초록 ▼

A process for regenerating a deteriorated antimony containing oxide catalyst comprising as essential components of (i) antimony and (ii) at least one metal element selected from the group consisting of iron, cobalt, nickel, manganese, uranium, cerium, tin and copper wherein the deteriorated antimony

A process for regenerating a deteriorated antimony containing oxide catalyst comprising as essential components of (i) antimony and (ii) at least one metal element selected from the group consisting of iron, cobalt, nickel, manganese, uranium, cerium, tin and copper wherein the deteriorated antimony containing oxide catalyst is impregnated or sprayed with an aqueous hydrogen peroxide solution and the impregnated catalyst is dried and then calcined at a temperature of about 200°to 1,000°C.

대표청구항 ▼

A process for regenerating a deteriorated antimony containing metal oxide catalyst used in oxidative reactions with olefins having the following empirical formula: MeaSbbXcRdQeOf wherein Me is at least one element selected from the group consisting of Fe, Co, Ni, Mn, U, Ce, Sn and Cu; X is at least

A process for regenerating a deteriorated antimony containing metal oxide catalyst used in oxidative reactions with olefins having the following empirical formula: MeaSbbXcRdQeOf wherein Me is at least one element selected from the group consisting of Fe, Co, Ni, Mn, U, Ce, Sn and Cu; X is at least one element selected from the group consisting of V, Mo, W, Nb and Ta; R is at least one element selected from the group consisting of B, P, Bi and Te; Q is at least one element selected from the group consisting of Mg, Ca, Sr, Ba, La, Ti, Zr, Cr, Re, Ru, Os, Rh, Ir, Pd, Pt, Ag, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Pb, As, S and Se; the subscripts a, b, c, d, e and f represent atomic ratios, and where a is 10, b is 5 to 60, c is 0 to 30, d is 0 to 10, e is 0 to 20, and f is the number of oxygen atoms that combine with these components to form an oxide which comprises impregnating or spraying said antimony containing metal oxide catalyst with 0.05 to 60 wt % based on said catalyst of an aqueous hydrogen peroxide solution, having a concentration of about 0.5 to 35 wt %, drying thus impregnated catalyst, and calcining the catalyst from 400°to 1,000°C. The process of claim 1, wherein said aqueous hydrogen peroxide solution additionally contains at least one member selected from the group consisting of vanadic acid, molybdic acid, tungstic acid and salts thereof. The process of claim 1, wherein said aqueous hydrogen peroxide solution additionally contains a compound prepared by oxidizing metallic tellurium, tetravalent telluride or tellurium oxide hydrate with hydrogen peroxide.