초록 ▼

Improved fiber resin matrix prepreg fabrics are disclosed which are comprised of a first layer of reinforcing fabric coated with an epoxy resin composition and a discrete second layer of an epoxy resin modified with an elastomeric polymer. The discrete second layer is provided with a support compris

Improved fiber resin matrix prepreg fabrics are disclosed which are comprised of a first layer of reinforcing fabric coated with an epoxy resin composition and a discrete second layer of an epoxy resin modified with an elastomeric polymer. The discrete second layer is provided with a support comprising a gauze-like, lightweight fibrous mat or carrier of lightweight fibers that preserves the second "interleaf" layer during cure. Cured composites having the continuous interleaf layer intact exhibit high impact strength and resistance to impact damage. 6

대표청구항 ▼

1. A method for producing an interleafed fiber resin matrix prepreg fabric comprising (1) incorporating a non-woven or woven fibrous mat or carrier of lightweight supporting filaments into an interleaf resin composition comprising (a) a first thermosetting epoxy resin composition containing (b

1. A method for producing an interleafed fiber resin matrix prepreg fabric comprising (1) incorporating a non-woven or woven fibrous mat or carrier of lightweight supporting filaments into an interleaf resin composition comprising (a) a first thermosetting epoxy resin composition containing (b) about 8% to 70% by weight of a rubbery vinyl addition polymer to provide a supported interleaf resin layer; and (2) introducing said supported interleaf resin layer to at least one surface of a fiber resin matrix comprising (a) a fabric of high-strength reinforcing filaments and (b) a second thermosetting epoxy resin composition coating and impregnating said fabric. 2. The method of claim 1, wherein said first thermosetting epoxy resin composition exhibits shear modulus of at least 50,000 psi and yield strength of at least 3,000 psi at high temperatures, and shear strain to failure of at least 6% at -67° F. and at least 15% at room temperature; and said second thermosetting epoxy resin composition exhibits shear modulus of at least 90,000 psi at high temperatures or at least 50,000 psi at high temperatures under wet conditions. 3. The method of claim 1, wherein said supporting filaments are selected from the group consisting of lightweight glass, carbon, graphite, polyaramide, polyester, and cellulosic filaments. 4. The method of claim 1, wherein said fabric is comprised of interwoven tows containing from about 1,000 to 12,000 high-strength reinforcing filaments. 5. The method of claim 4, wherein said reinforcing filaments are selected from the group consisting of glass, carbon, graphite, silicon carbide, boron, polyaramide, polyester, polyamide, rayon, polybenzimidazole, and polybenzothiazole filaments, and metal-coated such filaments. 6. The method of claim 1, wherein said rubbery vinyl addition polymer comprises about 8% to 24% by weight of said interleaf resin composition, said second thermosetting epoxy resin composition comprises about 35% to 60% by weight of said fiber resin matrix, and said fibrous mat or carrier comprises less than 5% by weight of the interleafed fiber resin matrix prepreg fabric. 7. The method of claim 6, wherein a cross-linked interface is formed between said interleaf resin layer and said fiber resin matrix. 8. The method of claim 1, wherein said first and second thermosetting epoxy resin compositions are, independently, comprised of epoxy compounds selected from the group consisting of polyglycidyl ethers of polyfunctional phenols, polyglycidyl ethers of the chlorination or bromination products of polyvalent phenols, polyglycidyl ethers of novolacs, polyepoxy compounds derived from aromatic amines and epichlorohydrin, and mixtures thereof. 9. The method of claim 2, wherein said first and second thermosetting epoxy resin compositions both exhibit an ultimate shear stress above about 3,000 psi. 10. The method of claim 8, wherein said epoxy resin compositions further include curing agents 11. The method of claim 10, wherein said curing agents are diamines. 12. The method of claim 11, wherein said diamines are selected from the group consisting of diaminodiphenyl sulphone, diaminodiphenyl methane, and phenylenediamine. 13. The method of claim 1, wherein said rubbery vinyl addition polymer is a homopolymeric or copolymeric diene rubber derived from a conjugated diene having 4 to 8 carbon atoms. 14. The method of claim 13, wherein said vinyl addition polymer is a butadiene-acrylonitrile polymer or a carboxcylic-functional butadiene acrylonitrile polymer. 15. In a method for producing an interleafed fiber resin matrix prepreg comprising (A) a fiber resin matrix comprising (i) a fabric of interwoven high-strength reinforcing filaments coated and impregnated with (ii) a thermosetting epoxy resin composition, and (B) a discrete interleaf resin layer on at least one surface of said fiber resin matrix comprising (i) a thermosetting epoxy resin composition and (ii) about 8% to 70% by weight of a rubbery vinyl addition polymer, the improvement which comprises incorporating a fibrous mat or carrier of lightweight supporting filaments into said interleaf resin layer. 16. An interleafed fiber resin matrix prepreg fabric comprising (A) a fiber resin matrix comprising (i) 40% to 70% by weight high-strength filaments interwoven to form a reinforcing fabric, and (ii) 30% to 60% by weight of a first thermosetting epoxy resin composition coating said fabric, said first epoxy resin composition comprising (a) a polyepoxide compound or combination of polyepoxide compounds, and (b) a curing agent effective to catalyze polymerization of said polyepoxide compound; and (B) a discrete interleaf resin layer comprising (i) a non-woven or woven fibrous mat or carrier of lightweight supporting filaments, and (ii) a second thermosetting epoxy resin composition coating said non-woven or woven fibrous mat or carrier, said second epoxy resin composition comprising (a) a polyepoxide compound or a combination of polyepoxide compounds, (b) about 8% to 70% by weight of a rubbery vinyl addition polymer, and (c) a curing agent affective to catalyze polymerization of said polyepoxide compound. 17. The prepreg fabric of claim 16, wherein said first thermosetting epoxy resin composition exhibits shear modulus of at least 50,000 psi and yield strength of at least 3,000 psi at high temperatures, and shear strain to failure of at least 6% at -67° F. and at least 15% at room temperature; and said second thermosetting epoxy resin composition exhibits shear modulus of at least 90,000 psi at high temperatures or at least 50,000 psi at high temperatures under wet conditions. 18. The pregreg fabric of claim 16, wherein said supporting filaments are selected from the group consisting of lightweight glass, carbon, graphite, polyaramide, polyester, and cellulosic filaments. 19. The pregreg fabric of claims 16, wherein said fabric is comprised of interwoven tows containing from about 1,000 to 12,000 high-strength reinforcing filaments. 20. The prepreg fabric of claim 19, wherein said reinforcing filaments are selected from the group consisting of glass, carbon, graphite, silicon carbide, boron, polyaramide, polyamide, rayon, polybenzimidazole, and polybenzothiazole filaments, and metal-coated such filaments. 21. The pregreg fabric of claim 20, wherein said rubbery vinyl addition polymer comprises about 8% to 24% by weight of said interleaf resin composition, said second thermosetting epoxy resin composition comprises about 30% to 60% by weight of said fiber resin matrix, and said non-woven or woven fibrous mat or carrier comprises less than 5% by weight of the interleafed fiber resin matrix prepreg fabric. 22. The prepreg fabric of claim 16, wherein a cross-linked interface is formed between said interleaf resin layer and said fiber resin matrix. 23. The prepreg fabric of claim 16, wherein said first and second thermosetting epoxy resin compositions are, independently, comprised of epoxy compounds selected from the group consisting of polyglycidyl ethers of polyfunctional phenols, polyglycidyl ethers of the chlorination or bromination products of polyvalent phenols, polyglycidyl ethers of novolacs, polyepoxy compounds derived from aromatic amines and epichlorohydrin, and mixtures thereof. 24. The prepreg fabric of claim 17, wherein said first and second thermosetting epoxy resin compositions both exhibit an ultimate shear stress above about 3,000 psi. 25. The prepreg fabric of claim 23, wherein said epoxy resin compositions further include curing agents. 26. The prepreg fabric of claim 25, wherein said curing agents are diamines. 27. The prepreg fabric of claim 26, wherein said diamines are selected from the group consisting of diaminodiphenyl sulphone, diaminodiphenyl methane, and phenylenediamine. 28. The prepreg fabric of claim 16, wherein said rubbery vinyl addition polymer is a homopolymeric or copolymeric diene rubber derived from a conjugated diene having 4 to 8 carbon atoms. 29. The prepreg fabric of claim 28, wherein said vinyl addition polymer is a butadiene-acrylonitrile polymer or a carboxcylic-functional butadieneacrylonitrile polymer.