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Low alkaline inverted in-situ crystallized zeolite membrane 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • B01J-020/28
출원번호 US-0267760 (1994-07-08)
발명자 / 주소
  • Lai Wenyih Frank
출원인 / 주소
  • Exxon Research & Engineering Company
대리인 / 주소
    Bakun
인용정보 피인용 횟수 : 14  인용 특허 : 25

초록

Applicant has discovered a new zeolite membrane and a process for preparing the same. The membrane is unique in that the zeolite crystals making up the membrane pack in a manner such that the membrane is essentially continuous with no large scale voids even when the membrane is <10 .mu.m thick. Thus

대표청구항

[ What is claimed is:] [1.] A zeolite membrane comprising a substrate and a layer of zeolite crystals wherein said layer of zeolite crystals is a polycrystalline layer with at least 99% of said zeolite crystals having at least one point between adjacent crystals that is .ltoreq.20 .ANG. and wherein

이 특허에 인용된 특허 (25)

  1. Minet Ronald G. (592 Garfield Ave. South Pasadena CA 91030) Tsotsis Theodore T. (16312 Angler La. Huntington Beach CA 92647), Catalytic ceramic membrane steam/hydrocarbon reformer.
  2. Haag Werner O. (Lawrenceville NJ) Tsikoyiannis John G. (Princeton NJ), Catalytic conversion over membrane composed of a pure molecular sieve.
  3. Hazbun Edward A. (Media PA), Ceramic membrane and use thereof for hydrocarbon conversion.
  4. Nemet-Mavrodin Margaret (Cherry Hill NJ), Combustive membrane reactor and paraffin upgrading process.
  5. Suzuki Hiroshi (No. 12-11 ; Nakayama ; 3-chome Ichikawa ; Chiba 272 JPX), Composite membrane having a surface layer of an ultrathin film of cage-shaped zeolite and processes for production there.
  6. Hildenbrand Karlheinz (Krefeld DEX) Dhein Rolf (Krefeld DEX) Meister Willi (Dormagen DEX) Nerger Dittmar (Krefeld DEX), Composite membranes, processes for their preparation and their use.
  7. Mercer William C. (Brookfield CT) Coughlin Peter K. (Yorktown Heights NY) McLeod ; Jr. Donald (Briarcliff Manor NY) Flanigen Edith M. (White Plains NY), Composite moisture sensing apparatus and method.
  8. Ma Yi H. (Worcester MA) Xiang Shouhe (Tianjin CNX), Formation of zeolite membranes from sols.
  9. Coughlin Peter K. (Yorktown Heights NY) Mercer William C. (Brookfield CT) Flanigen Edith M. (White Plains NY), Grown crystalline sensor and method for sensing.
  10. Weisz Paul B. (Yardley PA) Yan Tsoung Y. (Philadelphia PA), Macrostructural unit having a catalytically-active zeolite surface.
  11. Haag Werner O. (Lawrenceville NJ) Tsikoyiannis John G. (Princeton NJ), Membrane composed of a pure molecular sieve.
  12. Soria Raymond (Bazet FRX) Gillot Jacques (Laloubere FRX), Membrane device for filtration, separation, or catalytic reaction.
  13. Sterzel Hans-Josef (Dannstadt-Schauernheim DEX) Sanner Axel (Frankenthal DEX), Membranes of organic polymers which contain crystalline carrier compounds, and their preparation.
  14. Dunne Stephen R. (Bethel CT) McKeon Michael J. (Brewster NY) Cohen Alan P. (New Fairfield CT) Behan Albert S. (Bronxville NY), Method of coating aluminum substrates with solid adsorbent.
  15. Lachman Irwin M. (Corning NY) Patil Mallanagouda D. (Corning NY), Method of crystallizing a zeolite on the surface of a monolithic ceramic substrate.
  16. Lachman Irwin M. (Corning NY) Nordlie Lawrence A. (Corning NY), Method of producing high-strength high surface area catalyst supports.
  17. Mercer William C. (Brookfield CT) Coughlin Peter K. (Yorktown Heights NY) McLeod ; Jr. Donald (Briarcliff Manor NY) Flanigen Edith M. (White Plains NY), Moisture sensing apparatus and method.
  18. Lachman Irwin M. (Corning NY) Nordlie Lawrence A. (Corning NY), Monolithic catalyst supports incorporating a mixture of alumina and silica as a high surface area catalyst support mater.
  19. Mercer William C. (Brookfield CT) Coughlin Peter K. (Yorktown Heights NY) Wilson Stephen T. (Shrub Oak NY) Flanigen Edith M. (White Plains NY), Multiphase composite and processes for preparing same.
  20. Lachman Irwin M. (Corning NY) Golino Carlo (Corning NY), Preparation of high surface area agglomerates for catalyst support and preparation of monolithic support structures cont.
  21. Lachman Irwin M. (Corning NY) Bardhan Pronob (Corning NY) Nordlie Lawrence A. (Corning NY), Preparation of monolithic catalyst support structures having an integrated high surface area phase.
  22. DiCosimo Robert (Shaker Heights OH) Burrington James D. (Richmond Heights OH) Grasselli Robert K. (Aurora OH), Process for effecting oxidative dehydrodimerization.
  23. Rojey Alexandre (Garches FRX) Deschamps Andr (Noisy Le Roi FRX) Grehier Alain (Paris FRX) Robert Eric (Rueil-Malmaison FRX), Process for separation of the constituents of a mixture in the gas phase using a composite membrane.
  24. Haag Werner O. (Lawrenceville NJ) Tsikoyiannis John G. (Princeton NJ) Valyocsik Ernest W. (Yardley PA), Synthesis of membrane composed of a pure molecular sieve.
  25. Hashimoto Kenji (Tsuzuki JPX) Masuda Takao (Uji JPX) Sato Atsushi (Ama JPX) Yoshida Shuichi (Handa JPX), Synthetic film of zeolite crystal body and method for manufacturing the zeolite film.

이 특허를 인용한 특허 (14)

  1. Fain, Sr., Douglas E.; Marshall, Bruce B.; Adcock, Kenneth D.; Phillips, Michael R.; Roettger, George E., Article and method for producing extremely small pore inorganic membranes.
  2. Falconer, John L.; Noble, Richard D.; Tokay, Begum; Zhang, Yanfeng, High flux SAPO-34 membranes for CO2/CH4 separation and template removal method.
  3. Li, Shiguang; Falconer, John L.; Noble, Richard D., High flux and selectivity SAPO-34 membranes for CO2/CH4separations.
  4. Falconer,John L.; Li,Shiguang; Noble,Richard D., High-selectivity supported SAPO membranes.
  5. Yan, Yushan, Hydrophilic zeolite coating.
  6. Yushan Yan, Hydrophilic zeolite coating.
  7. Vu, Tuan Anh; Noble, Richard D.; Falconer, John L., Isomorphously substituted molecular sieve membranes.
  8. Vu,Tuan Anh; Noble,Richard D.; Falconer,John L., Isomorphously substituted molecular sieve membranes.
  9. Funke Hans H. ; Klaus Jason W. ; George Steven M. ; Ott Andrew W. ; Falconer John L. ; Noble Richard D., Modified zeolite membrane.
  10. Deckman,Harry William; Jacobson,Allan Joseph; McHenry,James Alexander; Keizer,Klaas; Vroon,Zeger Alexander Eduard Pieter; Czarnetzki,Lothar Ruediger; Lai,Frank Wenyih; Bons,Antonie Jan; Burggraaf,Ant, Molecular sieve layers and processes for their manufacture.
  11. Tsapatsis, Michael; Jeong, Hae-Kwon; Choi, Jungkyu, Molecular sieve membranes and thermal treatment methods of making the same.
  12. Falconer, John L.; Carreon, Moises A.; Li, Shiguang; Noble, Richard D., Synthesis of zeolites and zeolite membranes using multiple structure directing agents.
  13. Tomita, Toshihiro; Nakamura, Shinji, Zeolite formed product, zeolite laminate intermediate, zeolite laminate composite and method for their preparation.
  14. Kim D. Pierotti ; Dell J. St. Julien, Zeolite membrane and a process for the production thereof.
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