[특허]Aqueous crosslinkable resin dispersions, method of their production and use thereof

[미국특허] Aqueous crosslinkable resin dispersions, method of their production and use thereof 원문보기

IPC분류정보
국가/구분	United States(US) Patent 등록
국제특허분류(IPC7판)	C08K-003/34
출원번호	US-0708368 (1991-05-31)
우선권정보	JP-0314069 (1987-12-14); JP-0314071 (1987-12-14); JP-0003089 (1988-01-12); JP-0026674 (1988-02-09); JP-0026675 (1988-02-09); JP-0044337 (1988-02-29); JP-0103396 (1988-04-25); JP-0117065 (1988-05-16)
발명자 / 주소	Izubayashi Masuji (Nishinomiya JPX) Yoshida Masatoshi (Osaka JPX) Matsunaga Toshiaki (Suita JPX) Hori Kohei (Takarazuka JPX) Kikuta Teruo (Nagaokakyo JPX) Nakano Shiro (Nichinan JPX) Hatta Hidetoshi
출원인 / 주소	Nippon Shokubai Co., Ltd. (Osaka JPX 03) Oji Paper Co., Ltd. (Tokyo JPX 03)
인용정보	피인용 횟수 : 28 인용 특허 : 0

초록 ▼

The present invention yields a coating film excellent in adhesion, water resistance, solvent resistance and durability. A compound having a carboxyl group and a long-chain alkylthio group or a salt thereof is used as an emulsifier and emulsion polymerization is carried out using a polymerizable monomer or monomers having, within their molecule, a group reactive with a carboxyl group as raw materials for emulsion polymerization, whereby the resin produced by emulsion polymerization and the emulsifier react with each other efficiently on the occasion of film formation and form a crosslinked structure. When a compound having a polymerizable unsaturated group in addition to the carboxyl group and long-chain alkylthio group or a salt thereof is used as the emulsifier, not only the above-mentioned crosslinked structure is formed but also the polymerizable unsaturated group in the emulsifier will react with the unsaturated group in the polymerizable monomer or monomers in the manner of grafting. As a result, the compatibility between the emulsifier and the emulsion-polymerized resin is improved.

대표청구항 ▼

An aqueous crosslinkable resin dispersion characterized by its being obtained by emulsion-polymerizing in an aqueous medium a monomer composition I composed of 0.1-40% by weight of at least one polymerizable monomer (a) having, within its molecular structure, a polymerizable double bond and an epoxy, aziridine or oxazoline group and 60-99.9% by weight of one or more other polymerizable monomers (b) copolymerizable with the polymerizable monomer (a), the sum total of the polymerizable monomers (a) and (b) being 100% by weight, in the presence of a water-soluble or water-dispersible emulsifier or emulsifiers selected from either one or both of the groups (P) and (Q) below: (P) polymers IIa having a terminal alkylthio group and an acid value of not less than 200 obtained by polymerizing a polymerizable monomer composition A containing an unsaturated carboxylic acid as an essential component thereof, in the presence of an alkylmercaptan B having 6-18 carbon atoms, or salts thereof; (Q) polymers IIb having a terminal alkylthio group and an acid value of not less than 200 obtained by polymerizing a polymerizable monomer composition A containing an unsaturated carboxylic acid as an essential component thereof, in the presence of an alkylmercaptan B having 6-18 carbon atoms, and further reacting the resulting polymer with at least one polymerizable monomer (c) having, within its molecular structure, a group reactive with a carboxyl group, or salts thereof.

이 특허를 인용한 특허 (28) 인용/피인용 타임라인 분석

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Kikuta Teruo (Nagaokakyo JPX) Kono Katsuyuki (Takatsuki JPX), Aqueous resin dispersion for heat-sensitive recording material and heat-sensitive recording material using the same.
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Kinoshita, Sachiko; Yokoyama, Hiromi; Koike, Takaaki; Miyajima, Koichiro; Moroishi, Yasuyuki; Ikeda, Shingo, Binder composition for non-aqueous secondary battery electrode.
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Stephens Michael L. ; Efner Howard F., Cement composition and process therewith.
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Schottman,Thomas C.; Hennessey,Patrick M.; Gruening,Rainer, Coating composition for multiple hydrophilic applications.
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Parker, Mark A; Cannon, David Keith, Coating compositions and methods, and articles coated with same.
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Wakizaka, Yasuaki; Sanbayashi, Masayuki; Tanaka, Jun, Coating material and use thereof.
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Zhu Dong-Wei, Crosslinked fluoroaliphatic coating composition having oxazoline or oxazine moieties and integrated colloidal silica.
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Hurley Steven M. ; Hansen Frederick C., Emulsion polymerization using polymeric surfactants.
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Chiou Shang Jaw ; Sheng Miao-Hsun Li, Grafted polymer composition.
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Shane, Kyle, In-mold-coated automotive interior and other products, and methods for manufacturing same.
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Shane, Kyle, In-mold-coated automotive interior and other products, and methods for manufacturing same.
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Ruckenstein Eli ; Li Hangquan,CNX, Methods for preparing polymer blends.
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Hu, Jinlian; Zeng, Fang; Li, Pei, Methods of manufacturing deodorants, and deodorants resulting thereof.
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Ryang Hong-Son ; Chung Young Jin ; Snyder ; II Joseph T. ; Sung An-Min Jason, Oxygen plasma resistant polymer for electrical devices.
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Russell Frederick Ross ; Ali Yahiaoui, Paper machine substrates resistant to contamination by adhesive materials.
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Ryang Hong-Son ; Chung Young Jin ; Snyder ; II Joseph T. ; Sung An-Min Jason, Polymers made with metal oxide sols.
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Geissler Ulrich,DEX, Polyvinyl ester dispersions and methods for their preparation.
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Lion, Jean-Pierre, Process for continuous production of a flocked and dyed cloth backing.
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Matthews, James Robert, Process of making a coated substrate by crosslinking nanoparticles.
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Ross, Russell Frederick; Yahiaoui, Ali, Process of making paper machine substrates resistant to contamination by adhesive materials.
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Englert,Mark H.; Immordino, Jr.,Salvatore C., Reduced dust acoustic panel.
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Adam, Johannes; Roscher, Christof; Eger, Christian; Adebahr, Thorsten; Wieczorreck, Robert; Pyrlik, Manfred, Silicon dioxide dispersion.
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Aihara, Hideo; Sawamura, Ichiro; Tohmatsu, Hiroshi; Okada, Shinji; Watari, Hirokazu, Thermosensitive recording material.
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[미국특허] Aqueous crosslinkable resin dispersions, method of their production and use thereof 원문보기

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