IPC분류정보
| 국가/구분 |
United States(US) Patent
등록
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| 국제특허분류(IPC7판) |
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| 출원번호 |
US-0209605
(1994-03-09)
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발명자
/ 주소 |
- Steinberg Meyer (Melville NY) Grohse Edward W. (Port Jefferson NY)
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| 출원인 / 주소 |
- Hydrocarb Corporation (Port Jefferson Station NY 02)
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| 인용정보 |
피인용 횟수 :
21 인용 특허 :
0 |
초록
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A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to im
A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.
대표청구항
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A continuous, integral cyclical process for the conversion of a bituminous or lignite coal feedstock to particulate carbon and methanol products, used separately and/or in combination as a pollutant-free liquid slurry product or fuel, which comprises: (a) reacting the feedstock in a first stage hydr
A continuous, integral cyclical process for the conversion of a bituminous or lignite coal feedstock to particulate carbon and methanol products, used separately and/or in combination as a pollutant-free liquid slurry product or fuel, which comprises: (a) reacting the feedstock in a first stage hydropyrolysis reaction zone maintained at a pressure within the range of from 10 to 200 atmospheres and at temperatures within the range of approximately 600°to 1200°C., with a hydrogen-rich gas stream containing, by volume, from about 5 to 30% methane, 50 to 90% hydrogen, 0.5 to 30% carbon monoxide, and 0 to 10% water plus carbon dioxide, to produce a methane-rich gas stream containing, by volume, from about 20 to 60% methane, 25 to 60% hydrogen, 0.5 to 15% carbon monoxide, and 1 to 40% water plus carbon dioxide; (b) decomposing the methane in the methane-rich gas stream in a second stage methane pyrolysis reaction zone, maintained at substantially the same pressure as the hydropyrolysis reaction zone in step (a) but at higher temperatures, ranging from 800°to 1400°C., to produce the particulate carbon product and a hydrogen-rich gas stream containing, by volume, from about 5 to 30% methane, 50 to 90% hydrogen, 0.5 to 30% carbon monoxide, and 0 to 10% water plus carbon dioxide; (c) passing the hydrogen-rich gas stream through a catalytic conversion zone maintained at substantially the same pressure as in the hydropyrolysis and methane pyrolysis zones, but at a lower temperature, ranging from 200°to 300°C., to catalytically convert the carbon monoxide, carbon dioxide and hydrogen contained therein to a methanol-rich, carbon monoxide-lean gas stream; (d) separating the methanol product from the methanol-rich, carbon monoxide-lean gas stream, leaving a methanol-lean gas stream; (e) separating and recovering the particulate carbon product and the methanol product separately or as a combined liquid slurry product; (f) directly recycling at least part of the methanol-lean gas stream from step (d) to step (a) for further hydropyrolysis; and (g) removing any remaining portion of the methanol-lean gas stream from the process; the temperatures and pressures in the respective reaction zones being so regulated as to maintain an atomic hydrogen/oxygen ratio in each of the hydrogen-rich and methane-rich gas streams in excess of 4.
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