초록 ▼

A process for the continuous preparation of finely divided homopolymers and copolymers of ethene by catalytic polymerization in a circular tube reactor using a liquid alkane as reaction medium in which the ethene or ethene/comonomer mixture to be polymerized is present in dissolved form and the poly

A process for the continuous preparation of finely divided homopolymers and copolymers of ethene by catalytic polymerization in a circular tube reactor using a liquid alkane as reaction medium in which the ethene or ethene/comonomer mixture to be polymerized is present in dissolved form and the polymer formed is present in suspended form and running the reaction mixture as a cycle stream to which the feed materials are added by bleeding in and from which the polymer formed is withdrawn by bleeding out reaction mixture, comprising (a) maintaining the mean concentration Cm of polymer in the cycle stream at a value within a certain range and (b) effecting the bleeding out of reaction mixture at a point of the cycle stream at which the concentration of polymer has a value which is lower than the mean concentration Cm by a distinct and definite amount.

대표청구항 ▼

A process for the continuous preparation of a finely divided homopolymer of ethene or copolymer of ethene with a minor amount of C3-C8-a53,477) of from 0.3 to 1.5 mm and a bulk density (by DIN 53,468) of from 0.400 to 0.600 g/cm3 by catalytic polymerization at from 60°to 100°C. and under a total pre

A process for the continuous preparation of a finely divided homopolymer of ethene or copolymer of ethene with a minor amount of C3-C8-a53,477) of from 0.3 to 1.5 mm and a bulk density (by DIN 53,468) of from 0.400 to 0.600 g/cm3 by catalytic polymerization at from 60°to 100°C. and under a total pressure of from 30 to 50 bar in a circular tube reactor using a C4-C8-alkane which is present in liquid form as reaction medium in which the ethene or ethene/comonomer mixture to be polymerized is present in dissolved form and the polymer formed is present in suspended form, and running the reaction mixture as a cycle stream to which the feed materials are added by bleeding in and from which the polymer formed is withdrawn by bleeding out reaction mixture, which comprises (a) maintaining the mean concentration Cm of polymer in the cycle stream at a value within the range from 0.40 to 0.70 g of polymer per g of reaction mixture and (b) effecting the bleeding out of reaction mixture at a point of the cycle stream where the concentration of polymer has a value within the range from 0.50×Cm to 0.70×Cm.