Cyclic N-halamine biocidal monomers and polymers and methods of using the same as biocides, wherein the functional group, halogenated oxazolidinones, may be homo- and copolymerized, are provided. The copolymerizations are effected with inexpensive monomers such as acrylonitrile, styrene, vinyl aceta
Cyclic N-halamine biocidal monomers and polymers and methods of using the same as biocides, wherein the functional group, halogenated oxazolidinones, may be homo- and copolymerized, are provided. The copolymerizations are effected with inexpensive monomers such as acrylonitrile, styrene, vinyl acetate, vinyl chloride, and the like. Grafting reactions were also accomplished with the N-halamine monomers and commercial polymers such as poly-acrylonitrile, poly-styrene, poly-vinyl acetate, poly-vinyl alcohol, poly-vinyl chloride, and cellulose. These N-halamine compounds are stable biocides which release small amounts of free halogen and other impurities. They will be useful as disinfectants for swimming pools, oil and water based paints, preservatives, medical and dental coatings, industrial and commercial coatings, fabrics, sterile bandages, liners of containers, and the like.
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[ What is claimed is:] [1.] A monomer of structure I:STRUCTURE I: [ STR 4 ] wherein X is chlorine or bromine; R.sub.1 is hydroxyl, C.sub.1 -C.sub.4 alkyl, benzyl, substituted benzyl, phenyl or substituted phenyl; and R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, C.sub.1 -C.sub.4 alkyl, be
[ What is claimed is:] [1.] A monomer of structure I:STRUCTURE I: [ STR 4 ] wherein X is chlorine or bromine; R.sub.1 is hydroxyl, C.sub.1 -C.sub.4 alkyl, benzyl, substituted benzyl, phenyl or substituted phenyl; and R.sub.2, R.sub.3 and R.sub.4 are independently hydrogen, C.sub.1 -C.sub.4 alkyl, benzyl, substituted benzyl, phenyl or substituted phenyl.
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이 특허에 인용된 특허 (12)
Kaminski James J. (Lawrence KS) Bodor Nicolae S. (Lawrence KS), 3-Chloro-2-oxazolidinones.
Worley Shelby D. (Auburn AL) Sun Gang (Auburn AL) Sun Wanying (Lodi NJ) Chen Tay-Yuan (Auburn AL), Monomeric and polymeric cyclic amine and-halamine compounds.
Nudel Ron (Brooklyn NY) Janauer Gilbert E. (Binghamton NY) Schrier Eugene E. (Vestal NY) Figura Ilona W. (White Plains NY), Water insoluble disinfectant composition.
Denkewicz, Jr.,Raymond P.; Giaya,Arjan; Kim,Yoojeong; Kagumba,Lawino; Shi,Fengying, Functionalized dendritic polymers for the capture and neutralization of biological and chemical agents.
Mahmud, Khaled; Kagumba, Lawino; Derks, Franciscus Johannes Marie, Functionalized dendritic polymers for the capture and neutralization of biological and chemical agents.
Sun, Yuyu; Chen, Zhaobin, Method for transformation of conventional and commercially important polymers into durable and rechargeable antimicrobial polymeric materials.
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