초록 ▼

This specification discloses a process for the production of oxygenated compounds, more specifically aldehydes and alcohols, by reacting an olefin with hydrogen and carbon monoxide in the presence of, as a ctalyst, an insoluble polymer containing a functional group, which may be an amine, thiol, pho

This specification discloses a process for the production of oxygenated compounds, more specifically aldehydes and alcohols, by reacting an olefin with hydrogen and carbon monoxide in the presence of, as a ctalyst, an insoluble polymer containing a functional group, which may be an amine, thiol, phosphine, or arsine group, having chemically bonded thereto a metal of Group VIII of the Periodic Table. The metal can be, for example, rhodium, cobalt, or ruthenium. The olefin can contain more than one carbon-to-carbon double bond, may be an open chain or a cyclic olefin, and may be substituted. Further, the olefin may be contained in a refinery stream such as a cracked gasoline. The reaction may be carried out in the presence of a polar solvent.

대표청구항 ▼

A process for the production of an oxygenated compound selected from the group consisting of aldehydes and alcohols comprising hydroformylating an olefin with carbon monoxide and hydrogen under hydroformylating conditions at a temperature up to about 250°C. and with a catalyst consisting essentially

A process for the production of an oxygenated compound selected from the group consisting of aldehydes and alcohols comprising hydroformylating an olefin with carbon monoxide and hydrogen under hydroformylating conditions at a temperature up to about 250°C. and with a catalyst consisting essentially of an insoluble organic polymer containing a functional group selected from the group consisting of amine, thiol, phosphine and arsine groups having chemically bonded thereto a metal selected from the group consisting of cobalt and rhodium.