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Means and methods are provided for determining the energy content of a hydrocarbon fuel by infrared spectroscopy. The relationship between the energy content of the fuel and the number of carbon-carbon and carbon-hydrogen bonds in the fuel is disclosed. This relationship is utilized to determine the

Means and methods are provided for determining the energy content of a hydrocarbon fuel by infrared spectroscopy. The relationship between the energy content of the fuel and the number of carbon-carbon and carbon-hydrogen bonds in the fuel is disclosed. This relationship is utilized to determine the energy content of the hydrocarbon fuel by measuring the concentration of such carbon-carbon and carbon-hydrocarbon bonds by infrared spectroscopy. A first embodiment irradiates a hydrocarbon fuel with infrared radiation of wavelengths at which specific carbon-carbon and carbon-hydrogen bonds strongly absorb. A detector array and microprocessor process the data to compute the energy content of the fuel or rate of energy consumption by a device using the fuel. A second embodiment exposes the hydrocarbon fuel to infrared energy by using frustrated total internal reflection.

대표청구항 ▼

1. An infrared energy device for measuring the energy content of a hydrocarbon fuel, comprising: an infrared light source adapted to emit infrared light of incident intensity I o into said hydrocarbon fuel including wavelengths absorbed by the CH and C--C groups; means for detecting the absorben

1. An infrared energy device for measuring the energy content of a hydrocarbon fuel, comprising: an infrared light source adapted to emit infrared light of incident intensity I o into said hydrocarbon fuel including wavelengths absorbed by the CH and C--C groups; means for detecting the absorbency of said infrared light by said groups; means for determining the concentration of said groups from the absorbency of said infrared light; and means for determining the energy content of said fuel from said concentrations. 2. The device of claim 1 wherein: said means for determining the absorbency of said infrared light detects transmitted light intensity I at said wavelengths absorbed by said groups; said means for determining the concentration of said groups generates a molecular cross section σ for each of said groups at said wavelengths; and said means for determining energy content of said fuel utilizes the relationships: ##EQU## where ##EQU##n' i =the concentration of group i bonds, ##EQU##d=optical pathlength in said fuel, ##EQU##I o (λ)=said infrared light's incident intensity at wavelength λ, I(λ)=said infrared light's transmitted intensity at wavelength λ, T=total energy per unit volume, E i =energy per mole associated with each group and N=Avogadro's number. 3. The device of claim 1 wherein said infrared energy source is adapted to emit infrared energy of at least one wave number from 1370 to 1390 cm -1 and at least one wave number from 2850 to 2960 cm -1 . 4. The device of claim 1 further including: means for detecting the rate of flow of said hydrocarbon fuel past said detecting means. 5. The device of claim 1 further including: light guide means inserted in said fuel between said infrared light source and said detecting means, which is adapted to totally internally reflect said infrared light directed therein. 6. The device of claim 1 further including means for confining at least a portion of said hydrocarbon fuel, and wherein said detecting means includes a plurality of infrared detectors positioned relative to said confining means so that the distribution of said selected groups in said confining means can be determined. 7. The device of claim 5 wherein said fuel has a first optical index of refraction and said light guide means is a light pipe having a second optical index of refraction which is larger than said first optical index of refraction. 8. The device of claim 1 wherein said detecting means includes a plurality of dielectric, multilayered, thin film bandpass filters adapted to pass infrared light of said wavelengths. 9. The device of claim 8 wherein said detecting means futher includes a substrate which is substantially transparent to infrared radiation and a plurality of pyroelectric detectors adapted to be responsive to infrared radiation, wherein said bandpass filters are on one surface of said substrate with said detectors disposed on an opposite surface of said substrate. 10. The device of claim 9 wherein said pyroelectric detectors include polyvinylidene flouride. 11. An infrared energy device for measuring the energy content of a hydrocarbon fuel, comprising: an infrared light source adapted to emit infrared light of incident intensity I o into said hydrocarbon fuel including wavelengths absorbed by the C=C, C≡C and benzene groups; means for detecting the absorbency of said infrared light by said groups; means for determining the concentration of said groups from the absorbency of said infrared light; and means for determining the energy content of said fuel from said concentrations. 12. The device of claim 11 wherein: said means for determining the absorbency of said infrared light detects transmitted light intensity I at said wavelengths absorbed by said groups; said means for determining the concentration of said groups generates a molecular cross section σ for each of said groups at said wavelengths; and said means for determining energy content of said fuel utilizes the relationships: ##EQU## where n' i =the concentration of group i bonds, d=optical pathlength in said fuel, I o (λ)=said infrared light's incident intensity at wavelength λ, I(λ)=said infrared light's transmitted intensity at wavelength λ, T=total energy per unit volume E i =energy per mole associated with each group and N=Avogadro's number. 13. The device of claim 11 wherein said infrared energy source is adapted to emit infrared energy of at least one wave number from each of the following ranges: 960 to 980 cm -1, 1490 to 1500 cm -1 and 2100 to 2140 cm -1 . 14. The device of claim 11 further including: means for detecting the rate of flow of said hydrocarbon fuel past said detecting means. 15. The device of claim 11 further including: light guide means inserted in said fuel between said infrared light source and said detecting means, said light guide means being adapted to totally internally reflect said infrared light directed along said light guide means. 16. The device of claim 15 wherein said fuel has a first optical index of refraction and said light guide means is a light pipe having a second optical index of refraction which is larger than said first optical index of refraction. 17. The device of claim 11 further including means for confining at least a portion of said hydrocarbon fuel, and wherein said detecting means includes a plurality of infrared detectors positioned relative to said confining means so that the distribution of said selected groups in said confining means can be determined. 18. The device of claim 11 wherein said detecting means includes a plurality of dielectric, multilayered, thin film bandpass filters adapted to pass infrared light of said wavelengths. 19. The device of claim 18 wherein said detecting means further includes a substrate which is substantially transparent to infrared radiation and a plurality of pyroelectric detectors adapted to be responsive to infrared radiation, wherein said bandpass filters are on one surface of said substrate and said detectors are disposed on an opposite surface of said substrate. 20. The device of claim 19 wherein said pyroelectric detectors include polyvinylidene flouride.