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An electrochemical device for separating oxygen from an oxygen-containing gas comprises a plurality of planar ion-conductive solid electrolyte plates and electrically-conductive gas-impermeable interconnects assembled in a multi-cell stack. Electrically-conductive anode and cathode material is appli

An electrochemical device for separating oxygen from an oxygen-containing gas comprises a plurality of planar ion-conductive solid electrolyte plates and electrically-conductive gas-impermeable interconnects assembled in a multi-cell stack. Electrically-conductive anode and cathode material is applied to opposite sides of each electrolyte plate. A gas-tight anode seal is bonded between the anode side of each electrolyte plate and the anode side of the adjacent interconnect. A biasing electrode, applied to the anode side of each electrolyte plate between the anode seal and the edge of the anode, eliminates anode seal failure by minimizing the electrical potential across the seal. The seal potential is maintained below about 40 mV and preferably below about 25 mV. A gas-tight seal is applied between the cathode sides of each electrolyte plate and the adjacent interconnect such that the anode and cathode seals are radially offset on opposite sides of the plate. The combination of biasing electrodes and offset seals is particularly effective in eliminating anode seal failure.

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[ We claim:] [1.] A method for separating oxygen from an oxygen-containing gas which comprises:(a) contacting the oxygen-containing gas with a first surface of a planar solid electrolyte capable of transporting oxygen ions;(b) supplying electrons to the first surface of the planar solid electrolyte

[ We claim:] [1.] A method for separating oxygen from an oxygen-containing gas which comprises:(a) contacting the oxygen-containing gas with a first surface of a planar solid electrolyte capable of transporting oxygen ions;(b) supplying electrons to the first surface of the planar solid electrolyte by a cathode in electrical contact with a portion of the first surface;(c) electrochemically reducing oxygen in the oxygen-containing gas by consuming electrons to produce oxygen ions;(d) transporting the resulting oxygen ions as current through the solid electrolyte by imposing an electrical potential across the solid electrolyte;(e) producing oxygen gas at a second surface of the solid electrolyte by consuming oxygen ions and producing electrons;(f) conducting the electrons of step (e) from the second surface by an anode in electrical contact with a portion of the second surface;(g) conducting the electrons of step (f) from the anode by a gas impermeable electrically conducting interconnect which is in electrical contact with the anode;(h) collecting the oxygen gas in a cavity bounded at least in part by the second surface of the solid electrolyte, the gas impermeable electrically conducting interconnect, and a gas-tight anode seal disposed between a portion of the second surface of the solid electrolyte and an opposing portion of the electrically conducting interconnect;(i) withdrawing oxygen gas from the cavity;(j) withdrawing an oxygen-depleted gas from contact with the first surface of the planar solid electrolyte; and(k) maintaining an anode seal potential below about 40 mV. [10.] The method of claim 1 wherein the oxygen-containing gas is a gas containing less than 20.9 vol % oxygen. [11.] The method of claim 10 wherein the oxygen-containing gas comprises argon and an argon product depleted in oxygen is withdrawn after contacting the oxygen-containing gas with the first surface of the solid electrolyte and after the oxygen is removed by reduction and transport across the solid electrolyte in steps (c) and (d). The method of claim 11 wherein the argon product is obtained at a pressure equal to or greater than the pressure of the oxygen gas in the cavity of step (h).