초록 ▼

A flexible, electrically-conductive, one-component epoxy adhesive composition and method for making the same are provided. The present adhesive composition comprises: (a) at least one polyepoxide resin having a hardness not exceeding a durometer Shore D reading of about 45 when cured with a stoichio

A flexible, electrically-conductive, one-component epoxy adhesive composition and method for making the same are provided. The present adhesive composition comprises: (a) at least one polyepoxide resin having a hardness not exceeding a durometer Shore D reading of about 45 when cured with a stoichiometric amount of diethylene triamine; (b) a substantially stoichiometric amount of curing agent including at least one amine-terminated butadiene-acrylonitrile polymer; and (c) an electrically-conductive filler. The epoxy adhesive, upon cure, has a volume resistivity not exceeding about 10.sup.-3 ohm-cm at room temperature and a drop resistance such that a 6-mil-thick (0.015 cm) bond effected by the adhesive can withstand at least six 60-inch (152 cm) drops onto a hard surface. Optional components in the epoxy adhesive include secondary rigid and semi-rigid epoxy resins, secondary amine curing agents, non-reactive flexibilizers, diluents, and processing aids. The adhesive bonds achieved using these epoxy adhesives are non-brittle, flexible, resilient, and drop-resistant, while also exhibiting strong adhesion and good processing characteristics.

대표청구항 ▼

[ What is claimed is:] [1.] A drop-resistant, flexible electrically-conductive epoxy adhesive comprising the cured reaction product of:(a) at least one flexible polyepoxide resin selected from the group consisting of the diglycidyl ether of polyoxypropylene glycol having an epoxy equivalent weight o

[ What is claimed is:] [1.] A drop-resistant, flexible electrically-conductive epoxy adhesive comprising the cured reaction product of:(a) at least one flexible polyepoxide resin selected from the group consisting of the diglycidyl ether of polyoxypropylene glycol having an epoxy equivalent weight of about 320; the polyglycidyl ether of an aliphatic polyol having an epoxy equivalent weight of about 650; the diglcidyl ether of 1,4-butanediol having an epoxy equivalent weight of about 130; the diglycidyl ether of neopentyl glycol having an epoxy equivalent weight of about 135; the diglycidyl ether of cyclohexane dimethanol having an epoxy equivalent weight of about 160; and the diglycidyl ether of polyoxypropylene glycol having an epoxy equivalent weight of about 190;(b) a substantially stoichiometric amount of curing agent comprising at least one amine-terminated butadiene-acrylonitrile polymer; and(c) an electrically-conductive filler comprising a noble metal selected from the group consisting of gold, silver platinum, nickel, and palladium and being present in said adhesive at a concentration within the range of about 20 to 30 volume percent,wherein said cured reaction product has a volume resistivity not exceeding about 10.sup.-3 ohm-cm at room temperature and a drop resistance such that a bond effected by said cured reaction product can withstand at lest six 60-inch (152 cm) drops onto a hard surface, said bond having a thickness of about 6 mils (0.015 cm).