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A supported catalyst is prepared by depositing oxides of nickel and cobalt, with or without noble metals, on a sintered low surface area porous inert support, surface of which is precoated with an oxide of Be, Mg, Ca or a mixture thereof so that a protective layer of the alkaline earth oxide is form

A supported catalyst is prepared by depositing oxides of nickel and cobalt, with or without noble metals, on a sintered low surface area porous inert support, surface of which is precoated with an oxide of Be, Mg, Ca or a mixture thereof so that a protective layer of the alkaline earth oxide is formed between the oxides of nickel and cobalt, with or without noble metal, and the support and hence direct chemical interactions between the oxides of the group VIII transition metals and the reactive components of support, which leads to the formation of catalytically inactive binary oxide phases are avoided.

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[ We claim:] [1.] A process for the preparation of a supported catalyst, containing oxides of nickel and cobalt, deposited on a precoated support, represented by the formula: EQU A.sub.a Co.sub.b NiO.sub.c (x)/MO.sub.d (y)/S rein: A is a noble metal element selected from the group consisting of Ru,

[ We claim:] [1.] A process for the preparation of a supported catalyst, containing oxides of nickel and cobalt, deposited on a precoated support, represented by the formula: EQU A.sub.a Co.sub.b NiO.sub.c (x)/MO.sub.d (y)/S rein: A is a noble metal element selected from the group consisting of Ru, Rh, Pd, Pt, Ir, Os, or a mixture thereof, Co is cobalt; Ni is nickel; O is oxygen; M is an alkaline earth element selected from the group consisting of Be, Mg, or a mixture thereof, a is an A/Ni mole ratio in the range of 0 to about 0.1; b is a Co/Ni mole ratio in the range of about 0.01 to about 2.0; c is a number of oxygen atoms needed to fulfill the valence requirement of A.sub.a Co.sub.b Ni; d is a number of oxygen atoms required to fulfill the valence requirement of M; S is a catalyst support comprising sintered, porous refractory inert solids comprising alumina, silica, silica-alumina, silicon carbide, zirconia, hafnia or a mixture thereof and having a surface area in the range of about 0.002 m.sup.2 g.sup.-1 to about 5.0 m.sup.2 g.sup.-1 ; y is a weight percent loading of the alkaline earth oxides, MO.sub.d, precoated on the support in the range of about 0.3 wt. % to about 30 wt. %; and x is a wt. % loading of the group VIII transition metal oxides, A.sub.a Co.sub.b NiO.sub.c, deposited on the precoated support in the range of about 0.3 wt. % to about 30 wt. %, useful for the oxidative conversion of methane, natural gas and biogas to syngas by processes involving partial oxidation with oxygen or oxidative steam and/or CO.sub.2 reforming with oxygen of methane or light hydrocarbons to syngas, which comprises:(1) precoating the surface of the support by the deposition of MO.sub.d by impregnating or coating the support with a compound represented by the formula: MZ.sub.h, wherein: M is alkaline earth element selected from the group consisting of Be, Mg, or a mixture thereof; Z is an anion selected from the group consisting of nitrate, acetate, formate, oxalate, hydroxide, carbonate and oxide anions; and h is a number of Z required to fulfill the valence requirement of M in the compound, which on decomposition converts into oxide form, in quantity sufficient to obtain a loading of MO.sub.d on the support in the range of about 0.3 wt. % to about 30 wt. %;(2) subsequent drying of the wet mass by heating it in air or under vacuum first slowly at about 50.degree. C. for about 6 h and then at about 120.degree. C. for about 2 h,(3) subsequent decomposition of the dried mass by heating it in air, inert gas or under vacuum at a temperature in the range of about 400.degree. C. to about 600.degree. C. for a period in the range of about 0.5 h to about 5 h;(4) and calcining it at a temperature in the range of about 750.degree. C. to about 1200.degree. C. in air, inert gas or under vacuum for a period in the range of about 0.1 to about 10 h, to obtain the support precoated with MO.sub.d, and(5) depositing A.sub.a Co.sub.b NiO.sub.c on the surface of the precoated support by impregnating or coating it with the compounds of nickel, cobalt and noble metals, represented by the formulae: NiY.sub.g, CoY.sub.f and AX.sub.e respectively, wherein: Ni is nickel; Co is cobalt, A is a noble metal element selected from the group consisting of Ru, Rh, Pd, Pt, Ir, Os, or their mixture; Y is an anion selected from the group consisting of nitrate, acetate, formate, oxalate, oxide, carbonate and hydroxide anions; X is an anion selected from the group consisting of nitrate, acetate, chloride and (H.sub.2 Cl.sub.6).sup.-4 anions; g and f are numbers of Y needed to fulfill the valence requirement of Ni and Co, respectively, in their compounds; and e is a number of X needed to fulfill the valence requirement of A in its compound, which on decomposition convert into their oxide form, with A/Ni and Co/Ni mole ratios in the range of 0 to about 0.1 and about 0.01 to about 2.0, respectively, and in quantities sufficient to obtain a loading of A.sub.a Co.sub.b NiO.sub.c on the precoated support in the range of about 0.3 wt. % to about 30 wt. %,(6) subsequent drying of the wet catalyst mass by heating it in air or under vacuum first slowly at about 50.degree. C. for about 6 h and further at about 120.degree. C. for about 2 h, and(7) subsequent decomposition of the dried catalyst mass by heating in air, inert gas or under vacuum at a temperature in the range of about 400.degree. C. to about 600.degree. C. for a period in the range of about 0.5 h to about 5 h and(8) finally calcining it in air, inert gas or under vacuum at a temperature in the range of about 750.degree. C. to about 1200.degree. C. for a period in the range of about 0.1 to about 10 h.