Cure controlled catalyzed mixtures of epoxy resins and curing agents containing mesogenic moieties
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C08G-059/06
C08G-059/10
C08L-063/00
C08L-063/02
출원번호
US-0457070
(1995-06-01)
발명자
/ 주소
Earls Jimmy D. (Lake Jackson TX) Hefner
Jr. Robert E. (Lake Jackson TX) Bertram James L. (Lake Jackson TX) Walker Louis L. (Clute TX)
출원인 / 주소
The Dow Chemical Company (Midland MI 02)
인용정보
피인용 횟수 :
28인용 특허 :
0
초록▼
Curable compositions containing (A) one or more epoxy resins, one (B) or more curing agents and (C) one or more cure controlling catalysts wherein at least one of components (A) or (B) or both components (A) and (B) contain a mesogenic moiety are prepared. These curable compositions permit processin
Curable compositions containing (A) one or more epoxy resins, one (B) or more curing agents and (C) one or more cure controlling catalysts wherein at least one of components (A) or (B) or both components (A) and (B) contain a mesogenic moiety are prepared. These curable compositions permit processing at higher temperatures and improved properties. They are useful in the preparation of coatings, castings, electrical or laminates or composites and the like.
대표청구항▼
A curable composition comprising; (A) at least one epoxy resin having an average of more than one vicinal epoxide group per molecule; (B) at least one curing agent for said epoxy resin in an amount which provides from about 0.8 to about 1.5 equivalents of curing agent per epoxide group; and (C) abou
A curable composition comprising; (A) at least one epoxy resin having an average of more than one vicinal epoxide group per molecule; (B) at least one curing agent for said epoxy resin in an amount which provides from about 0.8 to about 1.5 equivalents of curing agent per epoxide group; and (C) about 0.00005 to about 0.1 mole per epoxide equivalent of a cure controlling catalyst represented by any of the following formulas: [Figure] ((L1)3NL)+W- wherein each L is independently a hydrocarbyl group or inertly substituted hydrocarbyl group having from 1 to about 18 carbon atoms, which group also can contain one or more oxygen, sulfur or nitrogen atoms or two of such L groups can combine to form a heterocyclic ring containing one or more atoms other than carbon atoms; each L1 is independently hydrogen or L; Z is nitrogen, phosphorus, sulfur or arsenic; W is a weak nucleophilic anion selected from the group consisting of BF4-, BCI4-, NO3-, F-, Cl－CH2－CH2－CO2－, HO－CH2－CH2－CO2-, SbF5-, SbCl5-,AsF4-, AsCl4-, FP(O)2(OH)-, (F)2PO(O)2-, F3B(OH)-, F2B(OH)2-and C1P(O)2(OH)-; and z has a value of zero or 1 depending on the valence of Z; wherein at least one epoxy resin of component (A) is an epoxy resin which contains at least one mesogenic moiety represented by any one or more of the following formulas: [Figure] Formula II [Figure] Formula V [Figure] [Figure] Formula VI [Figure] Formula IX wherein: each R is independently hydrogen or a monovalent hydrocarbyl or hydrocarbyloxy group having from one to about carbon atoms, a halogen atom, a nitro group, a nitrile group or a －CO－R2 group; R2 is hydrogen or a monovalent hydrocarbyl group having from one to about 10; n has a value of zero or one; each A is independently a direct single bond, a divalent hydrocarbyl group having from one to about carbon atoms, －O－, －CO－, －SO－, －SO2－, －S－, －S－S－, －CR1=CR1－, －C≡C－, －N〓N－, －CR1=N－, －N=CR1-, －O－CO－, －CO－O－, －S－CO－, －CO－S－, －NR1－CO－, －CO－NR1－, －CR1=N－N=CR1－, －CO－CR1=CR1－, －CR1=CR1－CO－, －CR1=N－O－OC－, －CO－O－N= CR1－, －CO－NR1－NR1－OC－, －CR1=CR1－O－OC－, －CO－O－CR1=CR1－, －O－CO－CR1=CR1－, －CR1=CR1－CO－O－, －(CHR1)n′－O－CO－CR1=CR1－, －CR1=CR1－CO－O－(CHR1)n′－, －(CHR1)n′－CO－O－CR1=CR1－, －CH1=CH1－O－CO－(CHR1)n′－, －CH2－CH2CO－O－, －O－OC－CH2－CH2－, －C≡C－C≡C－, －CR1=CR1－CR1=CR1－, －CR1=CR1－C≡C－, －C≡C－CR1=CR1－, －CR1=CR1－CH2－O－OC－, －CO－O－CH2－CR1=CR1, －O－CO－C≡C－CO－O－, －O－CO－CR1=CR1－CO－O－, －O－CO－CH2－CH2－CO－O－, －S－CO－CR1=CR1－CO－S－, －CO－CH2－NH－CO－, －CO－NH－CH2－CO－, －NH－C(－CH3)=CH－CO－, －CO－CH=C(－CH3)－NH－, －CR1=C(－Cl)－, －C(－Cl) =CR1－, －CR1=C(－CN)－, －C(－CN)=CR1－, －N=C(－CN)－, －C(－CN)=N－, －CR1=C(－CN)－CO－O－, －O－CO－C(－CN)=CR1－, [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] [Figure] or [Figure] each A″is a divalent hydrocarbyl group having from one to about 6 carbon atoms; each A1 is independently a －CO－, －O－CO－, －CO－O－, －CO－S－, －S－CO－, －CO－NR1－or －NR1－CO－; each R1 is independently hydrogen or a monovalent hydrocarbyl group having from one to about 6 carbon atoms; each R4 is independently hydrogen or a monovalent hydrocarbyl group having from one to about 3 carbon atoms; n′has a value of one or two; p has a value from zero to about 30; and p1 has a value of from one to about 30, which, optionally, has been subjected to either (a) the application of an electric field, (b) the application of a magnetic field, (c) drawing or shear forces, or (d) any combination thereof.
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이 특허를 인용한 특허 (28)
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