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특허 상세정보

Catalytic production of aryl alkyl hydroperoxides by polynuclear transition metal aggregates (LAW229

국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판) C07C-409/08    C07C-409/10   
미국특허분류(USC) 568/575 ; 568/569 ; 568/573 ; 568/574
출원번호 US-0402077 (1995-03-10)
발명자 / 주소
출원인 / 주소
인용정보 피인용 횟수 : 10  인용 특허 : 0
초록

A method is provided for preparing organic hydroperoxides by oxidizing aryl alkyl hydrocarbons having a benzylic hydrogen with an oxygen containing gas using as a catalyst an oxo (hydroxo) bridged tetranuclear metal complex having a mixed metal core, one metal of the core being a divalent metal selected from Zn, Cu Fe, Co, Ni, Mn or mixtures thereof and another metal being a trivalent metal selected from In, Fe, Mn, Ga, and Al.

대표
청구항

A method for oxidizing an aryl alkyl hydrocarbon to an organic hydroperoxide comprising: contacting an aryl alkyl hydrocarbon having a benzylic hydrogen with an oxygen containing gas and a catalytically effective amount of an oxo(hydroxo) bridged tetranuclear metal complex having a mixed metal core, one metal of the core being a divalent metal selected from Zn, Cu, Fe, Co, Ni, Mn or mixtures thereof and another metal being a trivalent metal selected from In, Fe, Mn, Ga and Al or mixtures thereof.

이 특허를 인용한 특허 피인용횟수: 10

  1. Bond Jeffrey Evans ; Gorun Sergiu Mircea ; Schriver George William ; Stibrany Robert Timothy ; Vanderspurt Thomas Henry ; Via Grayson Hall ; Zhang Baoshan ; Dakka Jihad Mohammed,BEX. Catalytic production of aryl alkyl hydroperoxides by polynuclear transition metal aggregates. USP1999075922920.
  2. Vanderspurt, Thomas; Cordatos, Harry. Catalytic treatment of fuel to impart coking resistance. USP2010067744827.
  3. Spadaccini,Louis J.; Kaslusky,Scott; McLaughlin,Robert A.. Extended operability aircraft fuel delivery system. USP2007067231768.
  4. Spadaccini,Louis J.; Kaslusky,Scott; McLaughlin,Robert A.. Extended operability aircraft fuel delivery system. USP2006087093437.
  5. Spadaccini,Louis J.; Huang,He; Bertuccioli,Luca; Bayt,Robert L.. Gas turbine cooling system. USP2007067231769.
  6. Spadaccini,Louis J.; Huang,He; Sobel,David R.. Method of suppressing coke in endothermic fuel processing. USP2008027334407.
  7. Brandvold,Timothy A.; Lewis,Gregory J.; King,Lisa M.; Brewer,Lawrence E.. Process and catalyst for producing hydroperoxides. USP2008047361792.
  8. Brandvold,Timothy A.; Lewis,Gregory J.; King,Lisa M.; Brewer,Lawrence E.. Process and catalyst for producing hydroperoxides. USP2006057038090.
  9. Gosling,Christopher D.; Gatan,Ronald M.; Barger,Paul T.. Process for producing hydroperoxides. USP2007117297253.
  10. Dakka Jihad Mohammed,BEX ; Mathys Georges Marie Karel,BEX ; Goris Hans Karel Theresia,BEX. Process for the manufacture of oxygenates. USP2001026191308.