초록 ▼

Disclosed is a novel proton-exchange membrane (PEM) based solid polymer electrolyte electrochemical oxygen control (EOC) system that can deplete and control the oxygen from a closed container to levels sufficient for both disinfestation and preservation. With the use of this electrochemical process,

Disclosed is a novel proton-exchange membrane (PEM) based solid polymer electrolyte electrochemical oxygen control (EOC) system that can deplete and control the oxygen from a closed container to levels sufficient for both disinfestation and preservation. With the use of this electrochemical process, many insects that infest raw agricultural products and other produce can be exterminated, without detriment to the quality of the produce and without deposition of harmful residue, by reducing the ambient oxygen to a controlled low level for several days. The electrochemical process features the use of a bipolar stack comprised of a selected number of PEM cells connected electrically in series and separated by an electrically conductive bipolar plate. Each cell contains a membrane and electrode assembly, consisting of an anode structure and cathode structure in intimate contact with a PEM. When DC power is applied to the cell stack, electrons are supplied to the cathode, supporting reduction of oxygen at the cathode with the formation of water, and electrons removed from the anode, supporting oxygen evolution by the decomposition of water at the anode. The anode and cathode compartments are separated by the solid ionomer PEM, which transports protons generated at the anode through the PEM to the cathode to complete the electrical circuit internally. Oxygen is depleted by recirculating the gas in the dosed container over the cathode, and expelling the oxygen evolved at the anode by separating the oxygen from the recirculating anode water stream and venting it to the outside of the closed container. Nitrogen or other inert gas is added as makeup gas to avoid creating a negative pressure in the container. A unique feature of this process is that at a low oxygen concentration, the cell and stack cathode current becomes rate-limited in direct proportion to the oxygen level in the recirculating gas and can therefore be used as a measure of the container oxygen level. In the sensing/control scheme developed as part of this invention, the current is periodically allowed to rise to the diffusion limit in a "measure mode" and then reset according to the desired oxygen level, determined from a slope-intercept "measure mode" calibration curve, for a longer "control mode" period.

대표청구항 ▼

[ What is claimed is:] [1.] A proton-exchange membrane (PEM) based electrochemical oxygen control (EOC) system for depleting, monitoring and controlling oxygen in a closed container, said system comprising:a stack of a plurality of series-connected electrochemical oxygen transfer cells, each of said

[ What is claimed is:] [1.] A proton-exchange membrane (PEM) based electrochemical oxygen control (EOC) system for depleting, monitoring and controlling oxygen in a closed container, said system comprising:a stack of a plurality of series-connected electrochemical oxygen transfer cells, each of said cells having a cathode and an anode, said anode and said cathode in each cell being in intimate contact with and separated by a proton-exchange membrane;a power supply for imposing a controlled voltage and current on said electrochemical transfer cells to cause said anode to evolve oxygen from a supply of water and said cathode to consume oxygen from the recirculating gas in the closed container;a process controller for providing an integral reactor feedback electrical signal in response to an oxygen level in the closed container, to deplete, monitor and control the oxygen concentration in said recirculating gas in the dosed container to levels satisfactory for disinfestation and/or retention of the freshness, appearance and taste of the contents of the dosed container.