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Oxygenate analysis and control by Raman spectroscopy 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • G01J-003/44
출원번호 US-0449326 (1995-05-24)
발명자 / 주소
  • Cooper John B. (Virginia Beach VA) Wise Kent L. (Portsmouth VA) Welch William T. (Ashland KY) Sumner Michael B. (Huntington WV)
출원인 / 주소
  • Ashland Inc. (Ashland KY 02)
인용정보 피인용 횟수 : 21  인용 특허 : 18

초록

Oxygenated hydrocarbons can be predicted within ±0.2% wt or better, using Raman NIR spectroscopy and multivariate analysis, with optional fiberoptics multistreaming. The resulting signal can be used to control concentration of such compounds in product to desired levels.

대표청구항

A process comprising: a) irradiating a sample of a liquid mixture consisting essentially of liquid hydrocarbons and comprising one or more oxygenated component to produce Raman scattered radiation emitted from the sample; b) collecting Raman scattered radiation emitted from the sample; c) dispersing

이 특허에 인용된 특허 (18)

  1. Safinya Kambiz A. (Ridgefield CT) Tarvin Jeffrey A. (Brookfield Center CT), Apparatus and method for analyzing the composition of formation fluids.
  2. Carrabba Michael M. (Franklin MA) Rauh R. David (Newton MA), Apparatus for measuring Raman spectra over optical fibers.
  3. Maggard Steven M. (Barboursville WV) Welch William T. (Ashland KY), Determination of aromatics in hydrocarbons by near infrared spectroscopy.
  4. Maggard Steven M. (Huntington WV) Welch William T. (Ashland KY), Determination of aromatics in hydrocarbons by near infrared spectroscopy.
  5. Maggard Steven M. (Huntington WV) Welch William T. (Ashland KY), Determination of aromatics in hydrocarbons by near infrared spectroscopy and calibration therefor.
  6. Clarke Richard H. (Scituate MA), Hydrocarbon analysis based on low resolution raman spectral analysis.
  7. Maggard Steven M. (Lake Jackson TX), Indirect method for determining oxygenate content using near-infrared absorption spectra.
  8. Freeman David L. (Garland TX) Rockley Mark G. (Stillwater OK) Harville Donald G. (Grapevine TX), Method for quantitative analysis of core samples.
  9. Schulz Wolfgang W. (Lebanon NJ) Genowitz Mark W. (Phillipsburg NJ), Method for quantitatively determining the amount of saturates, olefins, and aromatics in a mixture thereof.
  10. Baylor Lewis C. (North Augusta SC) Buchanan Bruce R. (Aiken SC) O\Rourke Patrick E. (Martinez GA), Method for verification of constituents of a process stream just as they go through an inlet of a reaction vessel.
  11. Mullins Oliver C. (Ridgefield CT), Method of distinguishing between crude oils.
  12. Clarke Richard H. (Scituate MA) Tang Deming (Brighton MA), Methods and apparatus for determining hydrocarbon fuel properties.
  13. Maggard Steven M. (Huntington WV), Near infrared analysis of piano constituents and octane number of hydrocarbons.
  14. Maggard Steven M. (Huntington WV), Octane measuring process and device.
  15. Miemel Pentti (Jli FIX) Jaatinen Jarl (Helsinki FIX), Procedure for measuring contents of hydrocarbons in liquids containing such.
  16. Maggard Steven M. (Huntington WV), Process and apparatus for analysis of hydrocarbons by near-infrared spectroscopy.
  17. Maguire John F. (San Antonio TX), Remote spectroscopy for raman and brillouin scattering.
  18. Maggard Steven M. (Barboursville WV), Spectroscopic instrument calibration.

이 특허를 인용한 특허 (21)

  1. Allen Fritz Schreyer ; Zhao Jun ; Butterfield Danny S., Apparatus for measuring and applying instrumentation correction to produce a standard Raman spectrum.
  2. Smith Lee M. ; Benner Robert E., Compact and robust spectrograph.
  3. Antunovich, Jason J.; Hamfeldt, Arthur T.; Woods, Rodney J.; Shum, Sam C., Determining percent solids in suspension using Raman spectroscopy.
  4. Antunovich, Jason J.; Hamfeldt, Arthur T.; Woods, Rodney J.; Shum, Sam C., Determining percent solids in suspension using Raman spectroscopy.
  5. Antunovich, Jason J.; Hamfeldt, Arthur T.; Woods, Rodney J.; Shum, Sam C., Determining percent solids in suspension using raman spectroscopy.
  6. Gamble, Heather A.; Robbins, John C.; Mackay, Gervase I.; Schiff, Harold I., Development of a compact Raman spectrometer for detecting product interfaces in a flow path.
  7. Welch William T ; Bledsoe Roy R. ; Wilt Brian K. ; Sumner Michael B., Gasoline RFG analysis by a spectrometer.
  8. Martin, Gregory M.; Brown, James M.; Rose, Arthur H., Global crude oil quality monitoring using direct measurement and advanced analytic techniques for raw material valuation.
  9. Clarke, Lucas Lemar; Jett, Robert L., Laser induced fluorescence water measurement system for nuclear reactors.
  10. Welch,William T.; Bledsoe, Jr.,Roy R.; Wilt,Brian K., Method and apparatus for analysis of relative levels of biodiesel in fuels by near-infrared spectroscopy.
  11. Kaffka Karoly,HUX ; Jako Janos,HUX ; Domjan Gyula,HUX ; Valyi-Nagy Istvan,HUX ; Gyarmati Laszlo,HUX ; Godolle Laszlo,HUX, Method and apparatus for qualifying an object.
  12. Graeme Wm Scott, Method of determining fluid level and interface in a closed vessel.
  13. Wang Yung Xiang,JPX ; Dou Xiaoming,JPX, Method of optically measuring component in solution.
  14. Tubel, Paulo; Bidigare, Brian; Johnson, Michael; Harrell, John; Voll, Benn, Monitoring of downhole parameters and tools utilizing fiber optics.
  15. Tubel, Paulo; Bidigare, Brian; Johnson, Michael; Harrell, John; Voll, Benn, Monitoring of downhole parameters and tools utilizing fiber optics.
  16. Schmidt Gerald K. ; Tadano Ken, Preparation of alcohol-containing gasoline.
  17. Cooper John B ; Bledsoe ; Jr. Roy R ; Wise Kent L ; Sumner Michael B ; Welch William T ; Wilt Brian K, Process and apparatus for octane numbers and reid vapor pressure by Raman spectroscopy.
  18. Shabtai Joseph S. ; Zmierczak Wlodzimierz W. ; Chornet Esteban, Process for conversion of lignin to reformulated, partially oxygenated gasoline.
  19. Saby Claude-Alain,FRX, Process for tracking and monitoring a manufacturing unit and/or a near-infrared spectrometer by means of at least one i.
  20. Smith Lee M. ; Benner Robert E. ; Gray George R. ; Pan Ming-Wei ; Rallison Richard D., Raman spectroscopy apparatus and method using external cavity laser for continuous chemical analysis of sample streams.
  21. Rauch, Andrea L.; Murray, Richard C., Simulated moving bed systems for separation of para-xylene and processes for determining pump-around profiles of the simulated moving bed systems.
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