초록 ▼

Dense star polymers having terminal group densities greater than conventional star polymers exhibit greater and more uniform reactivity than their corresponding conventional star polymers. For example, a third generation, amine-terminated polyamidoamine dense star polymer prepared from ammonia, meth

Dense star polymers having terminal group densities greater than conventional star polymers exhibit greater and more uniform reactivity than their corresponding conventional star polymers. For example, a third generation, amine-terminated polyamidoamine dense star polymer prepared from ammonia, methyl acrylate and ethylenediamine has 1.24×10 -4 amine moieties per unit volume (cubic Angstrom units) in contrast to the 1.58×10 -6 amine moieties per unit volume contained by a conventional star polymer. Such dense star polymers are useful as demulsifiers for oil/water emulsions, wet strength agents in the manufacture of paper, and agents for modifying viscosity in aqueous formulations such as paints.

대표청구항 ▼

1. A star polymer having at least one core branch emanating from a core, each core branch having at least one terminal group provided that (1) the ratio of terminal groups to the branches emanating from the core is two or greater, (2) the density of terminal groups in the polymer is at least 1.5 tim

1. A star polymer having at least one core branch emanating from a core, each core branch having at least one terminal group provided that (1) the ratio of terminal groups to the branches emanating from the core is two or greater, (2) the density of terminal groups in the polymer is at least 1.5 times that of a conventional star polymer having similar core and monomeric moieties and a comparable molecular weight and number of core branches wherein each of such branches of the conventional star polymer bears only one terminal group, and (3) a molecular volume that is equal to or less than 60 percent of the molecular volume of said conventional star polymer. 2. The star polymer of claim 1 having (1) at least 2 core branches per core, (2) a terminal group density at least 5 times that of the corresponding conventional star polymer, and (3) a molecular volume that is equal to or less than 50 percent of the volume of the conventional star polymer. 3. The polymer of claim 1 which is a dendrimer having a polyvalent core that is covalently bonded to at least 1 ordered dendritic branch which extends to two generations such that each dendritic branch has at least four terminal groups and a symmetrical structure. 4. The polymer of claim 3 wherein the dendritic branches contain amidoamine linkages. 5. The polymer of claim 1 wherein the core is derived from a core compound having a plurality of active hydrogens capable of undergoing a Michael's addition reaction with an ethylenically unsaturated group. 6. The polymer of claim 5 wherein the core compound is an amine having a plurality of amine hydrogens. 7. An amidoamine dendrimer which is represented by the formula: ##STR## wherein A is a n-valent core derived from a nucleophilic compound, R is hydrogen or lower alkyl, B is a divalent moiety capable of linking amine groups, n is an integer of 3 or more corresponding to the number of the core branches and Z is hydrogen or ##STR## wherein R 1 is hydrogen or ##STR## provided that the dendrimer has no more than 20 generations wherein each generation is represented by ##STR## 8. The dendrimer of claim 7 wherein A is ##STR## R is hydrogen or methyl; B is the divalent residue of a polyamine, n is an integer from 3 to 8, and Z is ##STR## 9. The polymer of claim 1 which is represented by the formula: ##STR## 10. The polymer of claim 1 which is the reaction product of triaminoethylamine, methyl acrylate and ethylenediamine, said product having 6 core branches and 24 terminal amine moieties per molecule. 11. The dense star polymer of claim 2 having at least 3 core branches per core. 12. The dense star polymer of claim 11 which is a polyamine wherein the core is derived from an amine having a plurality of primary amine groups and the core branches have amine linkages. 13. The dense star polymer of claim 11 which is a polyaminosulfide wherein the core is derived from an amine having a plurality of primary amine groups and the core branches have amine and sulfide linkages. 14. A dendrimer having (1) a polyvalent core derived from a primary amine or a heterocyclic amine and (2) at least two ordered dendritic core branches which (a) are covalently bonded to the polyvalent core, (b) extend through at least two generations, and (c) have at least 3 terminal groups per core branch. 15. The dendrimer of claim 14 wherein (1) the dendritic core branches are derived from (a) an ester of α,β-ethylenically unsaturated carboxylic acid, acrylamide or maleic anhydride and (b) a polyamine, an alkanolamine or an aziridine and (2) there are from 4 to 1024 terminal groups per core branch. 16. The dendrimer of claim 15 wherein (1) the core is derived from a polyalkylene polyamine and (2) the core branch is derived from methyl acrylate and ethylene diamine or diethylenetriamine. 17. The polymer of claim 14 wherein the nucleophilic compound is a primary amine or a heterocyclic amine. 18. The polymer of claim 14 wherein the nucleophilic compound is a polyalkylenepolyamine, a polymethylenediamine, a polyaminoalkylarene, a tris(aminoalkyl)amine, hydroxyethylaminoethylamine, mercaptoethylamine, morpholine or piperazine. 19. The polymer of claim 14 wherein the nucleophilic compound is a polyalkylenepolyamine, or polymethylenediamine.