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Process swing adsorption processes for gas separation are carried out using overlapping pressure swing adsorption, feed gas repressurization and desorption steps. The adsorptive capacity of the system employed is increased, unit power consumption is decreased, and the overall efficiency of the opera

Process swing adsorption processes for gas separation are carried out using overlapping pressure swing adsorption, feed gas repressurization and desorption steps. The adsorptive capacity of the system employed is increased, unit power consumption is decreased, and the overall efficiency of the operation is enhanced.

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In a pressure swing adsorption process for the separation of the components of a feed gas mixture in an adsorption-desorption-repressurization cycle in an adsorption system having at least two adsorbent beds, each having a feed end and a product end, and containing adsorbent material capable of sele

In a pressure swing adsorption process for the separation of the components of a feed gas mixture in an adsorption-desorption-repressurization cycle in an adsorption system having at least two adsorbent beds, each having a feed end and a product end, and containing adsorbent material capable of selectively adsorbing a more readily adsorbable component from said feed gas, each bed, on a cyclic basis, undergoing a processing sequence comprising the following steps: (a) partial repressurization from a lower desorption pressure to an intermediate pressure by passing gas withdrawn from the product end of another bed in the system to the product end of each said bed for partial pressure equalization between each said bed and said another bed; (b) further partial repressurization from said intermediate pressure by passing product gas from the product end of another bed to the product end of each such bed, as in step (a) above, together with simultaneously introducing the feed gas mixture to the feed end of the bed for repressurization of each such bed to an upper adsorption pressure, said further partial repressurization, as in step (a) above, being terminated upon approaching full pressure equalization between the beds, with the introduction of the feed gas mixture to the feed end of the bed continuing to increase the pressure of the bed to an upper adsorption pressure; (c) introducing additional quantities of the feed gas mixture to the feed end of each such bed at the upper adsorption pressure, with the more readily adsorbable component being selectively adsorbed by the adsorbent material, and the less readily adsorbable component passing through each said bed and being recovered therefrom as a desired product gas stream; (d) introducing additional quantities of the feed gas mixture to the feed end of each such bed, as in step (c), with the passage of at least a part of the less readily adsorbable component recovered from the product end of each such bed being diverted from the product gas stream for bed purge purposes; (e) cocurrent depressurization from the upper adsorption pressure to said intermediate pressure by discharging gas from the product end of each said bed, the discharged gas being passed to the product end of another bed to be repressurized in step (a), for partial pressure equalization between the beds; (f) further partial depressurization from said intermediate pressure reached in step (e), by discharging gas from the product end of each said bed for passage to the product end of another bed, as in step (e) above, together with the simultaneous countercurrent depressurization of each said bed by discharging gas from the feed end thereof, said further partial depressurization being terminated upon approaching, as in step (b) above, said full pressure equalization between each said bed and said another bed; (g) further countercurrent depressurization of each said bed by withdrawing additional gas from the feed end thereof to reduce the pressure thereof to the lower desorption pressure and to discharge more readily adsorbable component from each said bed; (h) passing less readily adsorbable component recovered from the product end of another bed in the adsorption system and diverted for purge purposes to the product end of each said bed for passage therethrough as purge gas to facilitate the desorption and removal of said more readily adsorbable component from the feed end of each said bed; and (i) repeating the processing sequence of steps (a)-(h) as cyclic operation of the process in each said bed is continued, the time consumed by the pressure equalization of each said bed in steps (a) and (e), during which feed and exhaust blowers employed in the practice of the process are unloaded, is reduced by simultaneous, overlap steps (b) and (f), whereby the amount of feed gas processed in a given period of time is increased.