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A cryogenic technique for recovering ethene from a gaseous mixture containing methane, ethane, etc. Operating methods and apparatus are provided for passing the gas feed through a chilling train having a series of dephlegmator-type exchange units to condense liquid rich in ethene and ethane, while s

A cryogenic technique for recovering ethene from a gaseous mixture containing methane, ethane, etc. Operating methods and apparatus are provided for passing the gas feed through a chilling train having a series of dephlegmator-type exchange units to condense liquid rich in ethene and ethane, while separating a major portion of methane and lighter gas. A multizone demethanizer removes condensed methane from the C 2 fraction to provide multiple methane free liquid streams of varying ethene to ethane ratio at least one of which is essentially C 3 free.

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1. A cryogenic separation process for recovering C 2 hydrocarbons from a hydrocarbon feedstream comprising methane, ethene and ethane, said process comprising: (a) introducing said hydrocarbon feedstream into a dephlegmation zone at cryogenic temperatures; (b) dephlegmating said hydrocarbon feed

1. A cryogenic separation process for recovering C 2 hydrocarbons from a hydrocarbon feedstream comprising methane, ethene and ethane, said process comprising: (a) introducing said hydrocarbon feedstream into a dephlegmation zone at cryogenic temperatures; (b) dephlegmating said hydrocarbon feedstream into a primary methane-rich gas stream and a primary liquid condensate stream rich in C 2 + hydrocarbon components and containing a minor amount of methane; (c) passing said primary liquid condensate stream to a moderately low cryogenic temperature primary demethanizer unit and separating said primary liquid condensate stream into a C 2 + liquid bottoms stream and intermediate methane-rich overhead vapor stream; and (d) further separating said intermediate methane-rich overhead vapor stream from the moderately low cryogenic temperature primary demethanizer unit in an ultra-low temperature final demethanizer unit operating below about 175 psia to recover a first liquid ethene-rich hydrocarbon product stream and a final demethanizer ultra-low temperature vapor stream; whereby total energy requirements for refrigeration to separate the C 2 + hydrocarbon from the C 1 and lighter components are low. 2. A cryogenic separation process as defined in claim 1 wherein said ultra-low temperature demethanizer unit operates at below about 160 psia. 3. A cryogenic separation process as defined in claim 2 wherein said hydrocarbon feedstream is dried. 4. A cryogenic separation process as defined in claim 3 wherein said hydrocarbon feedstream comprises a gaseous hydrocarbon cracking effluent comprising from about 10 to about 50 mole percent ethene, from about 5 to about 20 mole percent ethane, from about 10 to about 40 mole percent methane and up to about 10 mole percent C 3 hydrocarbons. 5. A cryogenic separation process as defined in claim 3 wherein said hydrocarbon feedstream is compressed to a process pressure of from about 2500 kPa to about 3700 kPa prior to step (a). 6. A cryogenic separation process as defined in claim 3 wherein said hydrocarbon feed is prechilled in at least one heat exchanger prior to step (a). 7. A cryogenic separation process as defined in claim 1 wherein said dephlegmation zone comprises at least two serially connected dephlegmators. 8. A cryogenic separation process as defined in claim 7 including the step of: (b)(i) further dephlegmating said primary methane-rich gas stream from step (b) in a second dephlegmator to produce a secondary liquid condensate stream and a secondary methane-rich gas stream. 9. A cryogenic separation process as defined in claim 8 wherein step (d) also comprises effecting a further separation of the secondary liquid condensate stream from step (b)(i) in said ultra-low temperature final demethanizer unit. 10. A cryogenic separation process as defined in claim 8 wherein step (d) comprises (d)(i) contacting said intermediate methane-rich overhead vapor stream from the moderately low cryogenic temperature primary demethanizer unit and said secondary liquid condensate stream from the second dephlegmator in a countercurrent liquid-gas contact zone; and (d)(ii) feeding the resulting methane-depleted liquid stream from said countercurrent liquid-gas contact zone to a lower portion of the ultra-low temperature final demethanizer and feeding the resulting methane-enriched vapor from said countercurrent liquidgas contact zone to an upper portion of said ultra-low temperature final demethanizer; wherein said ultra-low temperature final demethanizer unit is operated at a pressure below about 160 psia; to recover a liquid ethene-rich hydrocarbon product stream and a final demethanizer ultra-low temperature vapor stream. 11. A cryogenic separation process as defined in claim 10 wherein said countercurrent liquid-gas contact zone comprises a packed column. 12. A cryogenic separation process as defined in claim 1 wherein said dephlegmation zone comprises two or more serially connected dephlegmators. 13. A cryogenic separation process as defined in claim 12 including the steps of (b)(i) further dephlegmating said primary methane-rich gas stream from step (b) in a second dephlegmator to produce a secondary liquid condensate stream and a secondary methane-rich gas stream; and (b)(ii) further dephlegmating said secondary methane-rich gas stream from step (b)(i) in a third dephlegmator to produce a third liquid condensate stream and a third methane-rich gas stream. 14. A cryogenic separation process as defined in claim 13 wherein step (d) also comprises effecting a further separation of secondary liquid condensate stream from the second dephlegmator and the third liquid condensate stream from the third dephlegmator in said ultra-low temperature final demethanizer unit. 15. A cryogenic separation process as defined in claim 14 wherein step (d) comprises: (d)(i) contacting said intermediate methane-rich overhead vapor stream from the moderately low cryogenic temperature primary demethanizer unit and said secondary liquid condensate stream from the second dephlegmator in a countercurrent liquid-gas contact zone; (d)(ii) feeding the resulting methane-depleted liquid stream from said countercurrent liquid-gas contact zone to a lower portion of the ultra low temperature final demethanizer and feeding the resulting methane-enriched vapor stream from said countercurrent liquid-gas contact zone to an upper portion of said ultra-low temperature final demethanizer; and (d)(iii) feeding the third liquid condensate stream to said ultra-low temperature final demethanizer at a point above the feedpoint of said resulting methane-enriched vapor stream. 16. A cryogenic separation process as defined in claim 15 wherein said countercurrent liquid gas contact zone comprises a packed column. 17. A cryogenic separation process as defined in claim 13 comprising the further step of separating the third methane-rich gas stream into a fourth overhead vapor stream and a fourth liquid bottoms stream and delivering the fourth liquid bottoms stream to the ultra low temperature final demethanizer. 18. A cryogenic separation process as defined in claim 17 comprising the further step of expanding a portion of the third methane rich gas from the third dephlegmator in an expansion turbine. 19. A cryogenic separation process as defined in claim 18 comprising the further step of expanding the final demethanizer ultra-low temperature vapor stream in an expansion turbine. 20. A cryogenic separation process as defined in claim 19 wherein the temperature and pressure at the first dephlegmator is about -35° F. and 500 psia; the temperature and pressure at the second dephlegmator is about -85° F. and 495 psia; the temperature and pressure at the third dephlegmator is about -145° F. and 480 psia; the temperature and pressure in the moderately low cryogenic temperature primary demethanizer is about -44° F. and 500 psia; the temperature and pressure in the ultra low cryogenic temperature final demethanizer is about -150° F. and 150 psia; the temperature and pressure in the countercurrent liquid-gas contact zone is about -85° F. and 475 psia; the temperature and pressure in the separation drum downstream of the third dephlegmator is about -225° F. and 480 psia; the temperature and pressure in the final gas separation drum is about -60° F. and 475 psia; the temperature and pressure of the third methane rich gas from the third dephlegmator entering the expansion turbine is about -100° F. and 475 psia; and the temperature and pressure in the methane product line is about 50° F. and 70 psia. 21. A cryogenic separation process as defined in claim 1 comprising the additional steps of (e) further fractionating the C 2 + bottoms stream from said moderately low cryogenic temperature primary demethanizer unit to remove ethane and heavier hydrocarbons and to provide a second ethene-rich product stream; and (f) fractionating said second ethene-rich product stream and the first ethene-rich product stream from said ultra-low temperature final demethanizer unit to obtain a substantially pure ethene product. 22. A cryogenic separation process as defined in claim 1 wherein the primary cryogenic temperature ranges from about 236° to about 270° K., the moderately low cryogenic temperature ranges from about 197° to about 235° K. and the ultra-low cryogenic temperature ranges from about 172° to about 196° K. 23. A cryogenic separation process as defined in claim 22 wherein a closed cycle propylene refrigeration loop system is employed as a moderately low temperature refrigerant and a closed cycle ethylene refrigeration loop system is employed as an ultra-low temperature refrigerant. 24. An apparatus for performing cryogenic separation of a hydrocarbon feedstream comprised of methane, ethane, ethylene which comprises: (a) means for dephlegmating the hydrocarbon feedstream; (b) means for demethanizing liquid from the means for dephlegmating the hydrocarbon feedstream comprising (i) a moderately low cryogenic temperature primary demethanizer unit serially connected to (ii) an ultra-low temperature final demethanizer unit operated at below about 160 psia; and (c) means for delivering a primary liquid condensate stream from said means for dephlegmating to said means for demethanizing. 25. An apparatus as defined in claim 24 wherein said means for dephlegmating the hydrocarbon feedstream comprises at least two serially connected dephlegmators. 26. An apparatus as defined in claim 25 further comprising a means for delivering a second liquid condensate stream from the second dephlegmator to said ultra-low temperature final demethanizer unit. 27. An apparatus as defined in claim 25 further comprising a means for countercurrently contacting a second liquid condensate stream from the second dephlegmator and an overhead vapor stream from said moderately low cryogenic temperature primary demethanizer and a means for operatively connecting said countercurrent contacting means to said ultra-low temperature final demethanizer unit. 28. An apparatus as defined in claim 27 wherein said means for dephlegmating the hydrocarbon feedstream comprises three serially connected dephlegmators. 29. An apparatus as defined in claim 28 further comprising a means for delivering a third liquid condensate stream from the third dephlegmator to an upper portion of said ultra-low temperature final demethanizer unit. 30. An apparatus as defined in claim 29 further comprising a hydrogen-methane separating means operatively connected to a third overhead vapor stream from said third dephlegmator. 31. An apparatus as defined in claim 30 further comprising a means for delivering a liquid stream from said hydrogen-methane separating means to said ultra-low temperature final demethanizer unit. 32. An apparatus as defined in claim 31 further comprising a means for expanding a portion of the third overhead vapor stream. 33. An apparatus as defined in claim 32 further comprising a means for expanding a final demethanizer ultra-low temperature vapor stream from the said ultra-low temperature final demethanizer unit. 34. An apparatus as defined in claim 27 wherein said means for operatively connecting said countercurrent contacting means to said ultra-low temperature final demethanizer unit further comprises a means for reducing pressure. 35. An apparatus as defined in claim 29 wherein said means for delivering a third liquid condensate stream from the third dephlegmator to an upper portion of said ultra-low temperature final demethanizer unit further comprises a means for reducing pressure. 36. An apparatus as defined in claim 31 wherein said means for delivering a liquid stream from said hydrogen-methane separating means to said ultra-low temperature final demethanizer unit further comprises a means for reducing pressure. 37. A cryogenic separation method for recovering C 2 + hydrocarbons from cracked hydrocarbon feed gas comprising methane, ethene and ethane, wherein cold pressurized gaseous streams are separated in a plurality of dephlegmator units, each of said dephlegmator units being operatively connected to accumulate condensed liquid in a lower dephlegmator drum vessel by gravity flow from an upper dephlegmator heat exchanger comprising a plurality of vertically disposed indirect heat exchange passages through which gas from the lower drum vessel passes in an upwardly direction for cooling with refrigerant fluid by indirect heat exchange within said heat exchange passages, whereby gas flowing upwardly is partially condensed on vertical surfaces of said passages to form a reflux liquid in direct contact with the upwardly flowing gas stream to provide a condensed stream of cooler liquid flowing downwardly and thereby enriching condensed dephlegmator liquid gradually with C 2 + hydrocarbon components; comprising the steps of introducing dry feed gas into a primary dephlegmation zone having a plurality of serially connected, sequentially colder dephlegmator units for separation of feed gas into a primary methane-rich gas stream recovered at low temperature and at least one primary liquid condensate stream rich in C 2 + hydrocarbon components and containing a minor amount of methane; passing at least one primary liquid condensate stream from the primary dephlegmation zone to serially connected demethanizer fractionators, wherein a moderately low cryogenic temperature is employed in a first demethanizer fractionator unit to recover substantially all of the methane from the primary liquid condensate stream in a first demethanizer overhead vapor stream and to recover a first C 2 + liquid demethanizer bottoms stream substantially free of methane; and further separating at least a portion of the first demethanizer overhead vapor stream in an ultra-low temperature final demethanizer fractionator unit operating at a pressure below about 160 psia; to recover a liquid ethene-rich predominantly C 2 hydrocarbon crude product stream and a final demethanizer ultra-low temperature overhead vapor stream substantially free of C 2 + hydrocarbons. 38. The process of claim 37 further comprising a countercurrent direct stream contact unit, operatively connected between the primary and secondary demethanizer zones, the liquid from said countercurrent contact zone is directed to a lower stage of the secondary demethanizer zone and the vapor from said countercurrent contact zone is directed to a higher stage of the secondary demethanizer zone. 39. The process of claim 38 wherein said serially connected rectification units include at least one intermediate rectification unit for partially condensing an intermediate liquid stream from primary rectification overhead vapor prior to final serial rectification unit; and contacting at least a portion of said first demethanizer overhead vapor stream with said intermediate liquid stream directly in a countercurrent contact zone operatively connected between the primary and secondary demethanizer zones, with methane-enriched vapor from said countercurrent contact zone being directed to an upper portion of the secondary demethanizer zone. 40. The process of claim 39 wherein said serially connected rectification units include two intermediate rectification units for partially condensing first and second progressively colder intermediate liquid streams respectively from primary rectification overhead vapor prior to a final serial rectification unit; fractionating the first intermediate liquid stream in the primary demethanzier zone; and fractionating the second intermediate liquid stream in the secondary low pressure demethanizer zone. 41. The process of claim 40 including the step of contacting at least a portion of said first demethanizer overhead vapor stream with said second intermediate liquid stream in a countercurrent contact zone operatively connected between the primary and secondary demethanizer zones, with ethene-rich liquid from said countercurrent contact zone being directed to an upper portion of the secondary low pressure demethanizer zone. 42. The process of claim 41 wherein said moderately low temperature coolant is maintained at a temperature of about 235° K. to 290° K. and the ultra low temperature coolant is maintained below 235° K. 43. The process of claim 42 wherein pressurized moderately low temperature refrigerant is condensed in a refrigerant cycle in heat exchange relationship with a primary demethanizer reboiler unit to heat liquid methanized bottoms therein. 44. The process of claim 43 including a closed loop moderately low temperature source of primary refrigerant consisting essentially of propylene and a separate closed loop ultra low temperature refrigerant source of secondary refrigerant consisting essentially of ethylene.