamber provided with a side outlet and a bottom outlet; separating by gravity molten slag and/or particulate matter from said gas stream; passing from about 0 to 20 vol. % of said gas stream as bleed gas along with said separated material through the bottom outlet of said diversion chamber and into a pool of quench water in a quench chamber located below said diversion chamber; and passing the remainder of said gas stream through a side exit passage in said diversion chamber directly through a thermally insulated transfer line and inlet passage of a separate thermally insulated gas-gas quench cooling and solids separation zone at substantially the same temperature and pressure as produced in step (1) less ordinary pressure drop in the lines; (3) impinging the gas stream from (2) in said gas-gas quench cooling and solids separation zone with a stream of recycle quench gas comprising cooled cleaned and compressed product gas from (7), thereby partially cooling the gas stream from (2) partially solidifying entrained molten slag, and separating from the gas stream a portion of the slag and particulate matter; and passing the partially cooled gas stream up through a separate thermally insulated upper chamber located above and communicating with said gas-gas quench cooling and solids separation zone and removing additional entrained solids from the gas stream; (4) cooling the gas stream from (3) in a main gas cooling zone and producing by-product steam by passing said gas stream in indirect heat exchange with preheated boiler feed water first upward through the tubes of a vertical high temperature shell-and-straight fire tube gas cooler having refractory lined inlet and outlet sections, one pass on the shell and tube sides and having fixed tube sheets, then passing the gas stream down through the tubes in the first tube-side pass of a vertical low temperature shell-and-straight fire tube gas cooler having two passes on the tube-side and one pass on the shell-side and having fixed tube sheets, and then upward through the tubes in the second tube-side pass of said second gas cooler; and wherein by-product steam is removed from the shell-sides of said first and second gas coolers; and preheating boiler feed water for use in (4) by indirect heat exchange with the gas stream leaving said second gas cooler; (5) cooling, and scrubbing the gas stream from (4) with water in gas cooling and scrubbing zones producing a carbon-water dispersion; (6) cooling the gas stream from (5) below the dew point and separating condensed water to produce said cooled, cleaned stream of product gas; and (7) compressing a portion of said product gas stream from (6) and introducing same into said gas-gas quench cooling and solids separation zone in (3) as said stream of recycle quench gas.