초록 ▼

Compounds of the formula: CH2〓C(R)－COO－(CH2－CH(CH3)－O)x－(CH2－CH2－O)y－OC－A－COOH or a salt thereof, wherein R is H or CH3, x is an integer from 2 to 20. y is an integer from 0 to 5, A is an alkylene, alkenylene, or phenylene radical such that A(COOH)2 is a dibasic acid capable of forming an anhydride

Compounds of the formula: CH2〓C(R)－COO－(CH2－CH(CH3)－O)x－(CH2－CH2－O)y－OC－A－COOH or a salt thereof, wherein R is H or CH3, x is an integer from 2 to 20. y is an integer from 0 to 5, A is an alkylene, alkenylene, or phenylene radical such that A(COOH)2 is a dibasic acid capable of forming an anhydride (A(CO)2O, are described. These are polymerizable compounds which have also surfactant properties. The compounds may be used to replace non-polymerizible surfactants in emulsion polymerization reactions, and preferably in those reactions which result in adhesive polymers which are suitable for surgical and medical use. Methods for preparing the compounds and pressure sensitive adhesives formed by copolymerization of the compounds with other acrylate monomers are also described.

대표청구항 ▼

An adhesive emulsion polymer of monomers consisting essentially of one or more acrylic monomers selected from the group consisting of acrylic and methacrylic acids or alkyl esters or hydroxyalkyl esters or amides thereof and one or more monomers of the formula (I): CH2〓C(R)－COO－(CH2－CH(CH3)－O－)x－(CH

An adhesive emulsion polymer of monomers consisting essentially of one or more acrylic monomers selected from the group consisting of acrylic and methacrylic acids or alkyl esters or hydroxyalkyl esters or amides thereof and one or more monomers of the formula (I): CH2〓C(R)－COO－(CH2－CH(CH3)－O－)x－(CH2－CH2－O)y－OC－A－COOH or a salt thereof, wherein R is H or CH3, x is an integer from 2 to 20, y is an integer from 0 to 5, and A is an alkylene, alkenyl or phenylene radical such that A(COOH)2 is a dibasic acid capable of forming an anhydride A(CO2)O. A polymer according to claim 1 which is a pressure-sensitive adhesive polymer of monomers which comprise 39 to 59% by weight of n-butyl acrylate, 39 to 59% by weight of 2-ethylhexyl acrylate, 0.3 to 5% by weight of acrylamide or hydroxyethyl methacrylate and 1 to 5% by weight of a methacrylyl poly(oxypropylene) succinate mono ester containing an average of 7 oxypropylene units per molecule or the ammonium salt thereof. An adhesive surgical or medical dressing comprising a pressure-sensitive adhesive polymer according to claim 2.