[특허]Integrated process for converting hydrocarbon gas to liquids

[미국특허] Integrated process for converting hydrocarbon gas to liquids 원문보기

IPC분류정보
국가/구분	United States(US) Patent 등록
국제특허분류(IPC7판)	C07C-027/00 C07C-273/00 C01C-001/04
출원번호	US-0369045 (1999-08-05)
발명자 / 주소	Gieskes Thomas
출원인 / 주소	Atlantic Richfield Company
대리인 / 주소	Scott
인용정보	피인용 횟수 : 98 인용 특허 : 2

초록 ▼

The present invention is an integrated process for converting light hydrocarbon gas to heavier hydrocarbon liquids. In each embodiment, a Fischer-Tropsch (FT) process comprising a thermal reformer and a reactor containing an FT catalyst is combined with one or more additional processes to achieve operational synergies. In a first embodiment, an FT process is integrated with a cryogenic liquefied natural gas (LNG) process wherein tail gas from the FT reaction is used to drive a refrigeration compressor in the LNG process. The tail gas, optionally supplemented with natural gas, may be fed directly to a gas turbine or may be combusted in steam boiler, which in turn provides steam to a steam turbine. The natural gas may be processed prior to its being fed to the LNG process and the FT process in order to remove any impurities and/or condensate. The process may be further integrated with a fertilizer production process comprising an ammonia synthesis process and a urea synthesis process. To produce ammonia, hydrogen separated from synthesis gas produced in a primary and/or secondary reformer in the FT process is combined with nitrogen produced in the LNG process. Nitrogen may also be supplied to the ammonia synthesis process from an optional air separation process, which also provides oxygen enrichment to the thermal reformer in the FT process. To produce urea, the ammonia is subsequently reacted with carbon dioxide removed during processing of the gas prior to its liquefaction. The integrated FT/LNG/Fertilizer process may be further integrated with a carbon dioxide removal process which separates flue gas from a gas turbine or steam generator driving the refrigeration compressor in the LNG process into nitrogen which is used in the ammonia synthesis process and carbon dioxide which is used in the urea synthesis unit. Alternatively, the FT process may be integrated directly with the fertilizer production process, in the absence of an LNG process. In an alternative embodiment, an FT process is integrated with a methanol synthesis process wherein tail gas from the FT reaction is used to fuel burners in a secondary thermal reformer.

대표청구항 ▼

[ What is claimed is:] [1.]1. An integrated process for converting hydrocarbon gas to liquids, comprising:(a) liquefying natural gas in a cryogenic liquefaction unit;(b) reforming natural gas into synthesis gas;(c) reacting the synthesis gas with a Fischer-Tropsch catalyst to produce liquid hydrocarbons and tail gas;(d) driving a refrigeration compressor in the cryogenic liquefaction unit with the tail gas; and(e) recovering liquefied natural gas and liquid hydrocarbons.

이 특허에 인용된 특허 (2) 인용/피인용 타임라인 분석

Waycuilis John J., Hydrocarbon gas conversion system and process for producing a synthetic hydrocarbon liquid.
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Agee Mark A. ; Weick Larry J., System and method for converting light hydrocarbons to heavier hydrocarbons with separation of water into oxygen and hydrogen.
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이 특허를 인용한 특허 (98) 인용/피인용 타임라인 분석

Pedersen, Peter S.; Yakobson, Dennis L., Apparatus and methods for the production of ammonia and fischer-tropsch liquids.
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Munson, Curtis L.; O'Rear, Dennis J.; Chinn, Daniel, Aqueous separation of syngas components.
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Ravikumar, Ravi; Koppel, Paul E.; Dabee, Sanjiv; Zychowicz, Johnathon, Configurations and method of integrating a gas to liquids (GTL) plant in a refinery.
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Davey, William; Wurzel, Thomas, Coproduction of methanol and ammonia from natural gas.
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Sites, O. Angus; Bohra, Lalit K., Enhanced coal-bed methane production.
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Della-Fera, Gabriel; Denman, Todd F.; Ellis, Scott E., Erosion suppression system and method in an exhaust gas recirculation gas turbine system.
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Steinberg, Meyer, Fertilizer production from fossil fuel with minimal carbon dioxide emission.
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Kennedy, Paul Edwin, Hydrocarbon conversion process using a plurality of synthesis gas sources.
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Espinoza, Rafael L.; Mohedas, Sergio R.; Goodwin, III, Ralph T.; Landis, Stephen R.; Belt, Barbara A., Hydrogen use in a GTL plant.
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Sheppard, Richard O.; Yakobson, Dennis L., Integrated Fischer-Tropsch and power production plant with low CO2 emissions.
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Zhou, Peizheng; Lu, Yijun; Rueter, Michael, Integrated process for the production of hydrocarbon liquids and ammonia.
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Sheppard, Richard O.; Yakobson, Dennis L., Integrated urea manufacturing plants and processes.
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Minta, Moses; Mittricker, Franklin F.; Rasmussen, Peter C.; Starcher, Loren K.; Rasmussen, Chad C.; Wilkins, James T.; Meidel, Jr., Richard W., Low emission power generation and hydrocarbon recovery systems and methods.
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Nelson, Eric D; Minta, Moses; Starcher, Loren K; Mittricker, Franklin; Sites, Omar Angus; Dickson, Jasper L, Low emission power generation and hydrocarbon recovery systems and methods.
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Oelfke, Russell H.; Minta, Moses, Low emission power generation systems and methods.
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[미국특허] Integrated process for converting hydrocarbon gas to liquids 원문보기

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