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Single-site catalysts for olefin polymerization 원문보기

IPC분류정보
국가/구분 United States(US) Patent 등록
국제특허분류(IPC7판)
  • B01J-031/18
출원번호 US-0417510 (1999-10-14)
발명자 / 주소
  • Nagy Sandor
  • Etherton Bradley P.
  • Krishnamurti Ramesh
  • Tyrell John A.
출원인 / 주소
  • Equistar Chemicals, L.P.
대리인 / 주소
    Schuchardt
인용정보 피인용 횟수 : 68  인용 특허 : 10

초록

A single-site olefin polymerization catalyst and method of making it are disclosed. The catalyst comprises an activator and an organometallic complex. The complex comprises a Group 3 to 10 transition or lanthanide metal, M, and at least one indenoindolyl ligand that is .pi.-bonded to M. The key liga

대표청구항

[ We claim:] [1.]1. A catalyst which comprises:(a) an activator; and(b) an organometallic complex comprising a Group 3 to 10 transition or lanthanide metal, M, and at least one indenoindolyl ligand that is .pi.-bonded to M.

이 특허에 인용된 특허 (10)

  1. Godfrey Alexander G. (Greenwood IN), 2-amino-3-aroyl-benzo[b 상세보기
  • Nagy Sandor ; Krishnamurti Ramesh ; Etherton Bradley P., Azaborolinyl metal complexes as olefin polymerization catalysts.
  • Hlatky Gregory G. (Houston TX) Turner Howard W. (Webster TX), Catalyst system of enhanced productivity.
  • Hlatky Gregory G. (Houston TX) Turner Howard W. (Webster TX), Catalyst system of enhanced productivity.
  • Turner Howard W. (Houston) Hlatky Gregory G. (Houston) Eckman Richard R. (Houston TX), Ionic metallocene catalyst compositions.
  • Turner Howard W. (Webster TX), New polymerization catalyst.
  • Turner Howard W. (Webster TX), New polymerization catalyst.
  • Etherton Bradley P. (Houston TX) Nagy Sandor (Grand Island NY), Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring.
  • Nagy Sandor (Grand Island NY) Krishnamurti Ramesh (Amherst NY) Tyrell John A. (Williamsville NY) Cribbs Leonard V. (Houston TX) Cocoman Mary (Grand Island NY), Polymerization of a 상세보기
  • Devore David D. (Midland MI) Timmers Francis J. (Midland MI) Stevens James C. (Richmond TX) Mussell Robert D. (Midland MI) Crawford Lenore H. (Midland MI), Titanium (II) or zirconium (II) complexes and addition polymerization catalysts therefrom.
  • 이 특허를 인용한 특허 (68)

    1. Lynch, Michael W.; Meverden, Craig C.; Nagy, Sandor; Neal-Hawkins, Karen L., Aluminoboronate activators for single-site olefin polymerization catalysts.
    2. Lynch, Michael W.; Meverden, Craig C.; Nagy, Sandor; Neal-Hawkins, Karen L., Aluminoboronate activators for single-site olefin polymerization catalysts.
    3. Barbara M. Tsuie, Amine elimination process for making single-site catalysts.
    4. Sandor Nagy, Bimetallic catalysts for olefin polymerization.
    5. Nagy, Sandor; Tsuie, Barbara M.; Sartain, William J., Bimetallic indenoindolyl catalysts.
    6. McGrath, Patrick J.; Morris, Ronald J.; Kreitz, Roy W., Cascaded boiling pool slurry reactors for producing bimodal low to medium density polyethylene polymers.
    7. Wang,Shaotian, Catalyst preparation method.
    8. Resconi, Luigi; Guidotti, Simona, Catalyst system for the polymerization of olefins.
    9. Resconi, Luigi; Guidotti, Simona, Catalyst system for the polymerization of olefins.
    10. Wang, Shaotian; Lee, Clifford C.; Mack, Mark P.; Hlatky, Gregory G.; Nagy, Sandor; Tsuie, Barbara M.; Meverden, Craig C., Catalysts for making polyolefins.
    11. Jonathan L. Schuchardt, Chelating pyrimidines as ligands for single-site olefin polymerization catalysts.
    12. Schuchardt, Jonathan L., Chelating pyrimidines as ligands for single-site olefin polymerization catalysts.
    13. Nagy, Sandor, Complexes based on four-membered cyclic anionic six-electron-donor ligands.
    14. Wang,Shaotian; Hlatky,Gregory G., Ethylene polymerization process.
    15. Meverden, Craig C.; Nagy, Sandor; Tsuie, Barbara M., High molecular weight polypropylene process.
    16. Mavridis, Harilaos, High tear strength film.
    17. Nagy, Sandor; Tsuie, Barbara M.; Todd, William G.; Holland, Charles S., High-temperature solution process for polyolefin manufacture.
    18. von Kannewurff, Michael C.; Goodman, Jeffrey A.; Culler, Mark F.; Evans, Scott C.; Morgan, Roger J.; Dougherty, John J.; DellaVecchia, Daniel J.; Welles, II, Kenneth B.; Dougherty, Matthew D., Home latch-key web based automation system.
    19. Reinking, Mark K.; Hlatky, Gregory G., Hydrosilane additives for increased polyolefin molecular weight.
    20. Klendworth,Douglas D.; Reinking,Mark K.; Kist,Edward D., Magnesium chloride support.
    21. Feng, Shaoguang; Shankar, Ravi B.; Timmers, Francis J., Metal complexes and polymerization process using same.
    22. Ilya E. Nifant'ev RU; Vladimir V. Bagrov RU, Metallocenes and catalysts for olefin-polymerisation.
    23. Tsuie, Barbara M.; Neal-Hawkins, Karen L.; Nagy, Sandor; Lynch, Michael W.; Mack, Mark P.; Wang, Shaotian; Merrick-Mack, Jean A; Lee, Clifford C.; Mutchler, Joel A.; Johnson, Kenneth W., Method for making polyolefins.
    24. Nagy, Sandor; Tsuie, Barbara M.; Schuchardt, Jonathan L., Olefin polymerization catalysts based on annulated cyclopentadienyl ligands.
    25. Nagy, Sandor; Schuchardt, Jonathan L., Olefin polymerization catalysts based on convex, polcyclic ligands.
    26. Nagy,Sandor, Olefin polymerization catalysts based on hydroxyl-depleted calixarene ligands.
    27. Nagy, Sandor, Olefin polymerization catalysts containing 1,3-diboretanyl ligands.
    28. Wang,Shaotian; Tsuie,Barbara M.; Mack,Mark P.; Vargas,Edward S.; Beran,Debra L., Olefin polymerization methods.
    29. Nagy, Sandor; Tsuie, Barbara M., Olefin polymerization process.
    30. Nagy, Sandor; Tsuie, Barbara M., Olefin polymerization process.
    31. Nagy, Sandor; Tsuie, Barbara M.; Clemons, Ronald J., Olefin polymerization process.
    32. Nagy, Sandor; Tsuie, Barbara M.; Etherton, Bradley P.; Merrick-Mack, Jean A.; Lewis, Everett O.; Mack, Mark P.; Nagy, Natalia; Vargas, Edward S., Olefin polymerization process.
    33. Nagy, Sandor; Tsuie, Barbara M.; Imfeld, Stephen M., Olefin polymerization process.
    34. Nagy, Sandor; Tsuie, Barbara M.; Merrick-Mack, Jean A.; Nagy, Natalia, Olefin polymerization process.
    35. Nagy, Sandor; Tsuie, Barbara M.; Merrick-Mack, Jean A.; Nagy, Natalia, Olefin polymerization process.
    36. Nagy,Sandor; Neal Hawkins,Karen, Olefin polymerization process.
    37. Sartain, William J., Olefin polymerization process.
    38. Wang, Shaotian, Olefin polymerization process.
    39. Wang, Shaotian, Olefin polymerization process.
    40. Wang, Shaotian; Klendworth, Douglas D.; Reinking, Mark K., Olefin polymerization process.
    41. Wang, Shaotian; Klug, Kenneth J., Olefin polymerization process.
    42. Winslow, Linda N.; Joseph, Sebastian; Nagy, Sandor; Nagy, Natalia; Tsuie, Barbara M.; Gates, Charles H., Olefin polymerization process.
    43. Wang,Shaotian; Klug,Kenneth J., Olefin polymerization process with improved operability and polymer properties.
    44. Garrison,Philip J.; Holland,Charles S.; Mack,Mark P.; Winslow,Linda N.; Lewis,Everett O.; Clark,James R.; Cribbs,Leonard V.; Etherton,Bradley P.; Merrick Mack,Jean A.; Nygard,Paula L., Polyethylene process.
    45. Etherton, Bradley P.; Imfeld, Stephen M.; Sasthav, Mohan, Polyethylene thick film and process for preparing polyethylene.
    46. Richard Allen Fisher ; Rolf Bodo Temme DE, Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands.
    47. Meverden, Craig C., Polyolefin block copolymers.
    48. Schwab, Thomas J.; Merrick Mack, Jean A.; Yau, Wallace W.; Williams, Kelly L., Polyolefin compositions.
    49. Wang, Shaotian; Hlatky, Gregory G.; Joseph, Sebastian; Merrick-Mack, Jean A.; Klug, Kenneth J.; Yau, Wallace W., Polyolefin resin blends for crack-resistant pipe.
    50. Meverden, Craig C.; Nagy, Sandor, Polypropylene preparation.
    51. Meverden, Craig C.; Lynch, Michael W., Prealkylated olefin polymerization catalysts and olefin polymerization employing such catalysts.
    52. Chandrashekar, Venki; Mack, Mark P.; Gates, Jr., Charles H.; Holland, Charles S.; Nagy, Natalia; Nagy, Sandor M.; Vargas, Edward S.; Merrick-Mack, Jean A., Preparation of multimodal polyethylene.
    53. Chandrashekar,Venki; Mack,Mark P.; Gates, Jr.,Charles H.; Holland,Charles S.; Nagy,Natalia; Nagy,Sandor M.; Vargas,Edward S.; Merrick Mack,Jean A., Preparation of multimodal polyethylene.
    54. Wang,Shaotian, Preparation of ultra high molecular weight linear low density polyethylene.
    55. Wang, Shaotian; Lee, Clifford C.; Mack, Mark P.; Hlatky, Gregory G.; Nagy, Sandor; Tsuie, Barbara M., Process for making low-density polyolefins.
    56. Wang, Shaotian; Hlatky, Gregory G., Process for making polyethylene.
    57. Winslow,Linda N.; Nagy,Sandor, Process for manufacturing single-site polyolefins.
    58. Resconi, Luigi; Guidotti, Simona; Baruzzi, Giovanni; Grandini, Cristiano; Nifant'ev, Ilya E.; Kashulin, Igor A.; Ivchenko, Pavel V., Process for producing substantially amorphous propylene-based polymers.
    59. Resconi, Luigi; Guidotti, Simona, Process for the polymerization of olefins.
    60. Etherton, Bradley P.; Imfeld, Stephen M.; Garrison, Philip J., Process for the preparation of multimodal polyethylene resins.
    61. Meverden, Craig C.; Hlatky, Gregory G.; Wang, Shaotian, Propylene polymerization process.
    62. Hlatky, Gregory G.; Nagy, Sandor, Single-site catalysts based on anionic thiopyran dioxide ligands.
    63. Gupte, Kiran M.; Tolley, Kevin; Mutchler, Joel A.; Holland, Charles S., Static reduction.
    64. Neal-Hawkins, Karen L.; Nagy, Sandor M.; Sartain, William J.; Gupte, Kiran; Johnson, Kenneth W., Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof.
    65. Wang, Shaotian; Maraschin, Norma J.; Beran, Debra L.; Sartain, William J., Supported olefin polymerization catalysts.
    66. Mason, Mark R., Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts.
    67. Lynch, Michael W.; Wang, Shaotian; Sartain, William J., Use of silanes to control molecular weight in olefin polymerizations.
    68. Meyer, Karen E.; Reinking, Mark K., Use of silanes to enhance activity in single-site polymerizations.

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