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A method for coating single crystal whiskers of carbides, nitrides or carbonitrides of Ti, Zr, Hf, V, Nb, Ta, or W with one or more layers of a carbide, nitride or carbonitride of Ti, Zr, Hf, Nb, Ta, or W, or oxides of Al, Zr, or Hf. The method involves flowing past the whiskers at about 1025°-1125°

A method for coating single crystal whiskers of carbides, nitrides or carbonitrides of Ti, Zr, Hf, V, Nb, Ta, or W with one or more layers of a carbide, nitride or carbonitride of Ti, Zr, Hf, Nb, Ta, or W, or oxides of Al, Zr, or Hf. The method involves flowing past the whiskers at about 1025°-1125°C. a mixture of hydrogen and one of the following gaseous mixtures: Group I comprises one or more of Ti, Zr, Hf, Nb, Ta, or W hhalides mixed with one or more of N2, NH3, or suitable free carbon forming aliphatic hydrocarbons. The atomic ratio of carbon and/or nitrogen to metal is about 5:1-16:1, and the volume ratio of hydrocarbon and/or N2 and/or NH3 to H2 is about 1:5 to 1:20. Group II comprises one or more Al, Zr, or Hf halides mixed with one or more suitable oxygen donor gases, in proportions selected to form the desired metal oxide.

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A process for producing coated metal carbide, nitride, or carbonitride whiskers comprising the step of flowing past whiskers comprising single crystals of a carbide, nitride, or carbonitride of Ti, Zr, Hf, V, Nb, Ta, and W, having an aspect ratio of length to diameter of about 5:1 to 500:1, and a di

A process for producing coated metal carbide, nitride, or carbonitride whiskers comprising the step of flowing past whiskers comprising single crystals of a carbide, nitride, or carbonitride of Ti, Zr, Hf, V, Nb, Ta, and W, having an aspect ratio of length to diameter of about 5:1 to 500:1, and a diameter of about 0.5-10 microns, in a reaction chamber sealed from the ambient atmosphere and essentially free from undesired contaminants, and heated to an operating temperature of about 1025°-1125°C., a gaseous reactant mixture comprising hydrogen and the gases of Group I or Group II or mixture thereof; wherein Group I comprises a mixture of one or more metal halide gases selected from the group consisting of halides of Ti, Zr, Hf, Nb, Ta, and W, and one or more gases selected from the group consisting of nitrogen, ammonia, and aliphatic hydrocarbon pyrolyzable at the operating temperature to form free carbon, in an atomic ratio of carbon plus nitrogen to metal of about 5:1 to 16:1 and a volume ratio of hydrocarbon, plus nitrogen plus ammonia to hydrogen of about 1:5 to 1:20; and Group II comprises a mixture of one or more gases selected from the halides of Al, Zr, and Hf, and one or more gases selected from the group consisting of oxygen donor gases reacting with the Al, Zr, and Hf halides at the operating temperature to form one or more oxides of Al, Zr, and Hf, in proportions selected to react to form the oxides; the flowing mixture of reactant gases being maintained at a suitable linear velocity for a time sufficient to deposit an adherent coating of a thickness between a monomolecular layer and about one-half the diameter of the whisker, on the whisker surfaces of one or more layers of a refractory material selected from the group consisting of carbides, nitrides, and carbonitrides of Ti, Zr, Hf, Nb, Ta, and W, and oxides of Al, Zr, and Hf, or a mixture or solid solution thereof, wherein the material of each layer is different from the material on which it is deposited.