초록 ▼

An amorphous silica supported palladium catalyst is provided which also contains a small amount of an additive metal compound selected from an oxide, hydroxide and carbonate of zirconium, thorium, hafnium, cerium, titanium and aluminum. By use of particular preparation conditions and the amount of a

An amorphous silica supported palladium catalyst is provided which also contains a small amount of an additive metal compound selected from an oxide, hydroxide and carbonate of zirconium, thorium, hafnium, cerium, titanium and aluminum. By use of particular preparation conditions and the amount of additive metal salt raw material used, the additive metal compound deposits from solution before or simultaneously with a palladium compound. The additive metal compound deposits on the silica support and serves as a base for the subsequently deposited palladium compound which is later reduced to palladium metal. The described catalyst is particularly suitable as a hydrogenation catalyst in a cyclic process for the manufacture of hydrogen peroxide.

대표청구항 ▼

In a process for producing hydrogen peroxide by alternately hydrogenating an alkylanthraquinone and/or a tetrahydroalkylanthraquione and oxygenating the resulting alkylanthrahydroquinone and/or tetrahydroalkylanthrahydroquinone to regenerate the alkylanthraquinone and/or tetrahydroalkylanthraquinone

In a process for producing hydrogen peroxide by alternately hydrogenating an alkylanthraquinone and/or a tetrahydroalkylanthraquione and oxygenating the resulting alkylanthrahydroquinone and/or tetrahydroalkylanthrahydroquinone to regenerate the alkylanthraquinone and/or tetrahydroalkylanthraquinone and to produce hydrogen peroxide, the improvement comprising conducting the hydrogenation in the presence of a catalyst consisting essentially of an amorphous silica support having deposited thereon about 0.05-5 percent by weight based on the weight of silica of at least one oxide, hydroxide or carbonate of at least one metal selected from the group consisting of zirconium, thoriium, hafnium, cerium, and titanium and about 0.1-10 percent by weight based on the weight of silica of palladium metal; the metal oxide, hydroxide or carbonate being deposited before or simultaneously with the palladium metal in the form of its oxide, hydroxide or carbonate.